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Interface studies of rare earth oxides on silicon and germanium substrates

Interface studies of rare earth oxides on silicon and germanium substrates

Interface studies of rare earth oxides on silicon and germanium substrates

... dielectric constant.22,25 Table 2.1: Summary of the dielectric constant (k), band gap (Eg), conduction (CBO) and valence band offsets (VBO) on Si values for rare earth (RE) oxides and transition metal ... explanation as to why rare earth oxides form good interfaces with Ge 2.1.1 Rare earth oxides as second generation high-k dielectrics The criterion of thermodynamic stability on Si limits the choice of ... Publications 211  vii List of Tables List of Tables Table 2.1: Summary of the dielectric constant (k), band gap (Eg), conduction (CBO) and valence band offsets (VBO) on Si values for rare earth...
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Báo cáo hóa học:

Báo cáo hóa học: "Influence of Rare Earth Doping on the Structural and Catalytic Properties of Nanostructured Tin Oxide" docx

... Sn#1000 Conversion/Selectivity (%) Conversion/Selectivity (%) ð1Þ The effects of the process of segregation and de-mixing of these rare earths on the SnO2 catalytic properties were studied and compared ... modification of the nanostructure and the basic sites of the particles Another phenomenon starts to occur on the surface of doped samples, a segregation process of particles of metastable solid solution, ... on the morphology and properties of tin oxide Rare earth cations have, as yet, been little explored as tin oxide dopants for catalytic purposes However, the consensus is that their influence on...
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Báo cáo hóa học:

Báo cáo hóa học: " Photoelectrochemical studies of DNA-tagged biomolecules on Au and Au/Ni/Au multilayer nanowires" docx

... images of Au and Au/ Ni /Au NWs with tagging; (d) and (f) fluorescence images of Au and Au/ Ni /Au NWs with tagging upon green light excitation of 532 nm NWs A distinct image of Au maximum emission and ... DNA, (iv) Au/ Ni /Au NWs with tagging of cy3-dye attached DNA PL images of (v) Au NWs and (vi) distinct difference of Au and Ni in Au/ Ni /Au multilayer NWs Figure Measurement of dark current and photocurrent ... PBS solution Page of for the synthesis of Au NWs and multilayer NWs The optical absorbance was lower in multilayer NWs because of the amount of wire aggregation and the force of attraction between...
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Structural, electrical and optical studies on the effects of rapid thermal processing on silicon germanium carbon films

Structural, electrical and optical studies on the effects of rapid thermal processing on silicon germanium carbon films

... STRUCTURAL, ELECTRICAL AND OPTICAL STUDIES ON THE EFFECTS OF RAPID THERMAL PROCESSING ON SILICONGERMANIUM -CARBON FILMS FENG WEI (M Eng, XJTU) A THESIS SUBMITTED FOR THE DEGREE OF DOCTOR OF ... was explained based on the theory of binary alloy oxidation and the consideration of large difference in the heat of formation of SiO2 and GeO2 Rapid thermal oxidation of SiGe films was examined ... activities The effect of rapid thermal processing (annealing and oxidation) on the structural, electrical and optical properties of strained Si1−xGex and Si1−x−yGexCy alloys is the main concern of this...
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A new mechanism for modulation of schottky barrier heights on silicon nanowires

A new mechanism for modulation of schottky barrier heights on silicon nanowires

... in contact with the end surfaces of the wires were obtained by annealing at 250 1C for 20 Using the Pd2Si contacts as source and drain and the silicon substrate as a back-gate, a transistor configuration ... configuration, contact geometry and charge distribution are demonstrated in Fig The preparation started from an SOI wafer with a silicon film thickness of 55 nm and a buried oxide layer (BOX) of 145 ... ¨m elementary point charges are placed on the surface of the wire to a concentration of  1012 cmÀ2 and mirrored in the metal The barrier lowering for this concentration at a distance of nm from...
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Studies of self assembled monolayers on highly oriented pyrolytic graphite using scanning tunneling microscopy and computational simulation 1

Studies of self assembled monolayers on highly oriented pyrolytic graphite using scanning tunneling microscopy and computational simulation 1

... concept of the self- assembled monolayers (SAMs) is primarily introduced by Zisman in 19 46 [12 , 13 ] The traditional SAMs is an organized layer of INTRODUCTION amphiphilic molecules in which one ... development, and biological process Works of thiols adsorbed on gold surfaces by Nuzzo and Allara [13 , 15 ] in the early 19 80s and trichlorosilanes on silicon oxide by Maoz and Sagiv [13 , 16 ] introduced ... deposited onto the substrate surface from either vapor or liquid phase A typical example is that the formation of thiolate monolayers on the gold (11 1) surface (Fig 1. 3) Fig 1. 3 Schematic of an n-dodecanethiolate...
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Studies of self assembled monolayers on highly oriented pyrolytic graphite using scanning tunneling microscopy and computational simulation 2

Studies of self assembled monolayers on highly oriented pyrolytic graphite using scanning tunneling microscopy and computational simulation 2

... Valiyaveettil Suresh’s group C12H25 C12H25 C12H25 N C12H25 C12H25 C12H25 N C12H25 C12H25 C12H25 C12H25 CPAH CHBC C12H25 Br N Br N C12H25 C12H25 C12H25 CHBC2 N C12H25 N C12H25 TCC 34 EXPERIMENTAL R ... C12H25 C12H25 N C12H25 C12H25 N C12H25 C12H25 CHBC3 Derivatives of perylene by Prof Valiyaveettil Suresh’s group C12H25 N O O O C12H25 N O O C12H25 N O S Br Br S O N O C12H25 O O DDPER N O C12H25 S170 ... C12H25 C12H25 N O O C12H25 N O OMe OMe MeO OMe MeO MeO OMe OMe O N O C12H25 S169 O N O C12H25 S1 72 36 EXPERIMENTAL O C12H25 N O O C12H25 N O OCH3 OCH3 H3CO S S H3CO OCH3 OCH3 O N O C12H25 SIV233...
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Studies of self assembled monolayers on highly oriented pyrolytic graphite using scanning tunneling microscopy and computational simulation 3

Studies of self assembled monolayers on highly oriented pyrolytic graphite using scanning tunneling microscopy and computational simulation 3

... calibration of the “A” scanner for scanning tunneling microscope function 3. 3.2 Calibration Procedures The calibration of STM can be conducted with a standard sample: highly ordered pyrolytic graphite ... bright carbon atoms was 0.267nm 44 CALIBRATION Fig 3. 4 Section Analysis of the STM image in Fig 3. 3 along the orientation of the white arrow Fig 3. 5 shows the standard parameters of the graphite ... finds useful applications such as the production and detection of sound, generation of high voltages, electronic frequency generation, microbalance, and ultra fine focusing of optical assemblies...
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Studies of self assembled monolayers on highly oriented pyrolytic graphite using scanning tunneling microscopy and computational simulation 4

Studies of self assembled monolayers on highly oriented pyrolytic graphite using scanning tunneling microscopy and computational simulation 4

... to verify the existence of interaction between the adsorbate and graphite surface 4. 2 STM Results and Computational Simulations 4. 2.1 Solution Preparation Three solutions of fatty acids in phenyloctane ... interaction as shown in Table 4. 2 Our computational simulation does not reveal the physisorption route and steps of the monolayers formation, instead, it can only provide the energies of the final ... about the configuration of two species within the 63 PHYSISORPTION OF BINARY FATTY ACIDS ON HOPG monolayers formed by the binary acids solution Fig 4. 9 Top view of Model A and B with graphite lattice...
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Studies of self assembled monolayers on highly oriented pyrolytic graphite using scanning tunneling microscopy and computational simulation 5

Studies of self assembled monolayers on highly oriented pyrolytic graphite using scanning tunneling microscopy and computational simulation 5

... steric repulsion Fig 5. 4 The molecular model of the DDPER arrays 5. 4 The Computational Simulation 5. 4.1 Conformation of gas phase DDPER and its derivatives Building of the computational model started ... interaction 83 FORMATION OF SAMs CONRTOLLED BY STERIC EFFECTS 5. 4.2 DDPER/HOPG vs S170/HOPG Computational simulation was applied to compare the adsorption energies of DDPER and S170 on graphite ... Section analysis showed that the DDPER centers had an average relative height of 0.2 nm (Fig 5. 3) Fig 5. 3 The height profile of the DDPER Self- Assembled Monolayers 78 FORMATION OF SAMs CONRTOLLED...
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Studies of self assembled monolayers on highly oriented pyrolytic graphite using scanning tunneling microscopy and computational simulation 6

Studies of self assembled monolayers on highly oriented pyrolytic graphite using scanning tunneling microscopy and computational simulation 6

... 3.900.80nm and 2.950 .60 nm N N N Fig 6. 4 Left: High resolution image of HHB monolayers: Bright hexagons represent the benzene ring of HHB Right: the molecular configuration of HHB (R-HHB) in monolayers ... N Fig 6. 3 Left: High resolution image of HHB monolayers: Bright hexagons represent the benzene ring of HHB Right: the molecular configuration of HHB (L-HHB) in monolayers (Vbias = 100mV, and Iset ... Fig 6. 8 Illustration of physisorption of HHB molecule onto HOPG surfaces 102 ADSORPTION-INDUCED CHIRAL SAMs The physisorption process can be considered as an addition reaction between the HHB and...
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Studies of self assembled monolayers on highly oriented pyrolytic graphite using scanning tunneling microscopy and computational simulation 7

Studies of self assembled monolayers on highly oriented pyrolytic graphite using scanning tunneling microscopy and computational simulation 7

... be 7. 4.1 Concentration It is very obvious that the possibility of forming SAMs on HOPG is highly concentration dependent   1 k [ P] When the concentration of the molecule increases, (7- 7) ... observation and equation (7- 10), a rough diagram [Fig 7. 4] of the surface coverage  vs [P] was proposed 1 17 FORMATION OF 2D CRYSTALS ON HOPG Fig 7. 4 Propsed diagram of surface coverage  vs solution ... growth of SAMs on HOPG Although the graphite surface has a high degree of perfection, they still have steps and defects, as shown in Fig 7. 1 112 FORMATION OF 2D CRYSTALS ON HOPG Fig 7. 1 STM image of...
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Scanning tunneling microscopy studies of self assembled nanostructures on graphite

Scanning tunneling microscopy studies of self assembled nanostructures on graphite

... Introduction Several studies of metals on graphite have demonstrated the fabrication of different types of nanostructures and behavior of metal atoms on graphite Ganz et al studied the growth of different ... interaction can alter particle shape significantly 1.1 Nucleation and Growth of nanostructures on Inert substrates The understanding of nucleation and growth of self- assembled nanostructures on solid ... characterize self- assembled nanostructures for fundamental interests along with several applications in the field of nanodevices [1113] The shape, size and location of self- assembled nanostructures...
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Growth and characterization of oxide thin films on silicon by pulsed laser deposition

Growth and characterization of oxide thin films on silicon by pulsed laser deposition

... method of pulsed laser deposition (PLD); investigate the growth mechanism of high quality MgO films on silicon Fabricate highly oriented CoFe2O4 films on silicon with the help of MgO buffer layer and ... thesis 2.1.1 Pulsed- laser deposition One of the most significant approaches to oxide film growth is pulsed- laser deposition Pulsed- laser deposition (PLD) is now a widely used deposition approach ... BiFeO3 thin films on silicon with the Pt buffer by the method of PLD; investigate ferroelectric, ferromagnetic and magnetoelectric properties of these Ba-doped BiFeO3 thin films on silicon and their...
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Sincerity and the end of theodicy - three remarks on Levinas and Kant

Sincerity and the end of theodicy - three remarks on Levinas and Kant

... itself endlessly Levinas s response to this return of the refuted is twofold On the one hand, it attests to the saying of the said, to the fact that the self-contradictory nature of the thesis (the ... constitute an exposition of a subject called to critique Think of that exposition as the description of suffering and that critique as the critique of theodicy, the announcing of the end of theodicy ... responsiblity as and for the excess of the saying over the said But, so conceived, this responsibility can only call for the proliferation of the said and the proliferation of a critique of the...
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