iron ii and ruthenium ii complexes of 4 apos substituted 2 2 apos 6 apos 2 apos apos terpyridine ligands
Cu(II) and Ni(II) complexes of n (2 hydroxybenzyl) amino acid ligands synthesis, structures, properties and catecholase activity 4
... 2. 089 (4) Ni (2) -O( 14) 2. 039 (4) Ni (2) -O(7) 2. 0 42 (4) Ni (2) -O(5)a 2. 048 (4) Ni (2) -O(13) 2. 070(3) Ni (2) -O (6) 2. 101(3) O(5)-Ni (2) b 2. 048 (4) O( 14) -Ni (2) -O(5)a 89 .4( 2) O(7)-Ni (2) -O(5)a 92. 9 (2) O(5)a-Ni (2) -O(13) ... 2. 26 (4) 3. 120 (6) 1 62 (4) O5 O17-H17A 0.89 (4) 2. 35(3) 2. 943 (6) 1 24 ( 3) O13 x, y-1, z x-1, y+1 /2, z1 O17-H17B 1.99 (4) 2. 8 42 (6) 157 (4) O3 O18-H18A 0.90(3) 1. 86( 3) 2. 729 (6) 1 64 ( 4) O8 O18-H18B 0.89 (4) ... 0.89 (2) 1. 84( 2) 2. 7 24 ( 6) 1 72( 2) O 16 O 14- H14A 0.09(3) 2. 35(5) 2. 803(15) 111(3) O20B x-1, y-1 /2, z-1 O 14- H14B 0.90(3) 1.99 (4) 2. 773 (6) 145 (5) O7 x, y+1, z O15-H15A 0.90(3) 1. 92 (4) 2. 7 72( 7) 158 (4) ...
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Cu(II) and Ni(II) complexes of n (2 hydroxybenzyl) amino acid ligands synthesis, structures, properties and catecholase activity 3
... absorption bands of III-1 to III-7 III-1 Absorption bandsa (nm) CT d-d 720 40 6 III -2 67 3 3 76 III-3 67 8 3 82 III -4 68 5 3 92 III-5 64 6 , 725 3 72 III -6 653, 740 366 III-7 64 8 , 7 34 3 62 Complex [a]: nujol ... 3131 16 02 13 74 1 26 0 22 8 III-5 344 5 3 1 46 1591 140 5 1 26 1 1 86 III -6 345 2 3151 160 6 1380 1 26 3 22 6 III-7 31 76 1 62 7 1371 25 6 12 74 3-3 -2 Electronic spectra Electronic spectral absorption bands of III-1 ... (cm-1) in III-1 to III-7 Complex υ(OH) υ(NH) υas(COO-) υs(COO-) υ (CO) Δυ phenolic III-1 3513 31 24 160 3 13 76 1 26 2 22 7 III -2 3 42 9 3118 15 72 13 62 1 26 2 21 0 III- 3 42 8 29 85 1570 1 348 1 26 8 22 2 III -4 3131...
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Cu(II) and Ni(II) complexes of n (2 hydroxybenzyl) amino acid ligands synthesis, structures, properties and catecholase activity 2
... 29 37 1 62 2 13 82 1 26 6 24 0 IIA-7 343 6 29 32 16 24 1381 1 26 2 24 3 IIA-8 3 42 9 29 28 1597 148 2 1 26 5 115 IIA-9 349 6 29 39 160 1 1395 12 64 20 6 IIA-10 345 8 29 36 161 0 13 96 1 26 2 2 14 IIA-11 340 6 29 20 161 1 143 6 129 9 ... phenolic IIA-1 3398 29 34 161 7 13 76 1 26 6 24 1 IIA -2 340 0 29 55 161 9 1375 1 26 6 24 4 IIA-3 3399 29 60 1 62 1 1 369 12 64 25 2 IIA -4 348 1 29 54 1 62 5 1 366 12 64 25 9 IIA-5 343 5 29 30 1 64 0 1373 127 2 26 7 IIA -6 344 7 29 37 ... (2. 8) 26 0 IIA -6 2H2O 65 – 168 4. 4 (4. 9) 26 5 IIA-7 2H2O 68 – 127 5.5 (5 .2) 27 0 IIA-8 6H2O 64 – 119 5.9 (5.5) 24 0 IIA-9 2H2O 80 – 1 46 5.8 (5.0) 25 0 IIA-10 2H2O 60 – 107 5 .2 (5.3) 27 0 IIA-11 3H2O 24 ...
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Cu(II) and Ni(II) complexes of n (2 hydroxybenzyl) amino acid ligands synthesis, structures, properties and catecholase activity
... IIA-2a 66 2- A -2- 2-3 [Cu2 (MeScp11 )2 (MeOH )2] .2MeOH, IIA-3a 68 2- A -2- 2 -4 [Cu2(OHScp11 )2( H2O )2] , IIA -4 70 2- A -2- 2-5 [Cu2(ClSch11 )2( MeOH )2] .2MeOH, IIA-6a 73 2- A -2- 2 -6 [{Cu2(Sch 12) 2 }2 Cu2(Sch 12) 2(H2O )2] .4H2O, ... 22 1 4- 4-1 IR spectra 22 1 4- 4 -2 Electronic spectra 22 2 4- 4-3 Thermogravimetric studies 22 2 4- 5 Summary 2 24 4 -6 Experimental 2 24 4 -6- 1 Synthesis of ligand 2 24 4 -6 -2 Synthesis of complex 22 5 viii ... IIB -2 [Cu2(Sam )2( H2O )2] .H2O xxiii IIB-3 [Cu2(Saes )2( H2O )2] .2H2O* IIB -4 [Cu2(Sae )2] .2H2O* IIB-5 [Cu2(Sae )2( DMF )2] .2DMF* IIC-1 [Cu2(Scp11 )2] .H2O* IIC -2 [Cu2(Scp11 )2( H2O )2] ·2Me2CO* H3Sas N- (2- hydroxybenzyl)-L-aspartic...
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Metal Complexes of 4′-Substituted-2,2′:6′,2″-Terpyridines in Supramolecular Chemistry
... 4 -Substituted2 ,2 :6 ,2 -Terpyridine Ligands 22 3 6. 1 Synthesis 2 24 6 .2 225 6. 3 Mass spectrometric characterisation 23 3 6 .4 Absorption spectroscopic characterisation 2 34 6. 5 Conclusion 23 5 6. 6 ... T4' T4 T2' N T2 N T2' T4 N N O N7 T2 T2' T3 N5 N N6 S2 N2 S3 N9 N1 T4' N8 N T4 N T2 N N7 N2 N6 N3 N10 N4 N5 N N T6 T6 4 - {2- [2- (Naphthalen-2ylmethoxy)ethoxy]ethoxy }2, 2′ :6 ,2 -terpyridine (L6) 4 - [2- (Naphthalen-2ylmethoxy)ethoxy ]2, 2′ :6 ,2 -terpyridine ... T2 T4 N T5 N5 T3' N10 N4 T3 T4 T4' N6 N3 O O N2 T4' T3' N10 S1 N8 N9 4 - {2- [2- (2Hydroxyethoxy)ethoxy]ethoxy }2, 2′ :6 ,2 -terpyridine (L3) 4 - [2- (2Hydroxyethoxy)ethoxy ]2, 2′ :6 ,2 -terpyridine (L2)...
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Chapter 098. Iron Deficiency and Other Hypoproliferative Anemias (Part 4) docx
... increase iron loss, or decrease iron intake or absorption can produce iron deficiency (Table 98 -2) Table 98 -2 Causes of Iron Deficiency Increased demand for iron and/ or hematopoiesis rapid growth ... red cell morphology and indices are normal Figure 98 -2 Laboratory studies in the evolution of iron deficiency Measurements of marrow iron stores, serum ferritin, and total iron- binding capacity ... prolonged iron- deficiency anemia, erythroid hyperplasia of the marrow develops, rather than hypoproliferation Causes of Iron Deficiency Conditions that increase demand for iron, increase iron loss,...
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Báo cáo y học: "Therapeutic effects of antibodies to tumor necrosis factor-α, interleukin-6 and cytotoxic T-lymphocyte antigen 4 immunoglobulin in mice with glucose-6-phosphate isomerase induced arthritis" docx
... immunoglobulin (CTLA-4Ig; on days and 12) ; (d) CTLA-4Ig (on days 12 and 16) ; and (e) or anti-IL -6 mAb just after the onset of arthritis (on day 8, on days and 12, or days 12 and 16; arrow) The mean ... in macrophages Nature 20 06, 44 3:998-10 02 19 Ruderman EM, Pope RM: Drug Insight: abatacept for the treatment of rheumatoid arthritis Nat Clin Pract Rheumatol 20 06, 2: 6 54- 66 0 20 Kremer JM, Westhovens ... M: Prevention and amelioration of collagen-induced arthritis by blockade of the CD28 costimulatory pathway: requirement for both B7-1 and B7 -2 Eur J Immunol 19 96, 26 :23 20 -23 28 23 Matsumoto I,...
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Tổng hợp, nghiên cứu cấu tạo và thăm dò hoạt tính sinh học các phức chất của Zn(II), Ni(II) và Cu(II) với n(4) phenyl thiosemicacbazon 2 benzoylpyriđin
... Letters 23 , pp 22 88 - 22 92 42 William Henderson, Clifton E.F (20 03), “Platinum (II) , palladium (II) and gold(III) complexes containing 1,1 ,4- trisubstituted dianionligands”, Inorganica Chimica Acta, 343 , ... Acta Part A, 63 , pp 66 9 - 6 72 22 El-Asmy A.A , Morsi M.A., and El - Shafei A.A (20 05), “Cobalt (II) , nickel (II) , copper (II) , zinc (II) and uranyl(VI) complexes of acetylacetone bis (4- phenylthiosemicarbazone)”, ... (20 05), “Structural and spectral studies of nickel (II) , copper (II) and cadmium (II) complexes of 3-furaldehyde thiosemicarbazone” Polyhedron, 24 , pp 327 3 32 34 Offiong O.E.,, S Martelli (19 92) ,...
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Structural and functional genomics study of singapore grouper iridovirus 2
... gi| 566 9 26 83 ORF 125 R gi| 566 927 62 ORF 140 R gi| 566 927 77 366 30. 86 Zgc:558 76 protein [Danio rerio] gi |41 9 46 787 26 66 3. 96 gi|983 743 9 2 745 5.31 21 775.95 gi |47 22 80 56 64 0 87.05 gi |21 35 741 5 51 969 .66 337 52. 51 ... gi| 566 92 64 4 ORF007L ORF012L SGIV protein 323 09 . 26 iTRAQ ratio (MO18/ MOctrl) 0.37 948 3 gi| 566 92 64 9 ORFs/ Protein name Protein MW (Da) 129 768 .6 0 .66 340 2 2 62 9 8 .25 0.579507 23 111. 84 0.57 360 1 gi| 566 9 26 83 ... nasutus] 0 .61 922 8 0 .6 52 344 0. 64 3 597 0. 64 3 597 gi|9 065 50 94 3 367 1.93 Zgc:558 76 protein [Danio rerio] gi |41 9 46 787 26 66 3. 96 splicing factor arginine/serine rich [Oryzias latipes] gi|983 743 9 2 745 5.31 40 S...
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Iron(III) and copper(II) complexes bearing 8 quinolinol with amino acids mixed ligands synthesis, characterization and antibacterial investigation
... 30 mm 29 mm 31 mm – 36 mm 30 mm mm Nil 29 mm 30 mm 25 mm 32 mm 20 mm 30 mm 29 mm Nil Nil Nil Nil 28 mm 32 mm 35 mm 24 mm 24 mm 26 mm 27 mm Nil Nil Nil Nil 33 mm 28 mm 24 mm 26 mm 32 mm 26 mm – ... 1 62 0 , 1 46 5, UV (nm); 340 , 40 4 ([Cu (HQ)(MET)]) 4d Yield 1 320 mg, 74. 2% , Anal Calc for C14H16CuN2O3S, C, 47 .25 ; H, 4. 53; N, 7.87; Found: C, 47 . 36; H, 4. 55; N, 7.83; IR (KBr, cmÀ1): 3500, 29 54, ... Found: C, 40 .10; H, 4. 36; N, 7.81; IR (KBr, cmÀ1): 3 741 , 160 0, 1 46 5, UV (nm) 338, 3 82 ([Fe (HQ)(MET)]Cl2H2O) 4b: Yield 41 0 mg, 19.5%, Anal Calc for C14H20ClFeN2O5S, C, 40 .07; H, 4. 80; N, 6. 67; Found:...
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Tài liệu Báo cáo khoa học: Insights into the interaction of human arginase II with substrate and manganese ions by site-directed mutagenesis and kinetic studies Alteration of substrate specificity by replacement of Asn149 with Asp docx
... 93 56 93 62 12 Ash DE (20 04) Structure and function of arginases J Nutr 1 34, 27 60 S 27 64 S 13 Morris SM (20 04) Recent advances in arginine metabolism Curr Opin Clin Nutr Metab Care 7, 45 –51 14 Kim ... [9, 24 ] However, the volume of the active site cleft was found to be larger for arginase II Moreover, the D2 32 (Od1)-Mn2+B FEBS Journal 27 2 (20 05) 45 40 45 48 ª 20 05 FEBS Interaction of arginase II ... (19 94) On the evolution of arginases and related enzymes J Mol Evol 39, 101–1 04 FEBS Journal 27 2 (20 05) 45 40 45 48 ª 20 05 FEBS Interaction of arginase II with substrate and manganese ions 21 Ahn...
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Báo cáo khoa học: NMR and molecular dynamics studies of an autoimmune myelin basic protein peptide and its antagonist Structural implications for the MHC II (I-Au)–peptide complex from docking calculations ppt
... P4, P6 and P9 anchoring pockets [N62a/N62a, Y13b/F11b (F11b points towards Y13b superimposed on DR2 and I-Au) and Y26b/Y26b form the P4 pockets; N62a/N62a, V65a/T65a and Y13b/F11b form the P6 ... S 76 N Q77 O R78 O S79 N S79 Oc Y9a N E74b Oe2 N62a Od1 Y61b OH Y66b OH N69a Od1 N69a Od1 ˚ van der Waals contacts ( 4. 5 A cut-off) < Q 74 Y9a, F11b, P13b, T28b, Y62b, E74b K75 F11b, E74b S 76 N62a, ... position 82 of 65 66 67 68 69 70 71 72 73 74 75 76 77 78 79 80 myelin basic protein 73– 86 for recruitment of V beta 8 .2+ T cells and encephalitogenicity in the Lewis rat J Immunol 1 62 , 829 – 8 36 Moscarello,...
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Báo cáo khoa học: Identification and functional expression of a second human b-galactoside a2,6-sialyltransferase, ST6Gal II docx
... significant similarities to hST6Gal I (X17 24 7 [22 ]) These sequences (GenBank accession numbers AB058780, BC00 866 0, AA3858 52; EST clones and AC108 049 , AC0 169 94, AC005 040 and NT_00 5 42 9; genomic clones) were ... (0. 52) b 0 100 (13. 86) b 1 .4 Asialofetuin Arylglycosides Oligosaccharides 66 83 5.3 8 .2 259 0 6 92 62 3 0 .6 0 .6 0 .4 72 2.5 0.7 87 120 a Rrepresents the remainder of the N-linked oligosaccharide chain ... ST6Gal I using Galb1–4GlcNAc [41 ] Ó FEBS 20 03 Characterization of the human ST6Gal II (Eur J Biochem 27 0) 957 Table Comparison of the acceptor substrate specificity of ST6Gal I and ST6Gal II...
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Báo cáo Y học: Distinct parts of minichromosome maintenance protein 2 associate with histone H3/H4 and RNA polymerase II holoenzyme pptx
... GST-TFIIS, GST-MCM2( 169 21 2)wt, GSTMCM2( 169 21 2)L192P/R193G, and GST-MCM2( 169 – 21 2)V203E/F204L proteins were expressed in BL21(LysS)DE3 cells and coupled to glutathione Sepharose 4B (Pharmacia) ... Figs and To test this hypothesis, we substituted conserved hydrophilic and hydrophobic residues in GST-MCM2( 169 21 2) as shown in Fig 6A GST, GST-MCM2( 169 21 2)V203E/ F204L, GST-MCM2( 169 21 2)L192P/R193G, ... full-length MCM2(1– 8 92) (lanes and 5), MCM2(1 23 0)V203E/F204L (lanes and 6) , MCM2(1 23 0)L192P/R193G (lanes and 7), and MCM2(1 23 0)wt (lanes and 8) were expressed in 29 3 cells and whole cell...
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Science and Golf II PROCEEDINGS OF THE 1994 WORLD SCIENTIFIC CONGRESS OF GOLF docx
... View CA 940 43 USA Tel 40 7 6 24 840 0 Fax 41 5 965 41 23 T.Melvin Spalding Sports Worldwide 42 5 Meadow Street Chicopee MA 01 021 0901 USA Tel 41 3 5 36 120 0 Fax 41 3 5 36 140 4 T.Meshizuka 3–11 2 40 4 Soshigaya ... Tel 6 14 29 2 20 01 Fax 6 14 29 2 71 62 W.G.Deddis University of Ulster Department of Surveying Newtownabbey County Antrim BT37 0QB Northern Ireland Tel 023 2 365 131 ext 25 65 Fax 023 2 3 62 8 26 R.Dewar ... Kingston MA 023 64 USA Tel 61 7 585 68 66 Fax 61 7 585 820 1 A.Smits Dept of Mechanical Engineering Princeton University PO Box CN 5 26 3 Princeton NJ 08 544 5 26 3 USA Tel 60 9 25 8 5117 Fax 60 9 25 8 22 76 S.K.Starrett...
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Báo cáo khoa học: Influence of divalent cations on the structural thermostability and thermal inactivation kinetics of class II xylose isomerases pdf
... 0.51 0 .61 0.5 34 0.739 0.771 0. 9 46 0.910 1. 02 0 . 42 0. 64 0 .22 0 .40 0 .41 0 .61 0.08 0 .20 0. 36 0 .49 0. 24 0. 52 0.57 0 .67 0. 02 0. 06 0 .48 0 .45 0.58 0 .48 0 .40 0. 34 0.59 0.57 0 .49 0.39 0 .48 0 .29 0 . 26 0.11 ... expðÀk1 tÞ k2 À k1 Metal Conc (mM) T (°C) A k1 (min)1) B k2 (min)1) b t1 ⁄ (min) v2 (· 10 )2) r2 Mn2+ Co2+ 99 1 02 1 04 1 06 96 99 1 02 1 04 92 96 99 1 02 87 90 100 100 0 . 42 8 0.518 0 .63 9 0 .66 8 0 .41 0 .43 0.51 ... 0.0 02 0.005 0.008 0.0 14 0.003 0.013 0. 020 0.038 0.001 0.011 0. 027 0.0 56 – – 0. 023 0.017 0.57 0 .48 0.39 0. 34 0.57 0.53 0 . 46 0. 36 0 .48 0 .29 0. 24 0.10 – – 0.55 0. 34 83 .2 6. 9 4. 2 2.3 59.5 14 5.8 2. 9...
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Báo cáo khoa học: Biochemical and structural analyses of a higher plant photosystem II supercomplex of a photosystem I-less mutant of barley pot
... 19 .4 20 .5 19.3 31.0 Zb63 CL Zb63 LL Zb63 HL WT CL Tot Car 50 .4 50 .6 52. 8 34. 6 5.9 6 .4 5 .4 4.9 4. 4 8.9 3.8 5 .6 4. 4 1 .6 2. 8 0.0 19 .2 19 .4 17.1 13 .4 7.1 2. 0 15.5 0.0 9.3 12. 5 8 .2 10.8 15.9 12 .4 22 .1 ... 8 64 . 9 133.0 Band 100.0 100.0 Band 41 2. 2 14. 3 Band 6+ 7 20 .9 89.9 Total Band Monomeric Lhc 50.5 Band Band Free pigments 37 .4 2 0 46 .7 8 72. 2 Band LHCII trimer C B6 B7 WT Zb63 WT Zb63 Band PSII core PsaA/B ... (20 00) 3D map of the plant photosys- 46 28 21 22 23 24 25 26 27 28 29 30 31 32 33 tem II supercomplex obtained by cryoelectron microscopy and single particle analysis Nat Struct Biol 7, 44 47 Nield...
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báo cáo hóa học:" Phase II trial of Modified Vaccinia Ankara (MVA) virus expressing 5T4 and high dose Interleukin-2 (IL-2) in patients with metastatic renal cell carcinoma" pot
... 1/1, 1 26 1/1770 1/9 56 1/1 ,45 2 < 1 /20 0,000 1/3 ,44 2 1 /2, 3 62 1 /2, 135 < 1 /20 0,000 1 /45 455 < 1 /20 0,000 1 /29 ,63 0 1 /61 9 1 /2, 1 12 1/1 ,44 5 1 /2, 901 1 /2, 3 16 1 /2, 68 5 1/10 ,21 6 1/5 ,40 5 1 /2, 335 1 /2, 273 < 1 /20 0,000 ... 1/1, 543 1/5 ,61 8 < 1 /20 0,000 1/ 868 < 1 /20 0,000 1/1 ,23 0 ND ND 1/ 62 9 1/5 ,20 8 1/870 1/1, 923 1/1,538 1/7, 143 1/1 ,29 9 1/11,3 64 1/10, 929 1 /4, 9 26 ND 1/10, 341 1/1 ,65 8 1/3,993 < 1 /20 0,000 1 /2, 62 9 1 /2, 0 84 ... 1/ 12, 821 < 1 /20 0,000 < 1 /20 0,000 < 1 /20 0,000 55 26 29 105 15 92 78 20 < 1 /20 0,000 1/19 ,23 1 < 1 /20 0,000 1/1,701 1 /21 ,27 7 1 /2, 113 < 1 /20 0,000 1/993 < 1 /20 0,000 1/ 12, 500 < 1 /20 0,000 1/11, 765 < 1 /20 0,000...
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Báo cáo hóa học: "A randomized phase II trial of mitoxantrone, estramustine and vinorelbine or bcl-2 modulation with 13-cis retinoic acid, interferon and paclitaxel in patients with metastatic castrate-resistant prostate cancer: ECOG 3899" pot
... Total (n = 63 ) n Percent Age Median 70 65 68 50-89 Range 45 -80 45 -89 Race White 30 94% 28 90% 58 Black 3% 10% 92% 6% Hispanic ECOG PS 3% 0% 2% 15 47 % 17 55% 32 51% 16 50% 12 39% 28 44 % 3% 6% 5% Measurable, ... Disease Present 14 44% 13 42 % 27 43 % Evaluable, Osseous Disease Present 28 88% 30 97% 58 92% Evaluable, Non-Osseous Disease Present Elevated PSA 13 32 41 % 100% 12 30 39% 97% 25 62 40 % 98% Lung 13% ... Bone 28 88% 29 94% 57 90% Bone Marrow 0% 3% 2% Pleura 3% 0% 2% Other Prior Treatment 11 34% 29 % 20 32% Orchiectomy 10 31% 23 % 17 27 % Prostatectomy 17 53% 15 48 % 32 51% Other Surgery 19 59% 20 65 %...
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Báo cáo sinh học: " Replicative homeostasis II: Influence of polymerase fidelity on RNA virus quasispecies biology: Implications for immune recognition, viral autoimmunity and other "virus receptor" diseases" pot
... RH, et al.: Vaccina- Page 16 of 20 (page number not for citation purposes) Virology Journal 20 05, 2: 70 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 tion of chimpanzees with plasmid ... http://www.virologyj.com/content /2/ 1/70 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 Bassett SE, Brasky KM, Lanford RE: Analysis of hepatitis C virusinoculated chimpanzees reveals unexpected clinical profiles ... (page number not for citation purposes) Virology Journal 20 05, 2: 70 58 59 60 61 62 63 64 65 66 67 68 69 70 71 72 73 74 75 76 77 78 79 80 81 82 Haldane J: Symposium sui fattori ecologi e genetici...
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