Thermodynamics and cement science

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Thermodynamics and cement science

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... hydrated Portland cement mortar after 28 days (PC 1, PC 2, PC3 (cement composition in [125]) and De Weerdt [123]) and 90 days (De Weerdt [124], [114]) and B) hydrated 65 Portland cement — 35%... R.J.Kirkpatrick and X.-D Cong, An Introduction to 27Al and 29Si NMR Spectroscopy of Cements and Concretes, in Application of NMR Spectroscopy to Cement Science, 55–75, Gordon and Breach Reading England [11]... material, and constant content by weight of cementitious material Thermodynamics applied to cement science and especially to cement hydration is very successful and valuable if used with caution Thus

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Mục lục

  • Thermodynamics and cement science

    • Introduction

    • Solubility data for cement hydrates

      • Available data

      • Determination of solubility data

        • Solubility data at standard conditions 25°C, 1bar

        • Solubility at other temperatures

          • Extrapolation based on measured solubility data

          • Extrapolation based on heat capacity, enthalpy or entropy data

          • Effect of pressure and crystal size on solubility

          • Maintenance of the thermodynamic database

          • Use of the thermodynamic approach

            • Saturation indexes

            • Phase diagrams

            • Stable hydrate assemblages

              • Influence of limestone

              • PC blended with SiO2 rich materials

              • Practical applications of thermodynamics applied to cement hydration

                • The sulpho-aluminate reactions

                • The carbo-aluminate reactions

                • The pozzolanic reaction

                • Conclusion

                • Acknowledgements

                • References

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