Chemistry of precious metals 1997 cotton

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Chemistry of precious metals 1997   cotton

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... include OsO3F2 ^^ OsOF5 18O0C On heating a 3:1 OsFJOsO4 mixture at 150-20O0C, a mixture OfOsOF5 and OsO4 is obtained that can be separated by using the greater volatility of OsOF5 OsO2F3 is a yellow-green... and terminal fluorines [28] Blue-green OsOF4 (m.p 8O0C) is a byproduct in the synthesis of OsOF5 and can also be made in small quantities by reduction of OsOF5 on a hot tungsten wire In the gas... A (trans) The shortness of the M-O bridge bonds is explained by the formation of two M—O—M threecentre MOs Figure 1.10 shows the formation of one of these by overlap of Figure 1.9 The dimeric

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  • 04136_fm.pdf

    • Front Matter

    • Preface

    • List of Abbreviations

    • Table of Contents

    • Index

  • 04136_toc.pdf

    • Front Matter

    • Table of Contents

    • 1. Ruthenium and Osmium

      • 1.1 Introduction

      • 1.2 The Elements and Uses

      • 1.3 Halides

      • 1.4 Oxides and Related Anions

      • 1.5 Other Binary Compounds

      • 1.6 Aqua Ions

      • 1.7 Compounds of Ruthenium(0)

      • 1.8 Compounds of Ruthenium(II) And (III)

      • 1.9 Complexes of Ruthenium(IV)

      • 1.10 Complexes of Osmium(0)

      • 1.11 Osmium Complexes in Oxidation States (II-IV)

      • 1.12 Compounds in High Oxidation States

      • 1.13 Simple Alkyls and Aryls

    • 2. Rhodium and Iridium

      • 2.1 Introduction

      • 2.2 The Elements and Uses

      • 2.3 Halides and Halide Complexes

      • 2.4 Oxides, Hydrides and Other Binary Compounds

      • 2.5 Aqua Ions and Simple Salts

      • 2.6 Compounds of Rhodium(0)

      • 2.7 Compounds of Rhodium(I)

      • 2.8 Rhodium(II) Complexes

      • 2.9 Rhodium(III) Complexes

      • 2.10 Iridium(I) Complexes

      • 2.11 Dioxygen Complexes

      • 2.12 Iridium(II) Complexes

      • 2.13 Iridium(III) Complexes

      • 2.14 Iridium(IV) Complexes

      • 2.15 Iridium(V) Complexes

      • 2.16 Nitrosyls of Iridium and Rhodium

      • 2.17 Simple Alkyls and Aryls of Iridium and Rhodium

    • 3. Palladium and Platinum

      • 3.1 Introduction

      • 3.2 The Elements and Uses

      • 3.3 Halides

      • 3.4 Other Binary Complexes

      • 3.5 Aqua Ions

      • 3.6 Palladium(0) and Platinum(0) Compounds

      • 3.7 Palladium(I) and Platinum(I) Compounds

      • 3.8 Complexes of Palladium(II) and Platinum(II)

      • 3.9 Palladium(III) and Platinum(III)

      • 3.10 Complexes of Platinum(IV)

      • 3.11 Complexes of Palladium(IV)

      • 3.12 The sigma-Bonded Organometallics of Palladium(IV) and Platinum(IV)

      • 3.13 Anti-Tumour Activity of Platinum Complexes

      • 3.14 Bond Lengths in Palladium and Platinum Analogues

    • 4. Silver and Gold

      • 4.1 Introduction

      • 4.2 The Elements and Uses

      • 4.3 Halides

      • 4.4 Oxides and Other Binary Compounds

      • 4.5 Aqua Ions

      • 4.6 Silver(I) Complexes

      • 4.7 Silver(II) Complexes

      • 4.8 Silver(III) Complexes

      • 4.9 Gold(-I) Complexes

      • 4.10 Gold(I) Complexes

      • 4.11 Gold(II) Complexes

      • 4.12 Gold(III) Complexes

      • 4.13 Gold(IV) Complexes

      • 4.14 Gold(V) Complexes

      • 4.15 Organometallic Compounds of Silver

      • 4.16 Organometallic Compounds of Gold

      • 4.17 Gold Cluster Complexes

      • 4.18 Relativistic Effects in Gold Chemistry

      • 4.19 Aurophilicity

      • 4.20 Silver and Gold Compounds in Medicine

      • 4.21 Mossbauer Spectroscopy of Gold Compounds

    • References

      • Chapter 1

      • Chapter 2

      • Chapter 3

      • Chapter 4

    • Index

  • 04136_01a.pdf

    • Front Matter

    • Table of Contents

    • 1. Ruthenium and Osmium

      • 1.1 Introduction

      • 1.2 The Elements and Uses

        • 1.2.1 Extraction

      • 1.3 Halides

        • 1.3.1 Ruthenium Halides

        • 1.3.2 Osmium Halides

        • 1.3.3 Oxyhalides

        • 1.3.4 Halide Complexes

        • 1.3.5 'Ruthenium Blues'

        • 1.3.6 Oxyhalide Complexes

      • 1.4 Oxides and Related Anions

        • 1.4.1 Anions

      • 1.5 Other Binary Compounds

      • 1.6 Aqua Ions

      • 1.7 Compounds of Ruthenium(0)

      • 1.8 Compounds of Ruthenium(II) And (III)

        • 1.8.1 Ammine Complexes

        • 1.8.2 Tertiary Phosphine Complexes

        • 1.8.3 Carboxylate Complexes

        • 1.8.4 Sulphide and Sulphoxide Complexes

        • 1.8.5 Nitrosyl Complexes

        • 1.8.6 Porphyrin Complexes

        • 1.8.7 EDTA Complexes

        • 1.8.8 Other Complexes of Ruthenium

      • 1.9 Complexes of Ruthenium(IV)

      • 1.10 Complexes of Osmium(0)

      • 1.11 Osmium Complexes in Oxidation States (II-IV)

        • 1.11.1 Ammine Complexes

        • 1.11.2 Tertiary Phosphine Complexes

        • 1.11.3 Carboxylate Complexes

        • 1.11.4 Nitrosyl Complexes

        • 1.11.5 Other Osmium Complexes

      • 1.12 Compounds in High Oxidation States

        • 1.12.1 Compounds of the MO2(2+) Groups

        • 1.12.2 Nitride Complexes

        • 1.12.3 Imides

      • 1.13 Simple Alkyls and Aryls

    • Index

  • 04136_01b.pdf

    • Front Matter

    • Table of Contents

    • 1. Ruthenium and Osmium

      • 1.1 Introduction

      • 1.2 The Elements and Uses

        • 1.2.1 Extraction

      • 1.3 Halides

        • 1.3.1 Ruthenium Halides

        • 1.3.2 Osmium Halides

        • 1.3.3 Oxyhalides

        • 1.3.4 Halide Complexes

        • 1.3.5 'Ruthenium Blues'

        • 1.3.6 Oxyhalide Complexes

      • 1.4 Oxides and Related Anions

        • 1.4.1 Anions

      • 1.5 Other Binary Compounds

      • 1.6 Aqua Ions

      • 1.7 Compounds of Ruthenium(0)

      • 1.8 Compounds of Ruthenium(II) And (III)

        • 1.8.1 Ammine Complexes

        • 1.8.2 Tertiary Phosphine Complexes

        • 1.8.3 Carboxylate Complexes

        • 1.8.4 Sulphide and Sulphoxide Complexes

        • 1.8.5 Nitrosyl Complexes

        • 1.8.6 Porphyrin Complexes

        • 1.8.7 EDTA Complexes

        • 1.8.8 Other Complexes of Ruthenium

      • 1.9 Complexes of Ruthenium(IV)

      • 1.10 Complexes of Osmium(0)

      • 1.11 Osmium Complexes in Oxidation States (II-IV)

        • 1.11.1 Ammine Complexes

        • 1.11.2 Tertiary Phosphine Complexes

        • 1.11.3 Carboxylate Complexes

        • 1.11.4 Nitrosyl Complexes

        • 1.11.5 Other Osmium Complexes

      • 1.12 Compounds in High Oxidation States

        • 1.12.1 Compounds of the MO2(2+) Groups

        • 1.12.2 Nitride Complexes

        • 1.12.3 Imides

      • 1.13 Simple Alkyls and Aryls

    • Index

  • 04136_01c.pdf

    • Front Matter

    • Table of Contents

    • 1. Ruthenium and Osmium

      • 1.1 Introduction

      • 1.2 The Elements and Uses

        • 1.2.1 Extraction

      • 1.3 Halides

        • 1.3.1 Ruthenium Halides

        • 1.3.2 Osmium Halides

        • 1.3.3 Oxyhalides

        • 1.3.4 Halide Complexes

        • 1.3.5 'Ruthenium Blues'

        • 1.3.6 Oxyhalide Complexes

      • 1.4 Oxides and Related Anions

        • 1.4.1 Anions

      • 1.5 Other Binary Compounds

      • 1.6 Aqua Ions

      • 1.7 Compounds of Ruthenium(0)

      • 1.8 Compounds of Ruthenium(II) And (III)

        • 1.8.1 Ammine Complexes

        • 1.8.2 Tertiary Phosphine Complexes

        • 1.8.3 Carboxylate Complexes

        • 1.8.4 Sulphide and Sulphoxide Complexes

        • 1.8.5 Nitrosyl Complexes

        • 1.8.6 Porphyrin Complexes

        • 1.8.7 EDTA Complexes

        • 1.8.8 Other Complexes of Ruthenium

      • 1.9 Complexes of Ruthenium(IV)

      • 1.10 Complexes of Osmium(0)

      • 1.11 Osmium Complexes in Oxidation States (II-IV)

        • 1.11.1 Ammine Complexes

        • 1.11.2 Tertiary Phosphine Complexes

        • 1.11.3 Carboxylate Complexes

        • 1.11.4 Nitrosyl Complexes

        • 1.11.5 Other Osmium Complexes

      • 1.12 Compounds in High Oxidation States

        • 1.12.1 Compounds of the MO2(2+) Groups

        • 1.12.2 Nitride Complexes

        • 1.12.3 Imides

      • 1.13 Simple Alkyls and Aryls

    • Index

  • 04136_02a.pdf

    • Front Matter

    • Table of Contents

    • 2. Rhodium and Iridium

      • 2.1 Introduction

      • 2.2 The Elements and Uses

        • 2.2.1 Extraction

      • 2.3 Halides and Halide Complexes

        • 2.3.1 Rhodium Halides

        • 2.3.2 Iridium Halides

        • 2.3.3 Halometallates

      • 2.4 Oxides, Hydrides and Other Binary Compounds

      • 2.5 Aqua Ions and Simple Salts

      • 2.6 Compounds of Rhodium(0)

      • 2.7 Compounds of Rhodium(I)

        • 2.7.1 Tertiary Phosphine Complexes

        • 2.7.2 Carbonyl Complexes

        • 2.7.3 Alkene Complexes

        • 2.7.4 Isocyanide Complexes

      • 2.8 Rhodium(II) Complexes

        • 2.8.1 Phosphine Complexes

        • 2.8.2 Dimers

        • 2.8.3 Other Complexes

      • 2.9 Rhodium(III) Complexes

        • 2.9.1 Complexes of O-Donors

        • 2.9.2 Complexes of Ammines

        • 2.9.3 Complexes of Other N-Donors

        • 2.9.4 Complexes of S-Donors

        • 2.9.5 Tertiary Phosphine Complexes

      • 2.10 Iridium(I) Complexes

        • 2.10.1 Tertiary Phosphine Complexes

        • 2.10.2 Vaska's Compound

      • 2.11 Dioxygen Complexes

      • 2.12 Iridium(II) Complexes

      • 2.13 Iridium(III) Complexes

        • 2.13.1 Complexes of Ammines

        • 2.13.2 Complexes of S-Donors

        • 2.13.3 Tertiary Phosphine and Arsine Complexes

        • 2.13.4 Hydride Complexes

        • 2.13.5 Case Study of Dimethylphenylphosphine Complexes

      • 2.14 Iridium(IV) Complexes

      • 2.15 Iridium(V) Complexes

      • 2.16 Nitrosyls of Iridium and Rhodium

      • 2.17 Simple Alkyls and Aryls of Iridium and Rhodium

    • Index

  • 04136_02b.pdf

    • Front Matter

    • Table of Contents

    • 2. Rhodium and Iridium

      • 2.1 Introduction

      • 2.2 The Elements and Uses

        • 2.2.1 Extraction

      • 2.3 Halides and Halide Complexes

        • 2.3.1 Rhodium Halides

        • 2.3.2 Iridium Halides

        • 2.3.3 Halometallates

      • 2.4 Oxides, Hydrides and Other Binary Compounds

      • 2.5 Aqua Ions and Simple Salts

      • 2.6 Compounds of Rhodium(0)

      • 2.7 Compounds of Rhodium(I)

        • 2.7.1 Tertiary Phosphine Complexes

        • 2.7.2 Carbonyl Complexes

        • 2.7.3 Alkene Complexes

        • 2.7.4 Isocyanide Complexes

      • 2.8 Rhodium(II) Complexes

        • 2.8.1 Phosphine Complexes

        • 2.8.2 Dimers

        • 2.8.3 Other Complexes

      • 2.9 Rhodium(III) Complexes

        • 2.9.1 Complexes of O-Donors

        • 2.9.2 Complexes of Ammines

        • 2.9.3 Complexes of Other N-Donors

        • 2.9.4 Complexes of S-Donors

        • 2.9.5 Tertiary Phosphine Complexes

      • 2.10 Iridium(I) Complexes

        • 2.10.1 Tertiary Phosphine Complexes

        • 2.10.2 Vaska's Compound

      • 2.11 Dioxygen Complexes

      • 2.12 Iridium(II) Complexes

      • 2.13 Iridium(III) Complexes

        • 2.13.1 Complexes of Ammines

        • 2.13.2 Complexes of S-Donors

        • 2.13.3 Tertiary Phosphine and Arsine Complexes

        • 2.13.4 Hydride Complexes

        • 2.13.5 Case Study of Dimethylphenylphosphine Complexes

      • 2.14 Iridium(IV) Complexes

      • 2.15 Iridium(V) Complexes

      • 2.16 Nitrosyls of Iridium and Rhodium

      • 2.17 Simple Alkyls and Aryls of Iridium and Rhodium

    • Index

  • 04136_02c.pdf

    • Front Matter

    • Table of Contents

    • 2. Rhodium and Iridium

      • 2.1 Introduction

      • 2.2 The Elements and Uses

        • 2.2.1 Extraction

      • 2.3 Halides and Halide Complexes

        • 2.3.1 Rhodium Halides

        • 2.3.2 Iridium Halides

        • 2.3.3 Halometallates

      • 2.4 Oxides, Hydrides and Other Binary Compounds

      • 2.5 Aqua Ions and Simple Salts

      • 2.6 Compounds of Rhodium(0)

      • 2.7 Compounds of Rhodium(I)

        • 2.7.1 Tertiary Phosphine Complexes

        • 2.7.2 Carbonyl Complexes

        • 2.7.3 Alkene Complexes

        • 2.7.4 Isocyanide Complexes

      • 2.8 Rhodium(II) Complexes

        • 2.8.1 Phosphine Complexes

        • 2.8.2 Dimers

        • 2.8.3 Other Complexes

      • 2.9 Rhodium(III) Complexes

        • 2.9.1 Complexes of O-Donors

        • 2.9.2 Complexes of Ammines

        • 2.9.3 Complexes of Other N-Donors

        • 2.9.4 Complexes of S-Donors

        • 2.9.5 Tertiary Phosphine Complexes

      • 2.10 Iridium(I) Complexes

        • 2.10.1 Tertiary Phosphine Complexes

        • 2.10.2 Vaska's Compound

      • 2.11 Dioxygen Complexes

      • 2.12 Iridium(II) Complexes

      • 2.13 Iridium(III) Complexes

        • 2.13.1 Complexes of Ammines

        • 2.13.2 Complexes of S-Donors

        • 2.13.3 Tertiary Phosphine and Arsine Complexes

        • 2.13.4 Hydride Complexes

        • 2.13.5 Case Study of Dimethylphenylphosphine Complexes

      • 2.14 Iridium(IV) Complexes

      • 2.15 Iridium(V) Complexes

      • 2.16 Nitrosyls of Iridium and Rhodium

      • 2.17 Simple Alkyls and Aryls of Iridium and Rhodium

    • Index

  • 04136_03a.pdf

    • Front Matter

    • Table of Contents

    • 3. Palladium and Platinum

      • 3.1 Introduction

      • 3.2 The Elements and Uses

        • 3.2.1 Extraction

      • 3.3 Halides

        • 3.3.1 Palladium Halides

        • 3.3.2 Platinum Halides

        • 3.3.3 Halide Complexes

      • 3.4 Other Binary Complexes

      • 3.5 Aqua Ions

      • 3.6 Palladium(0) and Platinum(0) Compounds

        • 3.6.1 Tertiary Phosphine Complexes

        • 3.6.2 Reactions of Pt(PPh3)n and Related Species

        • 3.6.3 Carbonyl Complexes

        • 3.6.4 Carbonyl Clusters

        • 3.6.5 Isocyanide Complexes

      • 3.7 Palladium(I) and Platinum(I) Compounds

        • 3.7.1 Phosphine Complexes

        • 3.7.2 Isocyanide Complexes

      • 3.8 Complexes of Palladium(II) and Platinum(II)

        • 3.8.1 Complexes of O-Donors

        • 3.8.2 Complexes of N-Donors

        • 3.8.3 Tertiary Phosphine Complexes

        • 3.8.4 Complexes of C-Donors

        • 3.8.5 Complexes of S-Donors

        • 3.8.6 Complexes of Ambidentate Ligands

        • 3.8.7 Stability of cis- and trans-Isomers

        • 3.8.8 Five-Coordinate Compounds

        • 3.8.9 The trans-Effect

        • 3.8.10 Structural Evidence for trans-Influence

        • 3.8.11 Spectroscopic Evidence for trans-Influence

      • 3.9 Palladium(III) and Platinum(III) Compounds

      • 3.10 Complexes of Platinum(IV)

        • 3.10.1 Complexes of N-Donors

        • 3.10.2 Tertiary Phosphine Complexes

        • 3.10.3 Complexes of S-Donors

        • 3.10.4 Application of the trans-Effect to Synthesis of Platinum(IV) Complexes

        • 3.10.5 The trans-Influence in Some Platinum(IV) Compounds

      • 3.11 Complexes of Palladium(IV)

      • 3.12 The sigma Bonded Organometallics of Palladium(IV) and Platinum(IV)

        • 3.12.1 Reductive Elimination Reactions

      • 3.13 Anti-Tumour Activity of Platinum Complexes

      • 3.14 Bond Lengths in Palladium and Platinum Analogues

    • Index

  • 04136_03b.pdf

    • Front Matter

    • Table of Contents

    • 3. Palladium and Platinum

      • 3.1 Introduction

      • 3.2 The Elements and Uses

        • 3.2.1 Extraction

      • 3.3 Halides

        • 3.3.1 Palladium Halides

        • 3.3.2 Platinum Halides

        • 3.3.3 Halide Complexes

      • 3.4 Other Binary Complexes

      • 3.5 Aqua Ions

      • 3.6 Palladium(0) and Platinum(0) Compounds

        • 3.6.1 Tertiary Phosphine Complexes

        • 3.6.2 Reactions of Pt(PPh3)n and Related Species

        • 3.6.3 Carbonyl Complexes

        • 3.6.4 Carbonyl Clusters

        • 3.6.5 Isocyanide Complexes

      • 3.7 Palladium(I) and Platinum(I) Compounds

        • 3.7.1 Phosphine Complexes

        • 3.7.2 Isocyanide Complexes

      • 3.8 Complexes of Palladium(II) and Platinum(II)

        • 3.8.1 Complexes of O-Donors

        • 3.8.2 Complexes of N-Donors

        • 3.8.3 Tertiary Phosphine Complexes

        • 3.8.4 Complexes of C-Donors

        • 3.8.5 Complexes of S-Donors

        • 3.8.6 Complexes of Ambidentate Ligands

        • 3.8.7 Stability of cis- and trans-Isomers

        • 3.8.8 Five-Coordinate Compounds

        • 3.8.9 The trans-Effect

        • 3.8.10 Structural Evidence for trans-Influence

        • 3.8.11 Spectroscopic Evidence for trans-Influence

      • 3.9 Palladium(III) and Platinum(III)

      • 3.10 Complexes of Platinum(IV)

        • 3.10.1 Complexes of N-Donors

        • 3.10.2 Tertiary Phosphine Complexes

        • 3.10.3 Complexes of S-Donors

        • 3.10.4 Application of the trans-Effect to Synthesis of Platinum(IV) Complexes

        • 3.10.5 The trans-Influence in Some Platinum(IV) Compounds

      • 3.11 Complexes of Palladium(IV)

      • 3.12 The sigma Bonded Organometallics of Palladium(IV) and Platinum(IV)

        • 3.12.1 Reductive Elimination Reactions

      • 3.13 Anti-Tumour Activity of Platinum Complexes

      • 3.14 Bond Lengths in Palladium and Platinum Analogues

    • Index

  • 04136_03c.pdf

    • Front Matter

    • Table of Contents

    • 3. Palladium and Platinum

      • 3.1 Introduction

      • 3.2 The Elements and Uses

        • 3.2.1 Extraction

      • 3.3 Halides

        • 3.3.1 Palladium Halides

        • 3.3.2 Platinum Halides

        • 3.3.3 Halide Complexes

      • 3.4 Other Binary Complexes

      • 3.5 Aqua Ions

      • 3.6 Palladium(0) and Platinum(0) Compounds

        • 3.6.1 Tertiary Phosphine Complexes

        • 3.6.2 Reactions of Pt(PPh3)n and Related Species

        • 3.6.3 Carbonyl Complexes

        • 3.6.4 Carbonyl Clusters

        • 3.6.5 Isocyanide Complexes

      • 3.7 Palladium(I) and Platinum(I) Compounds

        • 3.7.1 Phosphine Complexes

        • 3.7.2 Isocyanide Complexes

      • 3.8 Complexes of Palladium(II) and Platinum(II)

        • 3.8.1 Complexes of O-Donors

        • 3.8.2 Complexes of N-Donors

        • 3.8.3 Tertiary Phosphine Complexes

        • 3.8.4 Complexes of C-Donors

        • 3.8.5 Complexes of S-Donors

        • 3.8.6 Complexes of Ambidentate Ligands

        • 3.8.7 Stability of cis- and trans-Isomers

        • 3.8.8 Five-Coordinate Compounds

        • 3.8.9 The trans-Effect

        • 3.8.10 Structural Evidence for trans-Influence

        • 3.8.11 Spectroscopic Evidence for trans-Influence

      • 3.9 Palladium(III) and Platinum(III) Compounds

      • 3.10 Complexes of Platinum(IV)

        • 3.10.1 Complexes of N-Donors

        • 3.10.2 Tertiary Phosphine Complexes

        • 3.10.3 Complexes of S-Donors

        • 3.10.4 Application of the trans-Effect to Synthesis of Platinum(IV) Complexes

        • 3.10.5 The trans-Influence in Some Platinum(IV) Compounds

      • 3.11 Complexes of Palladium(IV)

      • 3.12 The sigma Bonded Organometallics of Palladium(IV) and Platinum(IV)

        • 3.12.1 Reductive Elimination Reactions

      • 3.13 Anti-Tumour Activity of Platinum Complexes

      • 3.14 Bond Lengths in Palladium and Platinum Analogues

    • Index

  • 04136_04a.pdf

    • Front Matter

    • Table of Contents

    • 4. Silver and Gold

      • 4.1 Introduction

      • 4.2 The Elements and Uses

        • 4.2.1 Extraction

        • 4.2.2 Gold Plating and Other Methods of Gold Deposition

      • 4.3 Halides

        • 4.3.1 Silver Halides

        • 4.3.2 Gold Halides

      • 4.4 Oxides and Other Binary Compounds

      • 4.5 Aqua Ions

      • 4.6 Silver(I) Complexes

        • 4.6.1 Complexes of O-Donors

        • 4.6.2 Complexes of N-Donors

        • 4.6.3 Tertiary Phosphine and Arsine Complexes

        • 4.6.4 Complexes of Halogen-Donors

        • 4.6.5 Complexes of C-Donors

        • 4.6.6 Complexes of S-Donors

      • 4.7 Silver(II) Complexes

      • 4.8 Silver(III) Complexes

      • 4.9 Gold(-I) Complexes

      • 4.10 Gold(I) Complexes

        • 4.10.1 Complexes of O-Donors

        • 4.10.2 Complexes of N-Donors

        • 4.10.3 Tertiary Phosphine and Arsine Complexes

        • 4.10.4 Complexes of Halogen-Donors

        • 4.10.5 Complexes of C-Donors

        • 4.10.6 Complexes of S-Donors

        • 4.10.7 MO Schemes for 2-Coordinate Gold(I) Complexes

      • 4.11 Gold(II) Complexes

      • 4.12 Gold(III) Complexes

        • 4.12.1 Complexes of Halogens

        • 4.12.2 Complexes of N-Donors

        • 4.12.3 Tertiary Phosphine and Arsine Complexes

        • 4.12.4 Other Complexes

        • 4.12.5 Coordination Numbers and Gold(III)

        • 4.12.6 The trans-Effect and trans-Influence

      • 4.13 Gold(IV) Complexes

      • 4.14 Gold(V) Complexes

      • 4.15 Organometallic Compounds of Silver

        • 4.15.1 Complexes of Unsaturated Hydrocarbons

      • 4.16 Organometallic Compounds of Gold

        • 4.16.1 Gold(I) Complexes

        • 4.16.2 Gold(III) Complexes

      • 4.17 Gold Cluster Complexes

      • 4.18 Relativistic Effects in Gold Chemistry

      • 4.19 Aurophilicity

      • 4.20 Silver and Gold Compounds in Medicine

      • 4.21 Mossbauer Spectroscopy of Gold Compounds

    • Index

  • 04136_04c.pdf

    • Front Matter

    • Table of Contents

    • 4. Silver and Gold

      • 4.1 Introduction

      • 4.2 The Elements and Uses

        • 4.2.1 Extraction

        • 4.2.2 Gold Plating and Other Methods of Gold Deposition

      • 4.3 Halides

        • 4.3.1 Silver Halides

        • 4.3.2 Gold Halides

      • 4.4 Oxides and Other Binary Compounds

      • 4.5 Aqua Ions

      • 4.6 Silver(I) Complexes

        • 4.6.1 Complexes of O-Donors

        • 4.6.2 Complexes of N-Donors

        • 4.6.3 Tertiary Phosphine and Arsine Complexes

        • 4.6.4 Complexes of Halogen-Donors

        • 4.6.5 Complexes of C-Donors

        • 4.6.6 Complexes of S-Donors

      • 4.7 Silver(II) Complexes

      • 4.8 Silver(III) Complexes

      • 4.9 Gold(-I) Complexes

      • 4.10 Gold(I) Complexes

        • 4.10.1 Complexes of O-Donors

        • 4.10.2 Complexes of N-Donors

        • 4.10.3 Tertiary Phosphine and Arsine Complexes

        • 4.10.4 Complexes of Halogen-Donors

        • 4.10.5 Complexes of C-Donors

        • 4.10.6 Complexes of S-Donors

        • 4.10.7 MO Schemes for 2-Coordinate Gold(I) Complexes

      • 4.11 Gold(II) Complexes

      • 4.12 Gold(III) Complexes

        • 4.12.1 Complexes of Halogens

        • 4.12.2 Complexes of N-Donors

        • 4.12.3 Tertiary Phosphine and Arsine Complexes

        • 4.12.4 Other Complexes

        • 4.12.5 Coordination Numbers and Gold(III)

        • 4.12.6 The trans-Effect and trans-Influence

      • 4.13 Gold(IV) Complexes

      • 4.14 Gold(V) Complexes

      • 4.15 Organometallic Compounds of Silver

        • 4.15.1 Complexes of Unsaturated Hydrocarbons

      • 4.16 Organometallic Compounds of Gold

        • 4.16.1 Gold(I) Complexes

        • 4.16.2 Gold(III) Complexes

      • 4.17 Gold Cluster Complexes

      • 4.18 Relativistic Effects in Gold Chemistry

      • 4.19 Aurophilicity

      • 4.20 Silver and Gold Compounds in Medicine

      • 4.21 Mossbauer Spectroscopy of Gold Compounds

    • Index

  • 04136_refa.pdf

    • Front Matter

    • Table of Contents

    • References

      • Chapter 1

      • Chapter 2

      • Chapter 3

      • Chapter 4

    • Index

  • 04136_indx.pdf

    • Front Matter

    • Table of Contents

    • Index

      • Gold

      • Iridium

      • Osmium

      • Palladium

      • Platinum

      • Rhodium

      • Ruthenium

      • Silver

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