Chemistry of precious metals 1997 cotton

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Chemistry of precious metals 1997   cotton

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... include OsO3F2 ^^ OsOF5 18O0C On heating a 3:1 OsFJOsO4 mixture at 150-20O0C, a mixture OfOsOF5 and OsO4 is obtained that can be separated by using the greater volatility of OsOF5 OsO2F3 is a yellow-green... and terminal fluorines [28] Blue-green OsOF4 (m.p 8O0C) is a byproduct in the synthesis of OsOF5 and can also be made in small quantities by reduction of OsOF5 on a hot tungsten wire In the gas... A (trans) The shortness of the M-O bridge bonds is explained by the formation of two M—O—M threecentre MOs Figure 1.10 shows the formation of one of these by overlap of Figure 1.9 The dimeric

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  • 04136_fm.pdf

    • Front Matter

    • Preface

    • List of Abbreviations

    • Table of Contents

    • Index

    • 04136_toc.pdf

      • Front Matter

      • Table of Contents

      • 1. Ruthenium and Osmium

        • 1.1 Introduction

        • 1.2 The Elements and Uses

        • 1.3 Halides

        • 1.4 Oxides and Related Anions

        • 1.5 Other Binary Compounds

        • 1.6 Aqua Ions

        • 1.7 Compounds of Ruthenium(0)

        • 1.8 Compounds of Ruthenium(II) And (III)

        • 1.9 Complexes of Ruthenium(IV)

        • 1.10 Complexes of Osmium(0)

        • 1.11 Osmium Complexes in Oxidation States (II-IV)

        • 1.12 Compounds in High Oxidation States

        • 1.13 Simple Alkyls and Aryls

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