Progress in Inorganic Chemistry Volume 57 Advisory Board JACQUELINE K BARTON CALIFORNIA INSTITUTE OF TECHNOLOGY, PASADENA, CALIFORNIA JAMES P COLLMAN STANFORD UNIVERSITY, STANFORD, CALIFORNIA ALAN H COWLEY UNIVERSITY OF TEXAS, AUSTIN, TEXAS RICHARD H HOLM HARVARD UNIVERSITY, CAMBRIDGE, MASSACHUSETTS EIICHI KIMURA SHIZUOKA UNIVERSITY, SHIZUOKA, JAPAN NATHAN S LEWIS CALIFORNIA INSTITUTE OF TECHNOLOGY, PASADENA, CALIFORNIA STEPHEN J LIPPARD MASSACHUSETTS INSTITUTE OF TECHNOLOGY, CAMBRIDGE, MASSACHUSETTS TOBIN J MARKS NORTHWESTERN UNIVERSITY, EVANSTON, ILLINOIS KARL WIEGHARDT ă LHEIM, GERMANY MAX-PLANCK-INSTITUT, MU PROGRESS IN INORGANIC CHEMISTRY Edited by KENNETH D KARLIN DEPARTMENT OF CHEMISTRY JOHNS HOPKINS UNIVERSITY BALTIMORE, MARYLAND VOLUME 57 Copyright Ó 2012 by John Wiley & Sons, Inc All rights reserved Published by John Wiley & Sons, Inc., Hoboken, New Jersey Published simultaneously in Canada No part of this publication may be reproduced, stored in a retrieval system, or transmitted in any form or by any means, electronic, mechanical, photocopying, recording, scanning, or otherwise, except as permitted under Section 107 or 108 of the 1976 United States Copyright Act, without either the prior written permission of the Publisher, or authorization through payment of the appropriate per-copy fee to the Copyright Clearance Center, Inc., 222 Rosewood Drive, Danvers, MA 01923, (978) 750-8400, fax (978) 750-4470, or on the web at www.copyright.com Requests to the Publisher for permission should be addressed to the Permissions Department, John Wiley & Sons, Inc., 111 River Street, Hoboken, NJ 07030, (201) 748-6011, fax (201) 748-6008, or online at http://www.wiley.com/go/permission Limit of Liability/Disclaimer of Warranty: While the publisher and author have used their best efforts in preparing this book, they make no representations or warranties with respect to the accuracy or completeness of the contents of this book and specifically disclaim any implied warranties of merchantability or fitness for a particular purpose No warranty may be created or extended by sales representatives or written sales materials The advice and strategies contained herein may not be suitable for your situation You should consult with a professional where appropriate Neither the publisher nor author shall be liable for any loss of profit or any other commercial damages, including but not limited to special, incidental, consequential, or other damages For general information on our other products and services or for technical support, please contact our Customer Care Department within the United States at (800) 762-2974, outside the United States at (317) 572-3993 or fax (317) 572-4002 Wiley also publishes its books in a variety of electronic formats Some content that appears in print may not be available in electronic formats For more information about Wiley products, visit our web site at www.wiley.com Library of Congress Catalog Card Number: 59-13035 ISBN 978-1-118-01063-1 Printed in the United States of America oBook ISBN: 978-1-118-14823-5 ePDF ISBN: 978-1-118-14868-6 ePub ISBN: 978-1-118-14820-4 eMobi ISBN: 978-1-118-14867-9 10 Contents Chapter Chapter Chapter Chapter Chapter Mechanisms of Water Oxidation Catalyzed by Ruthenium Coordination Complexes AURORA E CLARK and JAMES K HURST Biomimetic and Nonbiological Dinuclear Mxỵ Complex-Catalyzed Alcoholysis Reactions of Phosphoryl Transfer Reactions R STAN BROWN 55 Photoactivated DNA Cleavage and Anticancer Activity of 3d Metal Complexes AKHIL R CHAKRAVARTY and MITHUN ROY 119 Design and Evolution of Artificial Metalloenzymes: Biomimetic Aspects MARC CREUS and THOMAS R WARD 203 Functionalization of Fluorinated Aromatics by Nickel-Mediated C – H and C – F Bond Oxidative Addition: Prospects for the Synthesis of Fluorine-Containing Pharmaceuticals SAMUEL A JOHNSON, JILLIAN A HATNEAN, and MEGHAN E DOSTER 255 Chapter DNA Based Metal Catalysis JENS OELERICH and GERARD ROELFES Chapter Metallo-b-lactamases and Their Synthetic Mimics: Structure, Function, and Catalytic Mechanism MUTHAIAH UMAYAL, A TAMILSELVI, and GOVINDASAMY MUGESH v 353 395 vi Chapter CONTENTS A New Class of Nanostructured Inorganic–Organic Hybrid Semiconductors Based on II–VI Binary Compounds JING LI and RUIBO ZHANG 445 Oxygen Evolution Reaction Chemistry of Oxide-Based Electrodes YOGESH SURENDRANATH and DANIEL G NOCERA 505 Subject Index Cumulative Index 561 593 Chapter Chapter 1, Figure The DFT predicted mechanism for water oxidation catalyzed by [Ru2(OH)2(3,6Bu2Q)(btpyan)]2ỵ ion [3,6-Bu2Q ẳ 3,6-di-tert-butyl-1,2-benzoquinone and btpyan ¼ 1,8-bis (2,20 :60 ,200 -terpyrid-40 -yl)anthracene] (See text for full caption.) Absorbance (740 nm) Dark (b) (a) 0.6 0.10 0.09 0.08 0.07 0.06 0.4 300 400 Time (s) (c) {4,5} 0.2 NIR component RuIII RuII {3,4} 0.0 300 450 600 750 Wavelength (nm) 900 EPR signal intensity Absorbance Light 100 200 330 340 350 360 Magnetic field (mT) Chapter 1, Figure Photocatalyzed water oxidation by the system (See text for full caption.) 20 40 60 80 Time (s) S2O82/[Ru(bpy)3]2ỵ/blue dimer Chapter 2, Figure Molecular structure of 20:CuII2 :(HOÀ)(PhCH2O)2PO2À)(CF3SO3À)2 shown as an ORTEP drawing at the 50% probability level (Hydrogens and counterions are omitted for clarity.) Chapter 4, Figure 12 Enantioselectivity of artificial-transfer hydrogenases for acetophenone reduction In the achiral (planar trigonal) intermediate during catalytic turnover, incorporation of a hydride from one of the two possible prochiral faces will lead to enantiomers of the three-legged d6 piano stool complex (See text for full caption.) T6 N N Cu2+ HN X O ON7 N N HN X N ON8 Cu2+ O O O 1a N 3a Chapter 6, Scheme 17 Covalent approach to asymmetric DNA based catalysis Chapter 7, Figure Mono- and binuclear structures of mbls from Bacillus cereus (BcII) of subclass B1 (a) Panel a represents the overall protein structures of mbls, A, B and C from BcII with 2.5-, 1.85-, and 1.9˚ resolution, respectively (b) panel b (D–F) represents the active sites of corresponding protein structures A Water molecule and hydroxide ions are shown as red spheres, whereas Zn(II) ions are shown as gray spheres [PDB codes for structures A, B and C are 1BMC, 1BVT, and 1BC2, respectively (60–62) Chapter 7, Figure Structures of VIM-2 mbls of subclass B1 in both reduced G and I and oxidized H and J forms Panel a represents the overall protein structures, whereas panel b represents the active sites of these proteins [PDB codes for structures G and H are 1KO3 and 1KO2, respectively Here Ocs221 represents the cysteine sulfonic acid (66).] Chapter 8, Figure 32 (a) A reference UV LED (360 nm) illuminating blue light (commercially available) (b) Image of the same LED coated with a thin layer of 2D-[Cd2S2(ba)] before illumination (c) The illuminating image of the coated LED (d) The illuminating image of the coated LED after Mn2ỵ doping (0.1 mol%) CUMULATIVE INDEX, VOLUMES 1–57 Gray, Harry B., see Bowler, Bruce E Green, Malcom L H., see Brookhart, Maurice Green, Michael R., see Burstein, Bruce E Grove, David M., see Janssen, Maurits D Grubbs, Robert H., The Olefin Metathesis Reaction Graen, D M., Electronic Spectroscopy of High Temperature Open-Shell Polyatomic Molecules Gr€utzmacher, Jansj€org, see De Bruin, Bas Gultneh, Yilma, see Karlin, Kenneth D Hahn, James E., Transition Metal Complexes Containing Bridging Alkylidene Ligands Haiduc, Ionel, see Tiekink, Edward, R T., Haight, G, P., Jr., see Beattie, J K Haim, Albert Mechanisms of Electron Transfer Reactions: The Bridged Activated Complex Hall, Kevin P and Mingos, D Michael P., Homo-and Heteronuclear Cluster Compounds of Gold Hall, Tracy H., High Pressure Inorganic Chemistry Hancock, Robert D., Molecular Mechanics Calculations as a Tool in Coordination Chemistry Hatnean, Jillian A., see Johnson, Samuel A Haushalter, Robert C, see Finn, Robert C Hayaishi, Osamu, Takikawa, Osamu, and Yoshida, Ryotaro, Indoleamine 2,3-Dioxygenase, Properties and Functions of a Superoxide Utilizing Enzyme Hayashi, Takashi, see Watanabe, Yoshihito He, Chuan, see Li, Zigang He, Wei, Franzini, Raphael M., and Achim, Catalina, Metal-Containing Nucleic Acid Structures Based on Synergetic Hydrogen and Coordination Bonding Heard, Peter J., Main Group Dithiocarbamate Complexes Heintz, Robert A., see Dunbar, Kim R Helton, Matthew E., see Kirk, Martin L Hendry, Philip, and Sargeson, Alan M., Metal Ion Promoted Reactions of Phosphate Derivatives Hennig, Gerhart R., Interstitial Compounds of Graphite Henrick, Kim, Tasker, Peter A., and Lindoy, Leonard F., The Specification of Bonding Cavities in Macrocyclic Ligands Herbert, Rolle H., Chemical Applications of M€ossbauer Spectroscopy Hetterscheid, Dennis G H., see De Bruin, Bas Heumann, Andreas, Jens, Klaus-Joachim, and R€eglier, Marius, Palladium Complex Catalyzed Oxidation Reactions Hobbs, R J M., see Hush, N S 601 24 14 119 31 205 30 273 32 237 37 187 38 75 55 53 545 38 201 125 33 42 483 602 CUMULATIVE INDEX, VOLUMES 1–57 Hodgson, D J., The Structural and Magnetic Properties of First-Row Transition Metal Dimers Containing Hydroxo, Substituted Hydroxo, and Halogen Bridges Hodgson, Derek J., The Stereochemistry of Metal Complexes of Nucleic Acid Constituents Hodgson, Keith O., see Cramer, Stephen P Hoff, Carl, D., Thermodynamics of Ligand Binding and Exchange in Organometallic Reactions Hoffman, Brian E., see Michel, Sarah L J Ã Hogarth, Graeme, Transition Metal Dithiocarbamates: 1978–2003 Hollebone, B R., see Domini, J C Holloway, John H., Reactions of the Noble Gases Holm, R H., Everett, G W., and Chakravorty, A., Metal Complexes of Schiff Bases and B-Ketoamines Holm, R H and OConnor, M J., The Stereochemistry of Bis-Chelate Metal (II) Complexes Holm, Richard M., Ciurli, Stefano, and Weigel, John A., Subsite-SpecificStructures and Reactions in Native and Synthetic (4Fe-4-S) Cubane-Type Clusters Holmes, Robert R., Five-Coordinated Structures Hong, Bo, see Cotton, F A Hope, Hakon, X-Ray Crystallography: A Fast, First-Resort Analytical Tool Horrocks, William DeW., Jr and Albin, Michael, Lanthanide Ion Luminescence in Coordination Chemistry and Biochemistry Honv€ath, Isty€anT., see Adams, Richard D Humphries, A P and Kaesz, H D., The Hydrido-Transition Metal Cluster Complexes Hunt, J P and Friedman, H L., Aquo Complexes of Metal Ions Hurst, James K., see Clark, Aurora E Hush, N S., Intervalence Transfer Absorption Part Theoretical Considerations and Spectroscopic Data Hush, N S., see Allen, G C Hush, N S and Hobbs, R J M., Absorption-Spectra of Crystals Containing Transition Metal Ions Isied, Stephan S., Lon-Range Electron Transfer in Peptides and Proteins Isied, Stephan S., see Kuehn, Christa Jagirdar, Balaji R., Organometallic Fluorides of the Main Group Metals Containing the C-M-F Fragment James, B D and Wallbridge, M G H., Metal Tetrahydroborates 19 173 23 211 40 503 53 71 241 83 14 241 38 32 119 41 31 25 30 145 359 391 10 259 32 443 48 351 11 99 CUMULATIVE INDEX, VOLUMES 1–57 James, David W., Spectroscopic Studies of Ion-Ion Solvent Interaction in Solutions Containing Oxyanions James, David W and Nolan, M J., Vibrational Spectra of Transition Metal Complexes and the Nature of the Metal-Ligand Bond Janssen, Maurits D., Grove, David M., and Koten, Gerard van, Copper (I) Lithium and Magnesium Thiolate Complexes: An Overview with Due Mention of Selenolate and Tellumlate Analogues and Related Silver(I) and Gold(I) Species Jardine, F H., The Chemical and Catalytic Reactions of Dichlorotris (triphenylphosphine)(II) and Its Major Derivatives Jardine, F H., Chlrotris(triphenylphosphine)rhodium(I): Its Chemical and Catalytic Reactions Jeffrey, G A and McMullan, R K., The Clathrate Hydrates Jens, Klaus-Joachim, see Heumann, Andreas Johnson, B F G and McCleverty, J A., Nitric Oxide Compounds of Transition Metals Johnson, Michael K., Vibrational Spectra of Dithiolene Complexes Johnson, Samuel A., Hatnean, Jillian A., and Doster, Meghan E., Functionalization of Fluorinated Aromatics by Nickel-Mediated CH and C-F Bond Oxidative Additon: Prospects for the Synthesis of Fluorine-Containing Pharmaceuticals Jolly, William L., Metal-Ammonia Solution Jones, Peter, see Brown, S B Jorgensen, Chr., Klixbull, Electron Transfer Spectra Jorgensen, Chr., Klixbull, The Nephelauxetic Series Jurisson, Silvia, see Deutsch, Edward Kadish, Karl M., The Electrochemistry of Metalloporphyrins in Nonaqueous Media Kaesz, H D., see Humphries, A P Kahn, M Ishaque and Zubieta, Jon, Oxovanadium and Oxomolybdenum Clusters and Solids Incorporating Oxygen-Donor Ligands Kamat, Prashant V., Native and Surface Modified Semiconductor Nanoclusters Kampf, Jeff W., see Pecoraro, Vincent L Kanatzidis, Mercouri G and Sutorik, Anthony C., The Application of Polychalcogenide Salts to the Exploratory Synthesis of Solid-State Multinary Chalogenides at Intermediate Temperatures Karlin, Kenneth D and Gultneh, Yilma, Binding and Activation of Molecular Oxygen by Copper Complexes Katori, Tatsuo, see Miranda, Katrina M Kennedy, John D., The Polyhedral Metallaboranes, Part I: Metallaborane Clusters with Seven Vertices and Fewer 603 33 353 195 46 97 31 265 28 63 43 277 52 213 57 255 235 12 101 73 34 435 43 44 273 43 151 35 219 32 519 604 CUMULATIVE INDEX, VOLUMES 1–57 Kennedy, John D., The Polyhedral Metallaboranes, Part II: Metallaborane Clusters with Eight Vertices and More Kepert, D L., Aspects of the Stereochemistry of Eight-Coordination Kepert, D L., Aspects of the Stereochemistry of Seven-Coordination Kepert, D L., Aspects of the Stereochemistry of Six-Coordination Kepert, D L., Isopolytungstates Kepert, D L., see Favas, M C Kerscher, Marion, see Comba, Peter Kesselman, Janet M., see Tan, Ming X Kice, J L., Nucleophilic Substitution at Different Oxidation-States of Sulfur Kimura, Eiichi, Macrocylic Polyamine Zinc(II) Complexes as Advanced Models far Zinc(II) Enzymes King, R B., Transition Metal Cluster Compounds Kingsborough, Richard P., Transition Metals in Polymeric p-Conjugated Organic Frameworks Kirk, Martin L., The Electronic Structure and Spectroscopy of Metallo-Dithiolene Complexes Kitagawa, Teizo and Ogura, Takashi, Oxygen Activation Mechanism at the Binuclear Site of Heme-Copper Oxidase Superfamily as Revealed by Time-Resolved Resonance Raman Spectroscopy Klingler, R J and Rathke, J W., Homogeneous Catalytic Hydrogenation of Carbon Monoxide Kloster, Grant M., see Watton, Stephen P Koekkoek, Arjan J., see De Bruin, Bas Kolodziej, Andrew F., The Chemistry of Nickel-Containing Enzymes Konig, Edgar Structural Changes Accompanying Continuous and Discontinuous Spin-State Transitions Korobkov, Ilia, and Gambarotta, Sandro, Trivalent Uranium: A Versatile Species for Molecular Activation Koten, Gerard van, see Janssen, Maurits D Kramarz, K W and Norton, J R., Slow Proton-Transfer Reactions in Organometallic and Bioinorganic Chemistry Krausz, Elmars and Ferguson, James The Spectroscopy of the [Ru(bpy)3]2_System Kubas, Gregory J., see Vergamini, Philip J Kuehn, Christa and Isied, Stephan S., Some Aspects of the Reactivity of Metal Ion-Sulfur Bonds Kumar, Krishan, see Endicott, John F Kustin, Kenneth and Swinehart, James, Fast Metal Complex Reactions 34 211 24 179 25 41 23 4 199 4 17 147 41 15 443 287 48 123 52 111 45 431 39 113 41 493 35 527 54 321 42 37 293 27 153 13 107 CUMULATIVE INDEX, VOLUMES 1–57 Laane, Jaan and Ohlsen, James R., Characterization of Nitrogen Oxides by Vibrational Spectroscopy Lagow, Richard J and Margrave, John L., Direct Fluorination: A New Approach to Fluorine Chemistry Lagow, Richard J., and Chang, Hsuan-Chen, High-Performance Pure Calcium Phosphate Bioceramics: The First Weight Bearing Completely Resorbable Synthetic Bone Replacement Materials Laibinis, Paul E., see Tan, Ming, X La Monica, Girolamo, The Role of the Pyrazolate Ligand in Building Polynuclear Transition Metal Systems Lange, Christopher W., see Pierpont, Cortlandt G Laudise, R A., Hydrothermal Synthesis of Single Crystals Laure, B L and Schmulbach, C D., Inorganic Electrosynthesis in Nonaqueous Solvents Lay, Peter A., see Levina, Aviva Ledney, Michael, see Dutta, Prabir K Le Floch, Pascal, see Mezaillies, Nicolas Lentz, Dieter, see Seppelt, Konrad Leung, Peter C W., see Williams, Jack M Lever, A B P., see Donini, J C Levina, Aviva, Codd, Rachel, Dillon, Carolyn T., and Lay, Peter A., Chromium in Biology: Toxicology and Nutritional Aspects Lewis, J., see Figgis, B N Lewis, Nathan S., see Tan, Ming, X Li, Jing and Zhang, Ruibo, A New Class of Nanostructured Inorganic–Organic Hybrid Semiconductors Based on II–VI Binary Compounds Li, Zigang, Capretto, David A., and He, Chuan, Silver-Mediated Oxidation Reactions: Recent Advances and New Prospects Libson, Karen, see Deutsch, Edward Lieber, Charles M., see Wu, Xian Liang Liehr, Andrew D., The Coupling of Vibrational and Electronic Motions in Degenerate Electronic States of Inorganic Complexes Part I States of Double Degeneracy Liehr, Andrew D., The Coupling of Vibrational and Electronic Motions in Degenerate Electronic States of Inorganic Complexes Part II States of Triple Degeneracy and Systems of Lower Symmetry Liehr, Andrew D., The Coupling of Vibrational and Electronic Motions in Degenerate and Nondegenerate Electronic States of Inorganic and Organic Molecules Part III Nondegenerate Electronic States 605 27 465 26 161 50 317 46 151 14 65 51 145 57 445 56 281 455 385 606 CUMULATIVE INDEX, VOLUMES 1–57 Lindoy, Leonard F., see Deutsch, Edward Lindoy, Leonard F., see Henrick, Kim Lintvedt, Richard L., see Glick, Milton D Lippard, Stephen J., see Bruhn, Suzanne L Lippard, Stephen J., Eight-Coordination Chemistry Lippard, Stephen J., Seven and Eight Coordinate Molybdenum Complexes and Related Molybdenum (IV) Oxo Complexes, with Cyanide and Isocyanide Ligands Lippen, Bernhard, Platinum Nucleobase Chemistry Lippert, Bernhard, Alterations of Nucleobase pKa Values upon Metal Coordination: Origins and Consequences Lobana, Tarlok, S., Structure and Bonding of Metal Complexes of Tertiaryphosphine-Arsine Chalcogenides Including Analytical, Catalytic, and Other Applications of the Complexes Lockyer, Trevor N and Manin, Raymond L., Dithiolium Salts and Dithio-bdiketone Complexes of the Transition Metals Long, Jeffrey R see Welch, Eric J Long, K H., Recent Studies of Diborane Lorand, J P., The Cage Effect Lukehart, C M., see Cotton, F A Lupinetti, Anthony J., Strauss, Steven H., and Frenking, Gernot, Nonclassical Metal Carbonyl Mancardi, Daniele, see Miranda, Katrina M McAuliffe, C A., see Chow, S T McCleverty, J A., Metal 1,2-Dithiolene and Related Complexes McCleverty, J A., see Johnson, B F G McClure, Donald S., see George, Philip MacDonnell, Frederick M., see Wright, Jeffrey G McMaster, Jonathan, Chemical Analogues of the Catalytic Centers of Molybdenum and Tungsten Dithiolene-Containing Enzymes McMullan, R K., see Jeffrey, G A McNaughton, Rebecca L., see Kirk, Martin L Magyar, John S., see Claudia, Elizabeth S Maier, L., Preparation and Properties of Primary, Secondary and Tertiary Phosphines Malatesta, Lamberto, Isocyanide Complexes of Metals Malinak, Steven M and Coucouvanis, Dimitri, The Chemistry of Synthetic Fe-Mo-S Clusters and Their Relevance to the Structure and Function of the Fe-Mo-S Center Nitrogenase Manoharan, P T., see Venkatesh, B Margrave, John L., see Lagow, Richard J Marks, Tobin J., Chemistry and Spectroscopy off-Element Organometallics Part I: The Lanthanides 109 21 37 91 54 385 37 495 27 223 15 17 207 49 10 49 52 539 27 283 49 599 24 51 CUMULATIVE INDEX, VOLUMES 1–57 Marks, Tobin J., Chemistry and Spectroscopy off-Element Organometallics Part II: The Actinides Martin, Raymond L., see Lockyer, Trevor N Marzilli, Lulgi G., Metal-ion Interactions with Nucleic Acids and Nucleic Acid Derivatives Marzilli, Luigi G., see Toscano, Paul J Mathey, Francosis, see Mezaillies, Nicolas Mayr, Andreas and Bastos, Cecilia M., Coupling Reactions of Terminal Two-Faced p Ligands and Related Cleavage Reaction McKee, Vickie, see Nelson, Jane Meade, Thomas J and Busch, Daryle H., Inclusion Complexes of Molecular Transition Metal Hosts Mehrotra, Ram C and Singh, Anirudh, Recent Trends in Metal Alkoxide Chemistry Meyer, Franc, Synthetic Models for the Urease Active Site Meyer, Gerald J., see Castellano, Felix N Meyer, Thomas J., Excited-State Electron Transfer Meyer, T J., Oxidation-Reduction and Related Reactions of Metal-Metal Bonds M€ezaillies, Nicolas, Mathey, Francois, and Le Floch, Pascal, The Coordination Chemistry of Phosphinines: Their Polydentate and Macrocyclic Derivatives Michel, Sarah L J., Hoffman, Brian M., Baum, Sven M., and Barrett, Anthony G M., Peripherally Functionalized Porphyrazines: Novel Metallomacrocycles with Broad Untapped Potential Miller, J R., see Gerloch, M Miller, Joel S and Epstein, Anhur, J., One-Dimensional Inorganic Complexes Mingos, D Michael P., see Hall, Kevin P Miranda, Katrina M., Ridnour, Lisa, Esprey, Michael, Citrin, Deborah, Thomas, Douglas, Mancardi, Daniele, Donzelli, Sonia, Wink, David A., Katori, Tatsuo, Tocchetti, Carlo G., Ferlito, Marcella, Paolocci, Nazareno, and Fukuto, Jon M., Comparison of the Chemical Biology of NO and HNO: An Inorganic Perspective Mirkin, Chad A., see Slone, Caroline S Mitra, S., Chemical Applications of Magnetic Anisotropy Studies on Transition Metal Complexes Mitzi, David B., Synthesis, Structure and Properties of OrganicInorganic Perovskites and Related Materials Mody, Tarak D., Fu, Lei, and Sessler, Jonathan L., Texaphyrins: Synthesis and Development of a Novel Class of Therapeutic Agents Morgan, Grace, see Nelson, Jane Muetterties, E L., see Tachikawa, Mamoru Mugesh, Govindasamy, see Umayal Muthaiah Murphy, Eamonn F., see Jugirdar, Balayi R 607 25 223 23 225 40 33 59 46 56 239 487 30 389 19 49 455 50 473 20 54 349 22 309 48 49 551 608 CUMULATIVE INDEX, VOLUMES 1–57 Natan, Michael J., see Wright, Jeffrey G Natan, Michael J and Wrighton, Mark S., Chemically Modified Microelectrode Arrays Nelson, Jane, McKee, V and Morgan, G Coordination Chemistry of Azacryptands Neumann, Ronny, Polyoxometallate Complexes in Organic Oxidation Chemistry Nguyen, Sonbinh T., see Tan, Ming X Nocera, Daniel G., see Rosenthal, Joel and Surendranath, Yogesh Nolan, M J., see James, David W Norman, Nicholas, C., see Cowley, Alan H Norton, J R., see Kramarz, K W Oakley, Richard T., Cyclic and Heterocyclic Thiazines O’Connor, Charles J., Magnetochemistry—Advances in Theory and Experimentation O’Connor, M J., see Holm, R H Ogura, Takashi, see Kitagawa, Teizo Oelerich, Jens and Roelfes, Gerard, DNA Based Metal Catalysis O’Halloran, Thomas V., see Wright, Jeffrey G Ohlsen, James R., see Laane, Jaan Oldham, C., Complexes of Simple Carboxylie Acids Orrell, Keith, G., see Abel, Edward W Ozin, G A., Single Crystal and Cas Phase Raman Spectroscopy in Inorganic Chemistry Ozin, G A and Vander Voet, A., Cryogenic Inorganic Chemistry Paolocci, Nazareno, see Miranda, Katrina M Pandey, Krishna K., Coordination Chemistry of Thionitrosyl (NS), Thiazate (NSO–), Disulfidothionitrate (S3N–), Sulfur Monoxide (SO), and Disulfur Monoxide (S2O) Ligands Parish, R V., The Interpretation of 119 Sn-M€ossbauer Spectra Parkin, General, Terminal Chalcogenido Complexes of the Transition Metals Paul, Purtha P., Coordination Complex Impregnated Molecular Sieves-Synthesis, Characterization, Reactivity and Catalysis Peacock, R D., Some Fluorine Compounds of the Transition Metals Pearson, Ralph G., see Basolo, Fred Pecht, Israel, see Farver, Ole Pecoraro, Vincent L., Stemmler, Ann J., Gibney, Brian R., Bodwin, Jeffrey J., Wang, Hsin, Kampf, Jeff W., and Barwinski, Almut, Metallacrowns: A New Class of Molecular Recognition Agents 37 391 47 167 47 317 36 299 29 203 57 353 10 223 14 173 19 105 40 15 445 101 47 48 457 193 45 83 CUMULATIVE INDEX, VOLUMES 1–57 Perlmutter-Hayman, Berta The Temperature-Dependence of the Apparent Energy of Activation Peruzzini, Maurizio, De Los Rios, Issac, and Romerosa, Antonio, Coordination Chemistry of Transition Metals and Hydrogen Chalogenide and Hydrochalcogenido Ligands Pethybridge, A D and Prue, J E., Kinetic Salt Effects and the Specific Influence of Ions on Rate Constants Piarulli, Umberto and Floriani, Carlo, Assembling Sugars and Metals: Novel Architectures and Reactivities in Transition Metal Chemistry Pierpont, Conlandt G and Lange, Christopher W., The Chemistry of Transition Metal Complexes Containing Catechol and Semiquinone Ligands Pilato, Robert S., Metal Dithiolene Complexes in Detection: Past, Present, and Future Plieth, K., see Becker, K A Plumb, Robert C., see Edwards, John O Pope, Michael T., Molybdenum Oxygen Chemistry: Oxides, Oxo Complexes, and Polyoxoanions Power, Philip P., The Structures of Organocuprates and Heteroorganocuprates and Related Species in Solution in the Solid State Prue, J E., see Pethybridge, A D Purcell, D F., see Drago, R S Pyle, Anna Marie and Banon, Jacqueline K Banon, Probing Nuclei Acids with Transition Metal Complexes Que, Lawrence, Jr., and True, Anne E., Dinuclear Iron-and Manganese-Oxo Sites in Biology Ralston, Diana M., see Wright, Jeffrey G Ramasami, T., see Endicott, John F Raphael, Adrienne L., see Bowler, Bruce E Rathke, J W., see Klingler, R J Rauchfuss, Thomas B., The Coordination Chemistry of Thiophenes Rauchfuss, Thomas B., Synthesis of Transition Metal Dithiolenes Reglier, Marius, see Heumann, Andreas Ren, Tong, see Doyle, Michael P Rey, P see Caneschi, A Reynolds, Warren L., Dimethyl Sulfoxide in Inorganic Chemistry Ridnour, Lisa, see Miranda, Katrina M Rifkind, J M., see Venkatesh, B Roelfes, Gerard, see Oelerich, Jens 609 20 229 49 169 17 327 45 393 41 331 52 369 39 181 39 75 38 413 38 97 39 259 52 12 610 CUMULATIVE INDEX, VOLUMES 1–57 Roesky, Herbert W., see Jagirdar, Balaji R Roesky, Herbert W., see Witt, Michael Romerosa, Antonio, see Peruzzini, Maurizio Rosenthal, Joel, and Nocera, Daniel G., Oxygen Activation Chemistry of Pacman and Hangman Porphyrin Architectures Based on Xanthene and Dibenzofuran Species Rothwell, Ian P see Chisholm, Malcolm H Rotzinger, Francois P., see Endicott, John F Roundhill, D Max Metal Complexes of Calixarenes Rovis, Tomislav, and Evans, David A., Structural and Mechanistic Investigations in Asymmetric Copper(I) and Copper(II) Catalyzed Reactions Roy, Mithun, see Chakravarty, Akhil R Rudkevich, Dmitry M., Supramolecular Chemistry of Gases Sangita, See Bhattacharyya, Sibaprasad Sappa, Enrico, Tiripicchio, Antonio, Carty, Anhur J., and Toogood, Gerald E., Butterfly Cluster Complexes of the Group VIII Transition Metals Sargeson, Alan M., see Hendry, Philip Sanon, G., see Fleischauer, P D Sawyer, Donald T., see Sobkowiak, Andrzej Sawyer, Jeffery F., and Gillespie, Ronald J., The Stereochemistry of SB(III) Halides and Some Related Compounds Scandola, F., see Bignozzi, C A Schatz, P N., see Wong, K Y Schiek, Wolfgang, see Comba, Peter Schmulbach, C D., Phosphonitrile Polymers Schmulbach, C D., see Laure, B L Schoonover, J R., see Bignozzi, C A Schrock, Richard R., see Feldman, Jerald Schulman, Joshua M., see Beswick, Colin L Schultz, Arthur J., see Williams, Jack M Searcy, Alan W., High-Temperature Inorganic Chemistry Sellmann, Dieter, Dithiolenes in More Complex Ligends Seppelt, Konrad and Lentz, Dieter, Novel Developments in Noble Gas Chemistry Serpone, N and Bickley, D G., Kinetics and Mechanisms of lsomerization and Racemization Processes of Six-Coordinate Chelate Complexes Sessler, Jonhathan L., see Mody, Tarak D Seyferth, Dietmar, Vinyl Compounds of Metals Shatruk, Michael, Avedano, Carolina, and Dunbar, Kim R., Cyanide-Bridged Complexes of Transition Metals: A Molecular Magnetism Perspective Singh, Anirudh, see Mehrotra, Ram C 55 483 43 533 50 55 206 35 437 34 65 275 52 49 585 29 167 17 391 129 56 155 CUMULATIVE INDEX, VOLUMES 1–57 Slone, Caroline S., The Transition Metal Coordination Chemistry of Hemilabile Ligands Smith, David K., see Beer, Paul D Smith III, Milton R., Advances in Metal Boryl and Metal-Mediated B-X Activation Chemistry Sobkowiak, Andrzej, Tung, Hui-Chan, and Sawyer, Donald T., Iron-and Cobalt-Induced Activation of Hydrogen Peroxide and Dioxygen for the Selective Oxidation-Dehydrogenation and Oxygenation of Organic Molecules Spencer, James, T., Chemical Vapor Deposition of Metal-Containing Thin-Film Materials from Organometallic Compounds Spiro, Thomas G., Vibrational Spectra and Metal-Metal Bonds Stanbury, David M., Oxidation of Hydrazine in Aqueous Solution Stanton, Colby E., see Tan, Ming X Stemmler, Ann J., see Pecoraro, Vincent L Stiefel, Edward I., The Coordination and Bioinorganic Chemistry of Molybdenum Stiefel, Edward I., see Beswick, Colin L Stork, Jay R., see Garibay, Sergio J Stranski, I N., see Becker, K A Strauss, Steven H., see Lupinetti, Anthony J Strouse, Charles E., Structural Studies Related to Photosynthesis: A Model for Chlorophyll Aggregates in Photosynthetic Organisms Stucky, Galen D., The Interface of Nanoscale Inclusion Chemistry Suggett, A., see Brown, S B Suh, Junghun, see Chei, Woo Suk Surendranath, Yogesh and Nocera, Daniel G., Oxygen Evolution Reaction Chemistry of Oxide-Based Electrodes Sutin, Norman, Theory of Electron Transfer Reactions: Insights and Hindsights Sutorik, Anthony C, see Kanatzidis, Mercouri G Sutter, J€org, see Sellmann, Dieter Sutton, D., see Addison, C C Swager, Timothy M., see Kingsborough, Richard P Swinehart, James, see Kustin, Kenneth Sykes, A G and Weil, J A., The Formation, Structure, and Reactions of Binuclear Complexes of Cobalt Tachikawa, Mamoru and Muetterties, E L., Metal Carbide Clusters Takikawa, Osamu, see Hayaishi, Osamu Tamilselvi, A., see Umayal, Muthaiah 611 48 233 48 505 40 291 41 145 11 47 511 22 21 159 40 99 57 505 30 441 13 28 203 612 CUMULATIVE INDEX, VOLUMES 1–57 Tan, Ming X., Laibinis, Paul E., Nguyen, Sonbinh T., Kesselman, Janet M., Stanton, Colby E., and Lewis, Nathan S., Principles and Applications of Semiconductor Photochemistry Tasker, Peter A., see Henrick, Kim Taube, Henry, Interaction of Dioxygen Species and Metal Ions—Equilibrium Aspects Taylor, Colleen M., see Watton, Stephen P Templeton, Joseph L., Metal-Metal Bonds of Order Four Tenne, R., Inorganic Nanoclusters with Fullerene-Like Structure and Nanotubes Thomas, Douglas, see Miranda, Katrina M Thomas, J M and Callow, C R A., New Light on the Structures of Aluminosilicate Catalysts Thorn, Robert J., see Williams, Jack M Tiekink, Edward R T and Haiduc Ionel, Stereochemical Aspects of Metal Xanthate Complexes Supramolecular Self-Assembly Tiripicchio, Antonio, see Sappa, Enrico Titus, E O., see Chock, P B Tocchetti, Carlo G., see Miranda, Katrina M Tofield, B C., The Study of Electron Distributions in Inorganic Solids: A Survey of Techniques and Results Tolman, William B., see Kitajima, Nobumasa Toma, Henrique E and Araki, Koiti, Exploring the Supramolecular Coordination Chemistry-Based Approach for Nanotechnology Toney, Jeffrey, H., see Bruhn, Suzanne L Toogood, Gerald E., see Sappa, Enrico Toscano, Paul J and Marzilli, Luigi G., B12 and Related Organocobalt Chemistry: Formation and Cleavage of Cobalt Carbon Bonds Trofimenko, S., The Coordination Chemistry of Pyrazole-Derived Ligands True, Anne E., see Que, Lawrence Jr Tuck, D G., Structures and Properties of Hx2 and HXY Anions Tuck, D G., see Diamond, R M Tuck, D G and Carty, A., Coordination Chemistry of Indium Tung, Hui-Chan, see Sobkowiak, Andrzej Tunney, Josephine M., see McMaster, Jonathan Tyler, David R., Mechanic Aspects of Organometallic Radical Reactions Umayal, Muthaiah, Tamilselvi, A., and Mugesh, Govindasamy, Metallo-b-lactamases and their Synthetic Mimics: Structure, Function, and Catalytic Mechanism 41 21 34 607 26 211 50 269 35 54 127 20 153 56 379 31 105 34 115 161 19 243 36 125 57 395 CUMULATIVE INDEX, VOLUMES 1–57 Vander Voet, A., see Ozin, G A Van Houten, Kelly A., see Pilato, Robert S van Koten, see Janssen, Maurits D van Leeuwen, P W N M., see Vrieze, K Vannerberg, Nils-Gosta, Peroxides, Superoxides, and Ozonides of the Metals of Groups la, IIa, and IIb Venkatesh, B., Rifkind, J M., and Manoharan, P T Metal Iron Reconstituted Hybrid Hemoglobins Verchere, Jean-Francois, Chapelle, S., Xin, F., and Crans, D C., Metal-Carboxyhydrate Complexes in Solution Vergamini, Phillip J and Kubas, Gregory J., Synthesis, Structure, and Properties of Some Organometallic Sulfur Cluster Compounds Vermeulen, Lori A., Layered Metal Phosphonates as Potential Materials for the Design and Construction of Molecular Photosynthesis Systems Vlek, Antonin A., Polarographic Behavior of Coordination Compounds Vrieze, K and van Leeuwen, P W N M., Studies of Dynamic Organometallic Compounds of the Transition Metals by Means of Nuclear Magnetic Resonance Walder, L., see Gerfin, T Wallbridge, M G H., see James, B D Walton, R., Halides and Oxyhalides of the Early Transition Series and Their Stability and Reactivity in Nonaqueous Media Walton, R A., Ligand-Induced Redox Reactions of Low Oxidation State Rhenium Halides and Related Systems in Nonaqueous Solvents Wang, Hsin, see Pecoraro, Vincent L Wang, Hua H., see Williams, Jack M Wang, Kun, Electrochemical and Chemistry Reactivity of Dithiolene Complexes Ward, Roland, The Structure and Properties of Mixed Metal Oxides Ward, Thomas R., see Creus, Marc Watanabe, Yoshihito, and Hayashi, Takashi, Functionalization of Myoglobin Watton, Stephen P., Taylor, Colleen M, Kloster, Grant M., and Bowman, Stephanie C, Coordination Complexes in Sol-Gel Silica Materials Weigel, A., see Holm, Richard M Weil, J A., see Sykes, A G Weinberger, Dana A., see Slone, Caroline S 613 125 47 563 47 837 21 261 44 143 211 14 16 21 105 52 267 465 54 449 51 333 614 CUMULATIVE INDEX, VOLUMES 1–57 Welch, Eric J., and Long, Jeffrey R., Atomlike Building Units of Adjustable Character: Solid-State and Solution Routes to Manipulating Hexanuclear Transition Metal Chalcohalide Clusters Whangbo, Myung-Hwan, see Williams, Jack M White, Ross R see Cannon, Roderick D Wieghardt, Karl, see Chaudhuri, Phalguni Wieghardt, Karl, see Chaudhuri, Phalguni Wigley, David E., Organoimido Complexes of the Transition Metals Wilkinson, G and Cotton, F A., Cyclopentadienyl and Arene Metal Compounds Williams, Jack M., Organic Superconductors Williams, Jack M., Wang, Hau H., Emge, Thomas J., Geiser, Urs, Beno, Mark A., Leung, Peter C W., Carlson, K Douglas, Thorn, Robert J., Schultz, Arthur J., and Whangbo, Myung-Hwan, Rational Design of Synthetic Metal Superconductors Williamson, Stanley M., Recent Progress in Sulfur-Fluorine Chemistry Winchester, John W., Radioactivation Analysis in Inorganic Geochemistry Wink, David, see Ford, Peter C Wink, David A., see Miranda, Katrina M Witt, Michael and Roseky, Herbert W., Sterically Demanding Fluorinated Substituents and Metal Fluorides with Bulky Ligands Wong, Luet-Lok, see Brookhart, Maurice Wong, K Y and Schatz, P N., A Dynamic Model for Mixed-Valence Compounds Wood, John S., Stereochemical Electronic Structural Aspects of Five-Coordination Woolley, R Guy, see Gerloch, Malcolm Wright, Jeffrey G., Natan, Michael J., MacDonnell, Frederick M., Ralston, Diana, M., and OHalloran, Thomas V Mercury(Il)-Thiolate Chemistry and the Mechanism of the Heavy Metal Biosensor MerR Wrighton, Mark S., see Natan, Michael J Wu, Xian Liang and Lieber, Charles M., Applications of Scanning Tunneling Microscopy to Inorganic Chemistry Xin, Feibo, see Verchere, Jean-Francois Yoshida, Ryotaro, see Hayaishi, Osamu Zaleski, Jeffrey M see Bhattacharyya, Sibaprasad Zhang, Rubio, see Li, Jing 54 42 239 33 183 35 51 39 40 353 28 369 16 227 38 323 39 431 CUMULATIVE INDEX, VOLUMES 1–57 Zubieta, J A and Zuckerman, J J., Structural Tin Chemistry t-Coordination Zubieta, Jon, see Kahn, M Ishaque Zubieta, Jon, see Finn, Robert C Zuckerman, J J., see Zubieta, J A 615 24 251 ... MAX-PLANCK-INSTITUT, MU PROGRESS IN INORGANIC CHEMISTRY Edited by KENNETH D KARLIN DEPARTMENT OF CHEMISTRY JOHNS HOPKINS UNIVERSITY BALTIMORE, MARYLAND VOLUME 57 Copyright Ó 2012 by John Wiley & Sons, Inc... OF THE COORDINATION SPHERE VI MEDIUM EFFECTS A Ion Pairing B Anation Progress in Inorganic Chemistry Volume 57, First Edition Edited by Kenneth D Karlin Ó 2012 John Wiley & Sons, Inc Published... values Indeed, spin contamination was even observed for the openshell triplet states using DFT Interestingly, the authors avoided using the Noodleman’s spin projection correction to the BS/BS singlet-state