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Subscriber access provided by NEW YORK UNIV Article Tuning Magnetic Properties of BiFeO Thin Films by Controlling Rare-Earth Doping: Experimental and First-Principles Studies Hoa Hong Nguyen, Ngo Thu Huong, Tae-Young Kim, Souraya Goumri-Said, and Mohammed Benali Kanoun J Phys Chem C, Just Accepted Manuscript • DOI: 10.1021/acs.jpcc.5b03834 • Publication Date (Web): 03 Jun 2015 Downloaded from http://pubs.acs.org on June 15, 2015 Just Accepted “Just Accepted” manuscripts have been peer-reviewed and accepted for publication They are posted online prior to technical editing, formatting for publication and author proofing The American Chemical Society provides “Just Accepted” as a free service to the research community to expedite the dissemination of scientific material as soon as possible after acceptance “Just Accepted” manuscripts appear in full in PDF format accompanied by an HTML abstract “Just Accepted” manuscripts have been fully peer reviewed, but should not be considered the official version of record They are accessible to all readers and citable by the Digital Object Identifier (DOI®) “Just Accepted” is an optional service offered to authors Therefore, the “Just Accepted” Web site may not include all articles that will be published in the journal After a manuscript is technically edited and formatted, it will be removed from the “Just Accepted” Web site and published as an ASAP article Note that technical editing may introduce minor changes to the manuscript text and/or graphics which could affect content, and all legal disclaimers and ethical guidelines that apply to the journal pertain ACS cannot be held responsible for errors or consequences arising from the use of information contained in these “Just Accepted” manuscripts The Journal of Physical Chemistry C is published by the American Chemical Society 1155 Sixteenth Street N.W., Washington, DC 20036 Published by American Chemical Society Copyright © American Chemical Society However, no copyright claim is made to original U.S Government works, or works produced by employees of any Commonwealth realm Crown government in the course of their duties Page of 28 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 59 60 The Journal of Physical Chemistry Tuning Magnetic Properties of BiFeO3 Thin Films by Controlling Rare-Earth Doping: Experimental and First-Principles Studies Nguyen Hoa Hong 1*, Ngo Thu Huong 1,2, Tae-Young Kim 1, Souraya GoumriSaid3, and Mohammed Benali Kanoun4, † Nanomagnetism Laboratory, Department of Physics and Astronomy, Seoul National University, Seoul 151-747, Korea Hanoi University of Science, 334 Nguyen Trai, Thanh Xuan, Hanoi, Vietnam School of Chemistry and Biochemistry and Center for Organic Photonics and Electronics, Georgia Institute of Technology, Atlanta, Georgia 30332-0400, United States School of Physics, Georgia Institute of Technology, Atlanta, Georgia 30332-0400, United States ACS Paragon Plus Environment The Journal of Physical Chemistry 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 59 60 ABSTRACT Rare Earth (RE) - doped BiFeO3 (BFO) thin films were grown on LaAlO3 (LAO) substrates by using pulsed laser deposition technique All of BFO films doped with 10% of RE exhibit a rhombohedral single phase As for the Pr and Nd doping cases, the ferromagnetic phase is less favored because Fe2+ amount is not dominant When dopant concentration was increased up to 20%, the RE-doped BFO films have gone through a structural transition from rhombohedral to either pure orthorhombic phase (for Ho, Sm), or a mixed phase of orthorhombic and tetragonal (for Pr, Nd), or pure tetragonal (for Eu) As an important consequence, magnetic properties of RE-doped BFO films have drastically changed Our results give a guide for how to tailor the ferromagnetism of BFO films by appropriate controlling the type of RE dopant as well as dopant concentration The experimental findings are completed by performing density functional theory calculations to explore the effect of RE doping in BFO for the considered three phases ACS Paragon Plus Environment Page of 28 Page of 28 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 59 60 The Journal of Physical Chemistry INTRODUCTION Multiferroics are an interesting group of materials that exhibit both ferroelectricity and ferromagnetism with coupled electric and magnetic order parameters [1-3] Multiferroism is currently the subject of intensive scientific investigation, since they potentially offer a wide range of interesting applications [2-6] BiFeO3 (BFO) is known to be the only ABO3-type simple perovskite that shows multiferroic at room-temperature and, thus, is considered to be the most promising candidate for practical applications among multiferroic materials [3, 5, 6] At room temperature, BiFeO3 exhibits a distorted perovskite structure with rhombohedral polar R3c symmetry At higher temperatures (≈1100 K), the rhombohedral (R) phase undergoes a first order phase transition to a GdFeO3-like Pbnm structure [7-9] and a (probable) orthorhombic γphase [10] Basically, BiFeO3 should be G-type antiferromagnetic due to the local spin ordering of Fe3+, that forms a cycloidal spiral spin structure [11] There are several ways to stress the spiral magnetic ordering by applying a very high magnetic field, or reducing the dimensions of the samples, or by replacing Bi3+ or Fe3+ by other ions of comparable ionic sizes [12] Dimension reduction seems to be an effective method to enhance the magnetic moment in BFO thin films and in nanoparticles [6, 13] Some groups have reported about the increase of magnetization in the bulk, thin films, and nanoparticles of BFO, either by substituting on the Bi-site by trivalent rare-earth and divalent ions, or on the Fe-site by transition metal ions Thakuria and Joy had showed that the magnetic moment of the nanoparticles could be enhanced times by substituting Bi by Ho However, the reported saturated magnetization is still found only at a quite high field as of T [12, 14] Partial substitution of Bi by Rare-Earth (RE) ions is known to induce a ACS Paragon Plus Environment The Journal of Physical Chemistry 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 59 60 ferromagnetic response which has been attributed to suppression of the spiral modulation [15, 16] In particular, doping of the Bi3+ A site of the perovskite with rare earth cations (RE) has received extensive attention, with a variety of symmetries, and magnetic and electric behaviors reported with increasing values of x in Bi1-xRExFeO3 and/or decreasing ionic radii of the rare earth cation [8, 9, 17–18] Recent studies of bulk and thin films of (Bi,RE) FeO3 (RE = Nd, Sm) have revealed a formation of a stable antipolar, PbZrO3-like structure in a narrow rare-earth concentration range [8, 18-19] In this respect, ab initio calculations based on the density-functional theory (DFT) have played an important role in the description, understanding, as well as prediction—via identification of suitable material design rules—of magnetic, ferroelectric and magnetoelectric properties of multiferroics, due to its ability to describe the many active degrees of freedom within a comparable level of accuracy [3, 20-23] Theoretical modeling based DFT approach and effective Hamiltonian scheme have been subject of few recent works on RE doped BFO [19, 23, 24] where they mainly reported the dependence of critical temperature on the RE compositions In the present study, we attempt to tune the magnetic properties of BiFeO3 by several ways such as: selecting the suitable RE ion for doping; screening the appropriate concentration, targeting to obtain the largest magnetization possible at room temperature, and at a relatively low field The aim of the present work is to understand the relationship between structural and magnetic properties of RE-doped BFO films by combining ab initio calculations and thin-film growth experiments in order to control magnetism of this family of compounds, with hope to guide correctly the materials strategy for spintronic and magnetic applications ACS Paragon Plus Environment Page of 28 Page of 28 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 59 60 The Journal of Physical Chemistry EXPERIMENTAL AND COMPUTATIONAL DETAILS RExBi1-xFeO3 ceramic targets (where RE= Ho, Sm, Pr, Nd, and Eu; x = 0; 0.1, and 0.2) were prepared by a sol-gel auto ignition method [14] RE-doped BiFeO3 (RBFO) thin films have been deposited by Pulsed Laser Deposition (PLD) technique (eximer KrF laser with λ= 248 nm; the repetition rate was 13 Hz and the energy density was 2.1 J/cm2), with a typical thickness as of 200 nm All the films were grown on (001) LaAlO3 (LAO) substrates During deposition, the substrate temperature was kept at 700°C and the oxygen partial pressure (PO2) was 1.4×10-3 Torr After deposition, the sample was kept in the chamber at 500°C with the same oxygen partial pressure as during deposition for 30 min, and then finally cooled down slowly to room temperature [see also Ref 14 for details] The structural analysis was carried out by High Resolution X-ray diffraction (HRXRD) with Cu Kα radiation The M-T and M-H curves were collected by a Quantum Design Superconducting Quantum Interference Device (SQUID) system with magnetic field (H) ranging from up to 0.5 T and temperatures (T) ranging from 350 K down to K The oxidation states of RE-doped BFO thin films were characterized by X-ray photoelectron spectroscopy (XPS, KRATOS, AXIS-HSi) XPS measurements were performed with an Mg/Al X-ray source The energy calibrations were made against the C 1s peak and the Shirley background subtraction was used [as in Ref 14] The chemical elements’ content was also checked by Energy-dispersive X-ray diffraction spectroscopy (EDX) at room temperature Our calculations were performed using all electron linearized augmented plane wave method with local orbitals basis set based on DFT as implemented in the WIEN2k computer program [25] Exchange and correlation were treated within the generalized gradient approximation (GGA) of Perdew-Burke-Ernzerhof (PBE) [26] Onsite Hubbard interaction between the 5f ACS Paragon Plus Environment The Journal of Physical Chemistry 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 59 60 electrons was treated within the fully rotationally invariant version [27] Here, U (equal to what is often called Ueff = U − J) is taken as the on-site interaction term as suggested in Ref 28 The cutoff Rmt*Kmax was set to 7.0 to determine the basis sets To obtain more information on RE doped-BiFeO3, we were carried out DFT calculations by adopting the following supercell approach: (i) a 2×2×2 supercell that contains 12 FeBiO3 formula cells for the hexagonal R3c structure, and (ii) a 2×2×1 supercell that contains formula cells for the orthorhombic Pbnm and tetragonal P4mm structures In each supercell, a Bi atom was substituted by one RE impurity, in order to obtain Bi1-xRExFeO3 with x = 0.0833 for hexagonal structure and 0.25 orthorhombic and tetragonal structures For the integration over the Brillouin zone, a 4×4×1 Monkhorst–Pack kpoint mesh [29] was used for the rhombohedral (hexagonal) cell while a 5×5×3 Monkhorst–Pack k-point grid was adopted for the orthorhombic and tetragonal cells The convergence of selfconsistent calculations was attained with a total energy convergence tolerance of 0.1 mRy RESULTS AND DISCUSSION As we know, the EDX method could not give a very precise evaluation of content of each element in the case of thin films due to the fact that it is just most sensitive to the surface of the film but not as the whole However, one can see a slight tendency of deviation in resulting concentration if comparing to the starting doping concentration For example, if we substituted 20% of Bi by Ho, then the resulting Ho:Bi ratio is 22:78, if we substitute 20% of Bi by Sm, then the resulting Sm :Bi ratio is 26.4: 73.6 Therefore, thoroughly in this report we keep naming the compounds as their starting stoichiometry The XRD data show that for the case of doping of 10%, there is no significant change in structures in comparison with the pristine BiFeO3 All RE0.1Bi0.9O3 films have a rhombohedral structure showing very strong peaks of the BFO phase ACS Paragon Plus Environment Page of 28 Page of 28 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 59 60 The Journal of Physical Chemistry Doping with different RE elements only causes some certain shift of the peak positions in the spectra, showing some change in lattice parameters The out-of-plane lattice parameter is 3.925, 3.925, 9329, 3.933, and 4.585 Ǻ for Sm, Ho, Nd, Pr and Eu doped BFO, respectively (as discussed partially in Ref 14] When the RE doping concentration increases up to 20%, a drastic change in structure of the compound has appeared: As for doping of Ho and Sm , the structure is single phase orthorhombic, while for Pr and Nd, it has become a mixed phase of orthorhombic and tetragonal, and for Eu doping case, it is single phase tetragonal Some typical spectra are shown in Figure for comparison between structures of 10% and 20% doping cases, showing changing from rhombohedral to orthorhombic for Ho doping case, and changing from rhombohedral to a mix of orthorhombic and tetragonal for Pr doping case In order to make it easier later for reference, we summarize the structure types for all RExFe1-xO3 thin films in Table ACS Paragon Plus Environment The Journal of Physical Chemistry 60 Kα LAO (003) LAO (003) LAO (002) LAO (002) (002) (006) (012) LAO (001) 100 50 (a) (b) LAO (002) Kα (104) (113) (006) 50 (012) Kα LAO (001) 100 80 (c) LAO (002) (012) 50 40 Kβ (002) (001) 20 LAO (001) 100 Intensity (a.u.) (d) LAO (003) Kα (131) Kα (214) Kβ Kα (113) (006) 50 LAO (001) 100 Kα (012) 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 59 60 Page of 28 20 40 60 80 theta (degree) Figure 1: X-ray diffraction patterns for 200 nm-thick- films grown on LaAlO3 substrates of (a) Ho0.1Bi0.9FeO3-showing Rhombohedral phase; (b) Ho0.2Bi0.8FeO3-showing Orthorhombic phase; (c) Pr0.1Bi0.9FeO3-showing Rhombohedral phase; and (d) Pr0.2Bi0.9FeO3-showing a mix of Orthorhombic and tetragonal phases Table 1: List of structural phases and Fe2+:Fe3+ ratio calculated from XPS data for RExBi1-xFeO3 films (RE= Ho, Sm, Eu, Pr, and Nd) element Pr Nd Ho Sm Eu x = 0.1 Rhombohedral Rhombohedral Rhombohedral Rhombohedral Rhombohedral x = 0.2 Orthorhombic Orthorhombic Orthorhombic Orthorhombic Tetragonal concentration ACS Paragon Plus Environment Page of 28 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 59 60 The Journal of Physical Chemistry Tetragonal Tetragonal Ratio Fe2+: Fe3+ x = 0.1 40 : 60 x = 0.2 51.8 : 48.2 40 : 60 48.5 : 51.5 50 : 50 50 : 50 48.6 : 51.4 45.6 : 54.4 43.7 : 56.3 48.7 : 51.3 Magnetization versus magnetic field taken at 300 K for RE0.1Bi0.9O3 film is shown in Fig (a) One can see that among all RE doped films, Eu-doped, Sm-doped and Ho-doped BFO films have rather large magnetic moments One cannot attribute this big ferromagnetic signal to any impurity If impurities are more than 5% as resolution of the apparatus, one must see from XRD spectra (as we see that no alien peak other than BFO peaks in XRD data), but if they are less than 5%, then the contribution should not have been that big in magnitude Some other group also got ferromagnetic ordering in Ho-doped BFO, however with much more modest magnitude, and the Ms was obtained at a much greater field (as of T) [12, 14], while we got much a larger Ms but at much lower field (as of 0.2 T) This makes a difference and it is quite meaningful for applications In comparison to those three dopants mentioned above, the Pr- and Nd-doped BFO films show much weaker magnetism: the curves in Figure (a) show a much smaller magnitude for magnetization, and the curves of M(H) at room temperature are almost linear indicating a paramagnetic phase [14, 30, 31] ACS Paragon Plus Environment The Journal of Physical Chemistry 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 59 60 Page 14 of 28 ourselves to the Sm-doped BFO for three phases calculated within GGA+U approximation, in order to avoid repetition with similar behavior of remaining RE dopants Figure shows the total and partial DOS (atom and orbital decomposed) of Sm-doped BFO in three phases The top of the valence band is set to zero, as indicated by a dotted vertical line Interestingly, the DOS results shown in Figure indicate that the rhombohedral and tetragonal phases are almost similar regarding orbital occupation and different than orthorhombic phase The total DOS curves of rhombohedral and tetragonal phases suggest that the contributions are larger from the spin-up (down) states below (above) the Fermi From PDOS, we can see that the highest occupied Sm 4f states for spin up are situated around -6.5 eV below the Fermi energy Above the Fermi level, we find the unoccupied f-levels and concentrate them into a sharp peak around eV The fundamental band gap separates the valence band maximum and unoccupied Sm 4f is about 0.44 eV For minority-spin bands, they are empty and situated in the conduction band minimum with a more localized peak about eV The valence band maximum for the occupied majority is dominated by the O 2p state The main O 2p valence band is found between and -7 eV The main Fe 3d valence band focus in a narrow range near -6 eV lightly mixed with the O 2p bonding state The peak of the majority-spin of the Bi 6s state is found between -10 and -11 eV Because of the coupling between the Bi 6s and the O 2p state, the antibonding Bi 6s state is found at the top of the valence band The conduction band minimum is mainly dominated by the Fe 3d state, but O 2p and Bi 6p states also contribute For the minority spin, we can see that the states in the energy range from -0.5 to 2.0 eV belong to the Fe 3d and O 2p states Note that the peak from the O 2p DOS at eV comes from separate bands without 4f contributions and thus these 4f states are localized and not hybridized with the O 2p states The difference of DOS between the tetragonal phase and the rhombohedral phase is that the minority-spin Fe 3d states 14 ACS Paragon Plus Environment Page 15 of 28 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 59 60 The Journal of Physical Chemistry of the tetragonal phase near the Fermi level move towards the high energy direction and become completely unoccupied with two mainly peaks In the case of the orthorhombic phases, the lowest energy majority- and minority-spin band of the valence band extends in the energy range from -11 to -10 eV, and it is mainly composed of the Bi 6s and O 2p states The majority- and minority-spin bands occur around the Fermi level, in the energy range from -1.0 to 1.0 eV, mostly due to the Fe 3d states interact with the O 2p states It is found that Sm 4f states in the majority spin are inserted below the Fermi level around -1.5 eV, whereas in the unoccupied minority-spin Sm 4f states are around eV above the Fermi level It can also be observed contrarily to the previous phases that there are two distinct peaks in the DOS of the majority spin where the first sharp peak appears at the Fermi level is half occupied and second peak is unoccupied that appear in conduction band around 5.5 eV Figure 5: The total and partial spin-polarized DOSs for ferromagnetic Sm-doped BFO Spin up and spin down correspond to positive and negative values, respectively The vertical dashed line denotes the Fermi level CONCLUSION 15 ACS Paragon Plus Environment The Journal of Physical Chemistry 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 59 60 Page 16 of 28 Our study on RE- doped BiFeO3 thin films have reported that all the films of 10% of RE doping show a single phase of rhombohedral structure The saturated magnetization in Ho-, Sm-, and Eu-doped films is much greater than those reported in literature previously, and was observed at a much lower field as of 0.2 T The magnetic moment of Ho-doped, Sm-doped, and Eu-doped BFO films are roughly largest The observed ferromagnetism in our RE-doped BFO films were supposed to result from the coexistence of Fe2+ and Fe3+ that favor double exchange via oxygen When the dopant concentration is increased up to 20%, the BFO films has gone through a structural transition: while Ho-, Sm-, Eu-doped BFO has become orthorhombic, along with the fact that the Fe2+ amount is reduced, Pr and Nd-doped BFO has changed to be mixed phase of orthorhombic and tetragonal, with the consequence is that Fe2+ is increased, leading to a favor of ferromagnetic ordering This measurement was followed by further analysis using firstprinciples calculations based on density functional theory within GGA+U to elucidate the effect of RE doping BFO on the electronic structures The calculation of total magnetic moment and contribution of each atom in different phases shows the change in polarization of BFO following the RE doping and the symmetry/structure Our experimental and theoretical findings reveal that by controlling the type and concentration of Rare-Earth doping, one can tune the magnetic properties of BiFeO3 films in order to fit the requirements of spintronic and magnetic applications AUTHOR INFORMATION Corresponding Authors * Email: nguyenhong@snu.ac.kr † Email: mohammed-benali.kanoun@physics.gatech.edu 16 ACS Paragon Plus Environment Page 17 of 28 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 59 60 The Journal of Physical Chemistry ACKNOWLEDGMENTS The authors thank Dr Raghavender for measurements of the undoped BFO, and Prof Kurisu, Prof Konishi and J.G Kim for EDX measurements N.H.H and T.Y.K would like to thank project 3348-20120033 of National Research Foundation of Korea for its financial support We are grateful for the help of the SNU National Center for Inter-University Research Facilities on XRD measurements and SNU Center for Materials Analysis on XPS measurements N T H thanks Korea Foundation for Advanced Studies for giving her the KFAS fellowship during 20132014, and the BK 21 Plus program of Department of Physics and Astronomy, SNU, for 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Goumri-Said, S., Kanoun, M B.; Manchon, A.; Roqan, I.; Schwingenschlögl U Ab initio Investigation on the Magnetic Ordering in Gd Doped ZnO J Appl Phys 2011, 109, 083929 20 ACS Paragon Plus Environment Page 21 of 28 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 59 60 The Journal of Physical Chemistry Table of content 21 ACS Paragon Plus Environment The Journal of Physical Chemistry 60 LAO (003) LAO (003) Kα LAO (002) (b) LAO (002) (002) (006) (012) LAO (001) 100 50 (a) (c) LAO (002) Kα (104) (113) (006) 50 (012) Kα LAO (001) 100 80 LAO (002) Kβ (002) (012) 50 40 LAO (001) 20 (001) 100 Intensity (a.u.) (d) LAO (003) Kα (131) Kα (214) Kβ Kα (113) (006) 50 LAO (001) 100 Kα (012) 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 59 60 20 40 60 80 theta (degree) FIG ACS Paragon Plus Environment Page 22 of 28 Page 23 of 28 Fig 15 EBFO (a) 10 SBFO M (emu/cm3) NBFO PBFO -5 HBFO -10 -15 -0.50 -0.25 0.00 0.25 0.50 H (T) 10 SBFO 10% PBFO EBFO -5 -10 -0.50 -0.25 0.00 HBFO 0.25 0.50 H (T) 10 NBFO M (emu/cm 3) M (emu/cm3) 25 M (emu/cm3) 50 -25 PBFO (c) 10% SBFO -5 -10 -0.50 -0.25 0.00 0.25 0.50 H (T) -50 -2 -1 H (T) 10 Magnetization (emu/cm3) 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 59 60 The Journal of Physical Chemistry Bi0.8Sm0.2FeO3 (c) -5 -10 -500 -250 250 500 Field (Oe) ACS Paragon Plus Environment The Journal of Physical Chemistry M-H BiFeO3 Target M [ emu / g ] (a) -1 -2 -1.0 -0.5 0.0 H[T] 0.5 1.0 BFO - 130 nm Thin film 1.5 (b) M [ emu /cm ] 1.0 0.5 0.0 -0.5 -1.0 -1.5 -6 Magnetization (emu/cm3) 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 59 60 15 -4 -2 H[T] (c) 10 -5 -10 5% HBFO 200nm 10% HBFO 200nm -15 -0.4 -0.2 0.0 0.2 0.4 Field (T) ACS Paragon Plus Environment Page 24 of 28 Page 25 of 28 The Journal of Physical Chemistry 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 59 60 ACS Paragon Plus Environment The Journal of Physical Chemistry 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 59 60 ACS Paragon Plus Environment Page 26 of 28 Page 27 of 28 The Journal of Physical Chemistry 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 59 60 ACS Paragon Plus Environment The Journal of Physical Chemistry 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 59 60 ACS Paragon Plus Environment Page 28 of 28 ... that by controlling the type and concentration of Rare-Earth doping, one can tune the magnetic properties of BiFeO3 films in order to fit the requirements of spintronic and magnetic applications... 60 The Journal of Physical Chemistry Tuning Magnetic Properties of BiFeO3 Thin Films by Controlling Rare-Earth Doping: Experimental and First-Principles Studies Nguyen Hoa Hong 1*, Ngo Thu Huong... doped BiFeO3 thin films have reported that all the films of 10% of RE doping show a single phase of rhombohedral structure The saturated magnetization in Ho-, Sm-, and Eu-doped films is much greater