Princeton WB OChem

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MCAT SciENCE WoRKBOOK TABLE OF CONTENTS PERIODIC TABLE OF THE ELEMENTS BIOLOGY QuESTIONS AND PAssAGEs • • •• •.•.• • SOLUTIONS 139 PHYSICS QuESTIONS AND pAS SAGES •• • .• • • • • .• 223 SoLUTIONS 353 GENERAL CHEMISTRY QuESTIONS AND PASSAGES 431 SoLUTIONS .• • •.• • .• • • • • • •.• 569 ORGANIC CHEMISTRY QuESTIONS AND PASSAGES 639 SoLUTIONS 731 MCAT SciENCE WoRKBOOK PASSAGE GUIDE BIOLOGY Chapter Number 10 MCAT Biological Sciences Review MCAT Biology Chapter Title Corresponding MCAT Science Workbook Passage Numbers Molecular Biology Microbiology Generalized Eukaryotic Cells Genetics and Evolution Nervous and Endocrine Systems Circulatory, Lymphatic, and Immune Systems Digestive and Excretory Systems Muscle and Skeletal Systems Respiratory and Skin Systems Reproductive Systems and Development 5, 12, 16, 18, 23,25, 27-32,55 13, 17, 19, 20, 21, 26, 34,35 1,2, 4,6, 7,10,24 33,56,62, 63,64, 65,66 8,9, 15,22,38,39,58,59,67-74 40,42,43,44,45, 46,47,61, 75 14,57, 76, 77,78 41,48,49,50,51,60, 79 52,53,54, 80 3, 11, 36,37,81, 82,83 MCAT Physical Sciences Review MCAT Physics Chapter Title Correspond;ng MCAT Science Workbook Passage Numbers Kinematics Mechanics I Mechanics II Mechanics Ill Fluids and Elasticity of Solids Electrostatics Electricity and Magnetism Oscillations and Waves Sound Light and Geometrical Optics 11 PHYSICS Chapter Number 10 3-9, 15-18 1Q-13, 19-24 31,32 25-30,33-39 14,40,45,46,48-55 42,43,56,57 41,44,47,58-60 GENERAL CHEMISTRY Chapter Number 10 MCAT Physical Sciences Review MCAT General Chemistry Chapter Title Corresponding MCAT Sqience Workbook Passage Numbers Atomic Structure Periodic Trends and Bonding Phases Gases Solutions Kinetics Equilibrium Acids and Bases Thermodynamics Redox and Electrochemistry 1-4,6,9-18,70 5, 7,19-28,43,72 35,57,59, 60,62, 63,65,66 40,61,64, 67 31,41, 42, 45,68, 69 33,44, 71 29,37,39,46 30,32,34,36,38,47-55 58, 73-78 8,56, 79-91 ORGANIC CHEMISTRY Chapter Number MCAT Biological Sciences Review MCAT Organic Chemistry Chapter Title Corresponding MCAT Science Workboo}f Passage Numbers Structure and Bonding Substitution and Elimination Reactions Electrophilic Addition Reactions Nucleophilic Addition/Cycloaddition Reactions Lab Techniques and Spectroscopy Biologically-Important Organic Chemistry 1,2, 4,5, 6, 7,8,9, 10 11, 12, 13, 14, 15, 16, 17, 18 19,20,21,22,23,24,25,26,27-30 31,32,33,34,35 36,37,38, 39,40,41,42,43 INTRODUCTION PERIODIC TABLE OF THE ELEMENTS r r He 4.0 H 1.0 Be B c Ll N 6.9 9.0 10.8 16.0 12 13 12.0 14 14.0 11 16 Na Mg AI Sl 23.0 24.3 27.0 28.1 15 p 31.0 19 20 21 22 24 26 27 28 29 Ca Sc: Ti v 2S K Cr Mo Fe Co Nl Cu 39.1 37 40.1 4.5.0 47.9 50.9 55.8 40 41 43 44 58.9 4.5 58.7 46 Kb Sr Zr Nb Mo Tc: Ku Rh 85 •.5 87.6 39 y 88.9 52.0 42 54.9 38 91.2 92.9 95.9 (98) 101.1 5.5 56 57 72 73 74 75 76 Cs 132.9 23 Ba La* ur Ta w Ke Os 137.3 138.9 178.5 180.9 10.5 Db (2621 183.9 186.2 107 Bb (262) 190.2 87 88 89 104 Fr Ka Act Kf (223) 226.0 227.0 (261) • t SCIENCE WORKBOOK s, _(263) 108 Hs (265) Ar 32.1 3.5 39.9 32 33 34 3.5 36 As Se Br Kr 63.5 69.7 72.6 74.9 79.0 79.9 83.8 47 48 49 50 51 Pd Ag 52 Cd lo So Sb Te 102.9 106.4 107.9 112.4 114.8 118.7 121.8 127.6 53 I 126.9 54 Xe 131.3 77 lr 192.2 78 79 80 81 82 83 81 209.0 85 Po At (209) (210) 86 Rn (222) 175.0 103 Pt Au Hg Tl Pb 195.1 197.0 200.6 204.4 207.2 84 109 Mt (267) 61 62 63 64 Sm Eu Gd 140.1 144.2 (145) 150.4 152.0 157.3 65 Tb 158.9 90 91· 92 93 94 95 96 97 Tb Pa Np Pu Am Cm Bk (243) (241} (247) (237) Cl Ge Pm 238.0 s 31 60 (231) 17 10 Ne 20.2 18 Ga Nd u F 19.0 30 Zn 65.4 59 Pr 140:9 58 Ce 232.0 MCAT 106 (244) 66 67 68 69 Dy 162.5 98 Ho Er Tm 164.9 167.3 168.9 70 Yb 173.0 cr 99 100 101 Es 102 Fm Md No Lr (251) (252) (257) (258) (259) (260) 7l Lu MCAT ORGANIC CHEMISTRY PRACTICE QUESTIONS AND pASSAGES 639 The structure below is shown without complete geometrical detail What is the correct assignment of the two indicated bond angles? Questions through 33 are NOT based on a descriptive passage H Identify the hybriziations of the two indicated carbon atoms in the following molecule H ~-! I I a H H < ~~ ~-O_J-H \\ H II· I b H A a=120°, b=120° B a= 109.5°, b = 120° C a = 90°, b = 120° D a 120°, b = 109.5° A B C D Which one of the following is the best resonance form for the molecule HONO? Cl = sp and C2 = sp C sp and C2 sp C =sp and C2 =sp C = sp and C2 = sp = = A Which two atomic orbitals interact to form the D-D bond in D ? A B C D B sands p and p sp and sp sp3 and sp c 1 u u u u and and and and H D How many a bonds and n bonds are there in ethene? A B C D 2° > 3° absence of rearrangement Substrate protonation Substituent
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