Đang tải... (xem toàn văn)
Phụ lục đính kèm về cây an điền hoa nhỏ
PHỤ LỤC 0.000 2.101 2.086 2.071 2.056 2.041 2.022 2.015 2.009 2.004 1.988 1.973 1.959 1.678 1.599 1.534 1.257 5.148 5.133 5.117 5.100 5.098 5.084 7.255 TENE.C2−CDCl3−1H Phuï luïc 1a: Phổ 1H-NMR hợp chất TENE.C2 F2 − Acquisition Parameters Date_ 20090428 Time 9.43 INSTRUM av500 PROBHD mm Multinucl PULPROG zg30 TD 65536 SOLVENT CDCl3 NS 16 DS SWH 10000.000 Hz FIDRES 0.152588 Hz AQ 3.2769001 sec RG 101.6 DW 50.000 usec DE 6.00 usec TE 0.0 K D1 1.00000000 sec MCREST 0.00000000 sec MCWRK 0.01500000 sec 28, 29, 30 ======== CHANNEL f1 ======== NUC1 1H P1 10.50 usec PL1 −3.00 dB SFO1 500.1335009 MHz 12 5 2.573 4.196 1.922 6.242 2.000 F2 − Processing parameters SI 32768 SF 500.1300157 MHz WDW EM SSB LB 0.30 Hz GB PC 1.00 11 Current Data Parameters NAME 111TENE.C2 EXPNO PROCNO 1 ppm F2 − Acquisition Parameters Date_ 20090428 Time 9.43 INSTRUM av500 PROBHD mm Multinucl PULPROG zg30 TD 65536 SOLVENT CDCl3 NS 16 DS SWH 10000.000 Hz FIDRES 0.152588 Hz AQ 3.2769001 sec RG 101.6 DW 50.000 usec DE 6.00 usec TE 0.0 K D1 1.00000000 sec MCREST 0.00000000 sec MCWRK 0.01500000 sec 1.534 Phụ lục 1b: Phổ 1H-NMR hợp chất TENE.C2 1.678 Current Data Parameters NAME 111TENE.C2 EXPNO PROCNO 1.599 2.101 2.086 2.071 2.056 2.041 2.022 2.015 2.009 2.004 1.988 1.973 1.959 5.148 5.133 5.117 5.100 5.098 5.084 TENE.C2−CDCl3−1H 28, 29, 30 11 ======== CHANNEL f1 ======== NUC1 1H P1 10.50 usec PL1 −3.00 dB SFO1 500.1335009 MHz 12 5.2 5.1 ppm 2.000 F2 − Processing parameters SI 32768 SF 500.1300157 MHz WDW EM SSB LB 0.30 Hz GB PC 1.00 1.8 1.7 1.6 6.242 1.9 1.922 2.0 4.196 2.1 2.573 2.2 ppm Current Data Parameters NAME 111TENE.C2 EXPNO PROCNO 39.796 39.774 28.327 26.857 26.751 25.654 17.666 16.057 16.012 77.275 77.021 76.767 135.129 134.919 131.204 124.502 124.389 124.369 TENE.C2−CDCl3−C13CPD Phụ lục 2a: Phổ 13C-NMR hợp chất TENE.C2 F2 − Acquisition Parameters Date_ 20090502 Time 11.30 INSTRUM av500 PROBHD mm Multinucl PULPROG zgpg30 TD 65536 SOLVENT CDCl3 NS 128 DS SWH 30030.029 Hz FIDRES 0.458222 Hz AQ 1.0912410 sec RG 8192 DW 16.650 usec DE 6.00 usec TE 0.0 K D1 2.00000000 sec d11 0.03000000 sec DELTA 1.89999998 sec MCREST 0.00000000 sec MCWRK 0.01500000 sec ======== CHANNEL f1 ======== NUC1 13C P1 10.50 usec PL1 −1.00 dB SFO1 125.7703643 MHz ======== CHANNEL f2 ======== CPDPRG2 waltz16 NUC2 1H PCPD2 88.00 usec PL2 −3.00 dB PL12 14.68 dB PL13 22.00 dB SFO2 500.1320005 MHz 12 11 10 F2 − Processing parameters SI 32768 SF 125.7577825 MHz WDW EM SSB LB 1.00 Hz GB PC 1.00 28 30 29 200 180 160 140 120 100 80 60 40 20 ppm Phụ lục 2b: Phổ 13C-NMR hợp chất TENE.C2 40 39.796 39.774 39 38 37 135 135.129 134.919 10 36 35 134 34 133 33 32 132 131.204 31 30 ppm 29 28.327 28 12 27 26.857 26.751 26 25.654 TENE.C2−CDCl3−C13CPD 25 24 124.502 23 22 124.5 124.389 124.369 11 21 20 19 ppm 17.666 18 30 17 28 29 16.057 16.012 ppm TENE.C2−CDCl3−C13CPD &DEPT DEPT90 Phụ lục 3a: Phổ DEPT-NMR hợp chất TENE.C2 210 200 190 180 170 160 150 140 130 120 110 100 90 80 70 60 50 40 30 20 ppm 200 190 180 170 160 150 140 130 120 110 100 90 80 70 60 50 40 30 20 ppm 200 190 180 170 160 150 140 130 120 110 100 90 80 70 60 50 40 30 20 ppm DEPT135 CH&CH3 CH2 210 C13CPD 210 TENE.C2−CDCl3−C13CPD &DEPT DEPT90 Phụ lục 3b: Phổ DEPT-NMR hợp chất TENE.C2 135 130 125 120 115 110 105 100 95 90 85 80 75 70 65 60 55 50 45 40 35 30 25 20 ppm 125 120 115 110 105 100 95 90 85 80 75 70 65 60 55 50 45 40 35 30 25 20 ppm 125 120 115 110 105 100 95 90 85 80 75 70 65 60 55 50 45 40 35 30 25 20 ppm DEPT135 CH&CH3 CH2 135 130 C13CPD 135 130 5.251 5.244 5.237 3.398 3.223 3.210 3.202 3.190 2.765 2.205 2.182 2.005 1.996 1.978 1.970 1.922 1.915 1.903 1.897 1.874 1.865 1.847 1.838 1.730 1.724 1.704 1.673 1.665 1.657 1.647 1.638 1.631 1.624 1.613 1.601 1.594 1.571 1.564 1.546 1.517 1.505 1.497 1.488 1.400 1.375 1.361 1.342 7.308 TENE.C1−CDCl3&MeOD−1H Current Data Parameters NAME 111TENE.PE2 EXPNO PROCNO Phụ lục 4a: Phổ 1H-NMR hợp chất TENE.C1 F2 − Acquisition Parameters Date_ 20090115 Time 11.24 INSTRUM av500 PROBHD mm TXI 1H−13 PULPROG zg30 TD 65536 SOLVENT CDCl3 NS 16 DS SWH 10000.000 Hz FIDRES 0.152588 Hz AQ 3.2769001 sec RG 90.5 DW 50.000 usec DE 6.00 usec TE 300.1 K D1 1.00000000 sec MCREST 0.00000000 sec MCWRK 0.01500000 sec nhóm -CH3 ======== CHANNEL f1 ======== NUC1 1H P1 7.80 usec PL1 −1.00 dB SFO1 500.1335009 MHz F2 − Processing parameters SI 32768 SF 500.1299893 MHz WDW EM SSB LB 0.30 Hz GB PC 1.00 12 18 1.130 1.000 0.993 1.066 3.262 6.634 4.698 4.887 4.065 5.213 7.332 3.309 2.915 3.796 1.532 ppm 5.2 12 1.000 Phuï luïc 4b: Phổ 1H-NMR hợp chất TENE.C1 5.251 5.244 5.237 5.0 2.2 2.205 18 0.993 2.182 4.8 2.1 4.6 2.0 2.005 1.996 1.978 1.970 4.4 1.9 1.8 4.2 1.922 1.915 1.903 1.897 1.874 1.865 1.847 1.838 4.0 1.730 1.724 1.704 1.673 1.665 1.657 1.647 1.638 1.631 1.624 1.613 1.601 1.594 1.571 1.564 1.546 1.517 1.505 1.7 3.8 6.634 TENE.C1−CDCl3&MeOD−1H 1.066 3.262 1.6 3.6 ppm 3.4 3.398 3.2 ppm 3.223 3.210 3.202 3.190 1.130 1.8 Phụ lục 4c: Phổ 1H-NMR hợp chất TENE.C1 1.7 1.6 1.5 1.4 1.3 1.2 1.1 27 TENE.C1−CDCl3&MeOD−1H 1.730 1.724 1.704 1.673 1.665 1.657 1.647 1.638 1.631 1.624 1.613 1.601 1.594 1.571 1.564 1.546 1.517 1.505 1.497 1.488 6.634 4.698 4.887 1.400 1.375 1.361 1.342 1.323 1.317 1.300 1.292 1.273 1.258 1.140 4.065 1.0 23 5.213 1.087 1.029 1.004 0.984 30 0.952 0.939 0.924 0.909 0.901 0.868 0.855 25 0.9 7.332 29 3.309 0.8 26 2.915 0.810 24 3.796 0.778 0.736 0.713 0.7 1.532 ppm ... 1.973 1.959 1.678 1.599 1.534 1.257 5.148 5.133 5.117 5.100 5.098 5.084 7.255 TENE.C2−CDCl3−1H Phụ lục 1a: Phổ 1H-NMR hợp chất TENE.C2 F2 − Acquisition Parameters Date_ 20090428 Time 9.43 INSTRUM... usec DE 6.00 usec TE 0.0 K D1 1.00000000 sec MCREST 0.00000000 sec MCWRK 0.01500000 sec 1.534 Phụ lục 1b: Phổ 1H-NMR hợp chất TENE.C2 1.678 Current Data Parameters NAME 111TENE.C2 EXPNO PROCNO... 16.012 77.275 77.021 76.767 135.129 134.919 131.204 124.502 124.389 124.369 TENE.C2−CDCl3−C13CPD Phụ lục 2a: Phổ 13C-NMR hợp chất TENE.C2 F2 − Acquisition Parameters Date_ 20090502 Time 11.30 INSTRUM