82 Green Energy Technology, Economics and Policy Table 10.1 World nuclear power production Operational Under Construction Country No. of Units Total MW(e) No. of Units Total MW(e) Argentina 2 935 1 692 Armenia 1 376 Belgium 7 5 863 Brazil 2 1 884 Bulgaria 2 1 906 2 1 906 Canada 18 12 573 China 11 8 438 21 20 920 Czech Republic 6 3 678 Finland 4 2 696 1 1 600 France 58 63 130 1 1 600 Germany 17 20 480 Hungary 4 1 889 Iran 1 915 India 18 3 984 5 2 708 Japan 54 46 823 1 1 325 Korea, Republic Of 20 17 705 6 6 520 Mexico 2 1 300 Netherlands 1 482 Pakistan 2 425 1 300 Romania 2 1 300 Russian Federation 31 21 743 9 6 894 Slovak Republic 4 1 762 2 810 Slovenia 1 666 South Africa 2 1 800 Spain 8 7 450 Sweden 10 8 992 Switzerland 5 3 238 Ukraine 15 13 107 2 1 900 United Kingdom 19 10 137 United States Of America 104 100 683 1 1 165 Total: 436 370 394 56 51 855 (Includes long term shutdown in Canada (4 units; 2530 Mwe) and Japan (1 unit; 246 MWe; Total includes Taiwan, China which has 6 (4 949 MW(e)) operating reactors and 2 (2 600 MW(e)) reactors under construction.) (based on IAEA – Power Reactor Information System) major accidents involving nuclear reactors, Three Mile Island in USA and Chernobyl in erstwhile USSR (presently Ukraine), economic pragmatism due to very low oil prices prevailed over energy planners. Many countries took decisions to roll back nuclear power and replace it other forms of energy in the late 80s and 90s (Cohen, 1990). That the nuclear aversion was really short-sighted dawned up on the energy planners during the last decade when three factors became apparent. The foremost was the fact that fossil fuel such as oil and coal are being exhausted faster than it was ever imagined. Their prices are no more very low nor their supply assured. Secondly the reality of global warming and the fact that the planet has only very limited capacity of accommodate more carbon was established by scientific studies. Nuclear power 83 Thirdly emerging economies of China and India amongst few others are breaking out into a phase high economic growth, which needs vast amounts of added energy supply. The International Atomic Energy Agency (IAEA) projects that the global nuclear power capacity will reach between 473 GWe (low projection) to 748 GWe (high pro- jection) in 2030. The International Energy Agency (IEA) has a reference projection of 433 GWe in 2030 (IAEA, 2009a). The IEA has published two climate-policy scenarios. The ‘550 policy scenario’, which corresponds to long-term stabilization of the atmospheric greenhouse gas con- centration at 550 parts per million of CO 2 , equates to an increase in global temperature of approximately 3 ◦ C. The ‘450’ policy scenario equates to a rise of around 2 ◦ C. In the 550 policy scenario, installed nuclear capacity in 2030 is 533 GWe. In the 450 policy scenario the nuclear share is 680 GWe. The OECD Nuclear Energy Agency has projected 404–625 GWe in 2030 and 580–1400 GWe in 2050. The US Energy Information Administration has a reference projection of 498 GWe of nuclear power in 2030. All the above projections tend to be generally revised upward in the present scenario of accelerated nuclear growth and heavy energy demand anticipated in some of the emerging economies such as China and India. 10.1.2 Nuclear power and green energies Considering the vast resources of uranium and thorium, the two fissionable materials widely available on the surface of earth, and its energy content, nuclear energy could be considered as a renewable source of energy. This could be multiplied many times if extraction of uranium from sea water is also taken in to account. Fast breeder reactors effectively utilize all the fissionable content of in uranium and thorium fuel and therefore generate very little waste. It is 100 times more efficient that current generation of light water and heavy water reactor technologies. This fact, combined with negligible emission of carbon, makes nuclear power a renewable and sustainable source of energy. Apart from being a source of power, nuclear energy could also contribute to pro- duction of hydrogen, desalination of seawater, thus compliment green energies. Small nuclear reactor designs such as Pebble Bed Modular Reactors (PBMR) and Compact High Temperature Reactors (CHTR) could support a decentralized model of power generation and provide process heat for hydrogen production or desalination of water (IAEA, 2008a). Nuclear power was recognized as a reliable, safe, clean and cheap source of energy since the mid 20thcentury when the first successful generation of electricity was demon- strated on December 20, 1951 at Experimental Breeder Reactor (EBR-1), Arco, Idaho (Michal, 2001). Before this reactor was shut down in 1964, it sufficiently laid the sustainable roadmap for nuclear power to utilize not only the uranium resources of the plant, but also the vast thorium resources, as well as the possibility of extracting power out of the used fuel by burning most of the long-lived isotopes. But the developments that dominated the first and second generation nuclearreactors thereafter was only based on use of uranium and utilization of only about 1% of the fissile and fissionable content of the fuel and discard the rest as waste to be stored and ultimately disposed of in deep geological repositories. 84 Green Energy Technology, Economics and Policy Third generation reactors today recycle part of the fissile content as Mixed Oxide Fuel (MOX) and the Fourth Generation reactors to a large extent will follow up with breeder design of EBR-1 to utilize thorium also in a fuel cycle, which will create or breed more fuel than it actually burns and thus elevating nuclear power to the status of renewable energy or green energy. 10.2 NUCLEAR FISSION Radioactivity was discovered in 1896 by Henri Becquerel. Additional work by Marie Curie, Pierre Curie, Ernest Rutherford and others proved that unstable atomic nucleus spontaneously loses energy by emitting ionizing particles and radiation. It was E. Rutherford who in 1917 demonstrated the possibility of splitting atom and emission of particles with high energies. Nuclear fission got its break-through when Otto Hahn and Fritz Strassmann in 1938 split the uranium atom by bombarding it with neutrons and proved that the elements barium and krypton were formed. Importance of nuclear fission started gaining atten- tion when it became apparent that fission of heavy elements is an exothermic (heat emitting) reaction which can release large amounts of energy, both as electromagnetic radiation and as kinetic energy of the fragments (DOE, 1993). The amount of energy released by nuclear fission was found to be several orders of magnitude higher than exothermic chemical reactions such as burning of wood, coal, oil or gas. Typically a fission event releases about ∼200 MeV (million electron volt) of energy. On the other hand, most chemical oxidation reactions such as burning coal or wood, release a few eV per event. Fission of a kilogram of 235 U can produce 7.2 × 10 13 Joules of energy, whereas only 2.4 × 10 7 Joules is obtained by burning one kilogram of coal. Therefore nuclear fuel contains more than twenty million times energy, than does a chemical fuel. The energy of nuclear fission is released as kinetic energy of the fission products and fragments and as electromagnetic radiation in the form of gamma rays. In a nuclear reactor this energy is converted to heat as the particles and gamma rays collide with the atoms that make up the reactor and its coolant, such as light water, heavy water or liquid metal. When the isotope 235 U fissions into two nuclei fragments a total mean fission energy 202.5 MeV is released. Typically ∼169 MeV appears as the kinetic energy of the daugh- ter nuclei. Additionally an average of 2.5 neutrons are emitted with a kinetic energy of ∼2 MeV each (total of 4.8 MeV). Many heavy isotopes are fissionable in the sense that they can undergo fission when struck by free neutrons. But isotopes that sustain a fission chain reaction when struck by low energy neutrons are also called fissile. A few particularly fissile and readily obtainable isotopes, such as 235 U and 239 Pu, are called nuclear fuels (Bodansky, 2003). 10.2.1 Fission chain reaction A nuclear chain reaction can occur when one nuclear reaction causes an average of one or more nuclear reactions, thus leading to a self-propagating number of these reactions (Fig 10.1). All fissionable and fissile isotopes undergo a small amount of spontaneous fission (a form of radioactive decay) which releases a few free neutrons. 86 Green Energy Technology, Economics and Policy 1 2 3 4 2 Figure 10.2 Oklo natural fission reactors (1. Nuclear reactor zone; 2. Sandstone; 3. Uranium ore zones; 4. Granite) in light-water reactors. For that reason natural uranium fission chain reactions would not be possible at present. The 235 U abundance in Oklo uranium ore was found to be only 0.44%. This low 235 U abundance and presence of neodymium and other elements suggest that a natural nuclear reactor existed in the past. It was apparent that considerable amount of 239 PU was also produced. The approximated shape of the reactor zone and hydraulic gradient allowed moderation and reflection of neutrons produced by spontaneous fission or cosmic ray induced fission. These conditions allowed the reactor to achieve criticality (Fig 10.2). As the reactor power increased, the water moderator would heat, reducing its density and its effectiveness as a moderator and reflector. The reactors thus could have operated cyclically, operating for half hour until accumulated heat boiled away the water, then shutting down for up to 2.5 hours until the rocks cooled sufficiently to allow water saturation. Based on the amount of fission products generated, the Oklo reactors are estimated to have operated for more than 150000 years. It is estimated that the average operating power was about 100 KW, similar to that of some modern research reactors. The reactors produced a total of 15GW yr of thermal energy and consumed an estimated 5–6 tonnes of 235 U and produced an equal mass of fission products. Majority of the fission products have remained in place for nearly 2 billion years, in spite of their location in fractured, porous, and water-saturated sandstone for most of the time. 10.2.3 Nuclear reactors A nuclear reactor is a device or system in which nuclear chain reactions are initiated, controlled, and sustained. Nuclear reactors are usually used for many purposes, but production of electrical power is the most dominant commercial application. It can be also used for production radio-isotopes for medical use, to power ships, submarines and ice-breakers, and for nuclear research. The production of electricity by a nuclear reactor is accomplished by utilizing the heat from the fission reaction to drive steam turbines. Nuclear power 87 Current nuclear reactors technology is based on a sustained nuclear fission chain reaction to induce in a fissile material fuel, releasing both energy and free neutrons. A reactor encloses nuclear fuel or reactor core surrounded by a neutron moderator such as light water, heavy water or graphite and control rods that control the rate of the reaction (DOE, 1993). In a nuclear reactor, the neutron flux at a given time is a function of the rate of fis- sion neutron production and the rate of neutron losses due to non-fission absorption and leakage from the system. When a reactor’s neutron population remains steady, so that as many new neutrons are produced as lost, the fission chain reaction will be self-sustaining and the reactor is referred as “critical’’. When the reactor’s neutron production exceeds the loss is called “supercritical’’, and when losses dominate, it is considered “subcritical’’. For the sustained chain reaction to be possible the uranium-fueled reactors must include a neutron moderator that interacts with newly produced fast neutrons from fis- sion events to reduce their kinetic energy from several MeV to several eV, making them more likely to induce fission. This is because 235 U is much more likely to undergo fis- sion when struck by one of these thermal neutrons than by a freshly-produced neutron from fission. Any element that strongly absorbs neutrons is called a reactor poison, because it tends to shut down an ongoing fission chain reaction. Some reactor poisons are delib- erately inserted into fission reactor cores to control the reaction. Boron or cadmium control rods are usually used for this purpose. Many reactor poisons are produced by the fission process itself, and buildup of neutron-absorbing fission products affects both the fuel economics and the controllability of nuclear reactors. While many fissionable isotopes exist in nature, the useful fissile isotope found in any sufficient quantity is 235 U. It is about 0.7% of the naturally occurring uranium ore. The rest about 99.3% is the fissionable 238 U isotope. Therefore in most of the light- water reactors uses 235 U must be enriched artificially up to 3–5%. Chemical properties of 235 U and 238 U are identical, so physical processes such as gaseous diffusion, gas centrifuge or mass spectrometry must be used for isotopic separation based on small differences in mass. Nuclear reactors with heavy water moderation can operate with natural uranium, eliminating altogether the need for enrichment. The Pressurized Heavy Water Reactors (PHWR) are an example of this type. Some graphite moderated reactor designs can also use natural uranium as fuel (Table 10.2). In the reactor core major part of the heat is generated due to conversion of the kinetic energy of fission products to thermal energy, when the nuclei collide with nearby atoms. Some of the gamma rays produced during fission are absorbed by the reactor and their energy converted to heat. Heat is also produced by the radioac- tive decay of fission products and materials that have been activated by neutron absorption. This decay heat source will remain for some time even after the reactor is shutdown. A nuclear reactor coolant is circulated through the reactor core to absorb the heat that it generates. Coolant is usually water but sometimes a gas or a liquid metal or molten salt is also used. The heat is carried away from the reactor and is then used to generate steam, which drives a turbine coupled with an electrical generator to produce electricity. Nuclear power 89 Table 10.3 Current world nuclear reactors Operating Reactors Reactors Under Construction Installed Capacity Installed Capacity Reactor Type Units (MWe) Units (MWe) Pressurized Water Reactor 265 244 337 47 44 689 Boiling Water Reactor (BWR) 92 83 690 3 3 925 Pressurized Heavy Water 45 22 639 3 1 096 Reactor (PHWR) Gas Cooled Reactor (GCR) 18 8 949 – – Light water cooled Graphite 45 22 639 1 925 Moderated Reactor (LWGR) Fast Breeder Reactor (FBR) 1 560 2 1 220 Total 436 370 394 56 51 855 (Based on IAEA Power Reactor Information System) In some reactors the coolant acts as a neutron moderator too. A moderator increases the power of the reactor by causing the fast neutrons that are released from fission to lose energy and become thermal neutrons. Thermal neutrons are more likely than fast neutrons to cause fission, so more neutron moderation means more power output from the reactors. The power output of the reactor is controlled by controlling how many free neutrons are able to create more fission. Control rods that are made of a nuclear poison are used to absorb neutrons, so that there are fewer neutrons available to cause fission. Inserting the control rod deeper into the reactor will reduce its power output, and extracting the control rod will increase it. Depending on the type of nuclear reaction, reactors are classified as thermal reactors and fast reactors. Thermal reactors use slow or thermal neutrons. Almost all current reactors are of this type. These contain neutron moderator materials that slow neu- trons until their neutron temperature is thermalized, that is, until their kinetic energy approaches the average kinetic energy of the surrounding particles. Thermal neutrons have a far higher cross section or probability of fissioning the fissile nuclei 235 U, 239 Pu and 241 Pu and relatively lower probability of capture by 238 U, compared to the faster neutrons that originally result from fission. This allows the use of low-enriched uranium or even natural uranium fuel in thermal reactors. The moder- ator is often also the coolant, such as water under high pressure to increase the boiling point. Fast reactors use fast neutrons to cause fission in the fuel. Fast reactors do not require a neutron moderator, and use less-moderating coolants. But maintaining a chain reaction in a fast reactor requires the fuel to be enriched to about 20% or more in fissile material. This is due to the relatively lower probability of fission versus capture by 238 U. Fast reactors have the potential to produce less transuranic waste because all actinides are fissionable with fast neutrons. Pressurized Water Reactors, Boling Water Reactors and Pressurized Heavy Water Reactors are the mainstay of world nuclear power programme as can be seen from Table 10.3 (IAEA, 2010). 90 Green Energy Technology, Economics and Policy Table 10.4 Nuclear fuel cycle stages and activities (Adapted from IAEA, 2009b) Sub-cycle Stage Activity FRONT END Uranium Mining and Milling Uranium Mining Uranium Ore Processing U Recovery from Phosphates Conversion Conversion to UO 2 Conversion to UO 3 Conversion to UF 4 Conversion to UF 6 Re-Conversion to U 3 O 8 (Depleted U) Conversion to U Metal Enrichment Uranium Enrichment Uranium Fuel Fabrication Re-conversion to UO 2 Powder Fuel Fabrication (U Pellet-Pin) Fuel Fabrication (U Assembly) Fuel Fabrication (Burnable Poison Pellet-Pin) Fuel Fabrication (Research Reactors) Fuel Fabrication (Pebble) IRRADIATION IN REACTORS BACK END Spent Fuel Reprocessing and Spent Fuel Reprocessing Recycling Re-Conversion to U 3 O 8 (Rep U) Co-conversion to MOX Powder Fuel Fabrication (MOX Pellet-Pin) Fuel Fabrication (MOX Assembly) Fuel Fabrication (RepU-ERU(Enriched Recycled uranium Pellet-Pin) Fuel Fabrication (RepU-ERU Assembly) Spent Fuel Storage AR Spent Fuel Storage AFR Wet Spent Fuel Storage AFR Dry Spent Fuel Storage Spent Fuel Conditioning Spent Fuel Conditioning Spent Fuel Disposal Spent Fuel Disposal 10.3 SUSTAINABLE NUCLEAR FUEL CYCLE OPTIONS The nuclear fuel cycle may be broadly defined as the set of processes and opera- tions needed to manufacture nuclear fuel, its irradiation in nuclear power reactors and storage, reprocessing, recycling or disposal (Table 10.4). The nuclear fuel cycle starts with uranium exploration and ends with disposal of the materials used and gen- erated during the cycle. Several nuclear fuel cycles can be considered depending on the type of reactor and the type of fuel used and whether or not the irradiated fuel is reprocessed and recycled. The Nuclear fuel cycle has been further subdivided into the front-end and the back- end sub-cycles. The front-end of the fuel cycle occurs before irradiation and the back- end begins with the discharge of spent fuel from the reactor (IAEA, 2009b). Nuclear power 91 If spent fuel is not reprocessed, the fuel cycle is referred to as an open fuel cycle (or a once-through fuel cycle); if the spent fuel is reprocessed, it is referred to as a closed fuel cycle. Choosing the ‘closed’ or ‘open’ fuel cycle is a matter of national policy. Some countries have adopted the ‘closed’ fuel cycle solution, and some others have chosen the ‘open’ fuel cycle. Combination of solutions or on hold (wait and see) is a position of other nuclear power countries. (IAEA, 2005a, b) In the open fuel cycle nuclear material passes through the reactor just once. After irradiation, the fuel is kept in at-reactor pools until it is sent to away from reactor storage. It is planned that the fuel will be conditioned and put into a final repository in this mode of operation. No final repositories for spent fuel have yet been established anywhere in the world. In the closed fuel cycle, the spent fuel is reprocessed to extract the remaining uranium and plutonium from the fission products and other actinides. The reprocessed uranium and plutonium is then reused in the reactors. This strategy has been adopted by some countries mainly in light water reactors in the form of mixed oxide (MOX) fuel. Another closed fuel cycle practice is the recycle of nuclear materials in fast reactors in which, reprocessed uranium and plutonium are used for production of fast reactor fuel. Such a reactor can produce more fissile plutonium than it consumes. In reprocessing stage, the fission products, minor actinides, activation products, and reprocessed uranium are separated from the reactor-grade plutonium, which can then be fabricated into MOX fuel. The proportion of the non-fissile even-mass isotopes of plutonium rises with recycle. So reuse plutonium from used MOX fuel beyond three recycles is not usually done in thermal reactors. This is not a limitation in fast reactors. 10.3.1 Thorium fuel cycle The most potential sustainable fuel cycle option for the future is that of thorium. Abundance of uranium and its relative ease of handling was the reason much attention was not paid in past in developing thorium fuel cycle. But the recent concerns about constraints in uranium supply well into future have promoted renewed attention to thorium. The historical thorium utilization details are given in Table 10.5. In thorium fuel cycle, the naturally abundant isotope of thorium, 232 Th, is fertile material which is transmuted into the fissile artificial uranium isotope 233 U which is the nuclear fuel. The sustained fission chain reaction could be started with existing 233 Uor some other fissile material such as 235 Uor 239 Pu. Subsequently a breeding cycle similar to but more efficient than that with 238 U– 239 Pu can be created (IAEA, 2005b). Thorium is at least 3–4 times more abundant in nature than all uranium isotopes and is fairly evenly spread on the surface of Earth. Unlike uranium, naturally occurring thorium consists of only a single isotope ( 232 Th) in significant quantities. Consequently, all mined thorium is useful in thermal reactors without the need for an enrichment process. Thorium based fuels exhibit several attractive nuclear properties relative to uranium- based fuels such as: • fertile conversion of thorium is more efficient in a thermal reactor. • fewer non-fissile neutron absorptions and improved neutron economy. • can be the basis for a thermal breeder reactor. 92 Green Energy Technology, Economics and Policy Thorium-based fuels also display favorable physical and chemical properties which improve reactor and repository performance. Compared to the predominant reactor fuel, uranium dioxide (UO 2 ), thorium dioxide (ThO 2 ) has a higher melting point, higher thermal conductivity, and lower coefficient of thermal expansion. Thorium dioxide also exhibits greater chemical stability. Because the 233 U produced in thorium fuels is inevitably contaminated with 232 U, thorium-based used nuclear fuel possesses inherent proliferation resistance. Elimina- tion of at least the transuranic portion of the nuclear waste problem is possible in thorium fuel cycle. But there are some long-lived actinides that constitute a long term radiological impact, especially 231 Pa. If thorium is used in an open fuel cycle (i.e. utilizing 233 U in-situ), higher burnup is necessary to achieve a favorable neutron economy. Although thorium dioxide has per- formed well at burnups of 170 000 MWd/t and 150 000MWd/t, there are challenges associated with achieving this burnup in light water reactors. The challenge associated with a once-through thorium fuel cycle is the comparatively long time scale over which 232 Th breeds to 233 U. The half-life of 233 Pa is about 27 days, which is an order of magnitude longer than the half-life of 239 Np in the uranium fuel cycle. As a result substantial 233 Pa builds into thorium-based fuels. 233 Pa is a significant neutron absorber, and although it eventually breeds into fissile 235 U, this requires two more neutron absorptions, which degrades neutron economy and increases the likelihood of transuranic production. If thorium is used in a closed fuel cycle in which 233 U is recycled, remote handling is necessary because of the high radiation dose resulting from the decay products of 232 U. This is also true of recycled thorium because of the presence of 228 Th, which is part of the 232 U decay sequence. Although there is substantial worldwide experience recycling uranium fuels (e.g. PUREX), similar technology for thorium (e.g. THOREX) is still under development. Historical thorium utilization in various reactors is given in Table 10.5. 10.3.2 Uranium resources and production Uranium is an element that is widely distributed within the earth’s crust. Its principal use is as the primary fuel for nuclear power reactors. Naturally occurring uranium is composed of about 99.3% 238 U, 0.7% 235 U and traces of 234 U. In order to use uranium in the ground, it has to be extracted from the ore and converted into a form which can be used in the nuclear fuel cycle. A deposit of uranium discovered by various exploration techniques is evaluated to determine the amounts of uranium materials that are extractable at specified costs. Uranium resources are the amounts of ore that are estimated to be recoverable at stated costs. IAEA Uranium 2007 Resources, Production and Demand (Red Book) reports that the total Identified Resources in 2007 is about 5 469 000 tonnes U in the <USD 130/kgU category (Table 10.6). Total Additionally Undiscovered Resources (Prog- nosticated Resources and Speculative Resources) amounts to another 10 500 000 tU (OECD/NEA-IAEA, 2008). The reported Identified Resources (∼5.5 million tonnes natural uranium) can last 83 years at the current rate of consumption of about 70 000 tonnes per year. Moreover, Table 10.5 Thorium utilization in different experimental and power reactors (Source IAEA, 2005b) Name and Country Type Power Fuel Operation period AVR, Germany HTGR, Experimental 15 MW(e) Th+ 235 U Driver Fuel, Coated fuel particles, 1967–1988 (Pebble bed reactor) Oxide & dicarbides THTR-300, Germany HTGR, Power (Pebble Type) 300 MW(e) Th+ 235 U, Driver Fuel, Coated fuel particles, 1985–1989 Oxide & dicarbides Lingen, Germany BWR Irradiation-testing 60 MW(e) Test Fuel (Th,Pu)O2 pellets Terminated in 1973 Dragon, UK OECD- HTGR, Experimental (Pin-in- 20 MWt Th+ 235 U Driver Fuel, Coated fuel particles, 1966–1973 Euratom also Sweden, Block Design) Oxide & Dicarbides Norway & Switzerland Peach Bottom, USA HTGR, Experimental 40 MW(e) Th+ 235 U Driver Fuel, Coated fuel particles, 1966–1972 (Prismatic Block) Oxide & dicarbides Fort St Vrain, USA HTGR, Power (Prismatic Block) 330 MW(e) Th+ 235 U Driver Fuel, Coated fuel particles, 1976–1989 Dicarbide MSRE ORNL, USA MSBR 7.5 MWt 233 U Molten Fluorides 1964–1969 Shippingport & Indian LWBR PWR, (Pin Assemblies) 100 MW(e), Th+ 233 U Driver Fuel, Oxide Pellets 1977–1982, 1962–1980 Point 1, USA 285 MW(e) SUSPOP/KSTR KEMA, Aqueous Homogenous 1 MWt Th+HEU, Oxide Pellets 1974–1977 Netherlands Suspension (Pin Assemblies) NRU & NRX, Canada MTR (Pin Assemblies) Th+ 235 U, Test Fuel Irradiation–testing of few fuel elements KAMINI; CIRUS; & MTR Thermal 30 kWt; 40 MWt; Al+ 233 U Driver Fuel,‘J’ rod of Th & ThO 2 , All three research reactors DHRUVA, India 100 MWt ‘J’ rod of ThO 2 in operation KAPS 1&2; KGS 1&2; PHWR, (Pin Assemblies) 220 MW(e) ThO 2 Pellets (For neutron flux flattening of Continuing in all new RAPS 2, 3&4, India initial core after start-up) PHWRs FBTR, India LMFBR, (Pin Assemblies) 40 MWt ThO 2 blanket In operation [...]... Total 302 000 344 000 319 000 40 0 000 132 000 54 000 44 000 45 2 000 18 000 100 000 33 000 75 000 300 000 2 573 000 Prognosticated Resources Th (tonnes) 330 000 40 0 000–500 000 – 2 74 000 132 000 32 000 128 000 – 130 000 280 000 81 000 – – 1 787–1 887 Table 10.8, are estimated to total about 4. 4 million tonnes Th (OECD/NEA-IAEA, 2008) The primary source of the world’s thorium is the rare-earth and thorium... operating reactors 1050 Total annual collective dose 105 46 0 1000 44 0 950 42 0 40 0 900 380 850 360 800 340 750 320 700 300 260 550 240 500 220 45 0 200 40 0 180 160 350 140 300 120 250 100 200 80 2005 2000 1995 1990 1985 1980 1975 0 1970 20 0 1965 40 50 1960 60 100 1957 150 Year Figure 10.6 Evolution of the total annual collective dose (man Sv) and number of operating reactors put into practice, the probability... produced using ocean and wastewater, and are biodegradable and relatively harmless to the environment Department of Energy, USA estimates that if algae fuel replaced all the petroleum fuel in the United States, it would require an area of 40 000 km2 This is less than 15% the area of corn harvested Marine energy encompasses wave energy and tidal energy obtained from oceans, seas, and other large bodies... wood processing; Energy crops: high yield crops grown specifically for energy applications; 112 Green Energy Technology, Economics and Policy Table 11.2.1 Gasification processes Process Products Remarks Pyrolysis H2 , CH4 , char Combustion CO2 , CO Gasification Water gas shift reaction CO, H2 CO2 , H2 Dependent on the properties of the carbonaceous material and determines the structure and composition... same amount of CO2 as a 40 0 MW coal power plant would produce and sending that CO2 through pipeline to Canada for enhanced oil recovery 11.3 M ARIN E EN ER GY Marine energy or ocean energy refers to the energy carried by ocean waves and tides The oceans represent a vast and largely untapped source of energy in the form of fluid flow (currents, waves, and tides) and thermal and salinity gradients There... reprocessed and 213 000 tHM are stored in spent fuel storage pools at reactors or in away-from-reactor (AFR) storage facilities AFR storage facilities are being regularly expanded both by adding modules to existing dry storage facilities and by building new facilities 98 Green Energy Technology, Economics and Policy Spent fuel discharged from reactors contains appreciable quantities of fissile (235 U and. .. have been applied in India to a large extent Most of the applications are 9 kWe systems used for water pumping and street lighting The open top, twin air entry, re-burn gasifier developed at Combustion, Gasification and 1 14 Green Energy Technology, Economics and Policy Table 11.2.2 Advantages and disadvantages of different types of gasifiers Gasifier Advantages Disadvantages Counter-current fixed bed... (particularly when methane is the primary feedstock used to produce the synthesis gas) Process conditions and catalyst composition 116 Green Energy Technology, Economics and Policy are usually chosen to favor higher order reactions (n>1) and thus minimize methane formation The process was invented in petroleum-poor but coal-rich Germany in the 1920s, to produce liquid fuels It was used in Germany and. .. nuclei fuse together to form a heavier nucleus and in doing so, release a large amount of energy Most design studies for fusion power plants involve using the fusion reactions to create heat, which is then used to operate a steam turbine, which drives generators to produce electricity (Atzeni and Meyer-ter-Vehn, 20 04) 100 Green Energy Technology, Economics and Policy Several fusion reactors have been built,... as a by-product of processing heavy-mineral sand deposits for titanium-, zirconium-, or tin-bearing minerals Worldwide thorium resources, which are listed by major deposit types in 96 Green Energy Technology, Economics and Policy Table 10.8 World resources of thorium Country Identified Resources Th (tonnes) Brazil Turkey India United States Norway Greenland Canada Australia South Africa Egypt Other . 302 000 330 000 Turkey 344 000 40 0 000–500 000 India 319 000 – United States 40 0 000 2 74 000 Norway 132 000 132 000 Greenland 54 000 32 000 Canada 44 000 128 000 Australia 45 2 000 – South Africa. (Atzeni and Meyer-ter-Vehn, 20 04) . 100 Green Energy Technology, Economics and Policy Several fusion reactors have been built, but as yet none has ’produced’ more thermal energy than electrical energy. as waste to be stored and ultimately disposed of in deep geological repositories. 84 Green Energy Technology, Economics and Policy Third generation reactors today recycle part of the fissile content