Engineering Materials 2 An Introduction to Microstructures, Processing and Design Engineering Materials 2 An Introduction to Microstructures, Processing and Design Second Edition by Michael F. Ashby and David R. H. Jones Department of Engineering, Cambridge University, England OXFORD AUCKLAND BOSTON JOHANNESBURG MELBOURNE NEW DELHI Butterworth-Heinemann Linacre House, Jordan Hill, Oxford OX2 8DP 225 Wildwood Avenue, Woburn, MA 01801-2041 A division of Reed Educational and Professional Publishing Ltd A member of the Reed Elsevier plc group First edition 1986 Reprinted with corrections 1988 Reprinted 1989, 1992 Second edition 1998 Reprinted 1999 © Michael F. Ashby and David R. H. Jones 1998 All rights reserved. No part of this publication may be reproduced in any material form (including photocopying or storing in any medium by electronic means and whether or not transiently or incidentally to some other use of this publication) without the written permission of the copyright holder except in accordance with the provisions of the Copyright, Designs and Patents Act 1988 or under the terms of a licence issued by the Copyright Licensing Agency Ltd, 90 Tottenham Court Road, London, England W1P 9HE. Applications for the copyright holder’s written permission to reproduce any part of this publication should be addressed to the publishers British Library Cataloguing in Publication Data A catalogue record for this book is available from the British Library Library of Congress Cataloguing in Publication Data A catalogue record for this book is available from the Library of Congress ISBN 0 7506 4019 7 Printed and bound in Great Britain by Biddles Ltd, Guildford and Kingd’s Lynn Contents General introduction ix A. Metals 1. Metals 3 the generic metals and alloys; iron-based, copper-based, nickel-based, aluminium-based and titanium-based alloys; design data 2. Metal structures 14 the range of metal structures that can be altered to get different properties: crystal and glass structure, structures of solutions and compounds, grain and phase boundaries, equilibrium shapes of grains and phases 3. Equilibrium constitution and phase diagrams 25 how mixing elements to make an alloy can change their structure; examples: the lead–tin, copper–nickel and copper–zinc alloy systems 4. Case studies in phase diagrams 34 choosing soft solders; pure silicon for microchips; making bubble-free ice 5. The driving force for structural change 46 the work done during a structural change gives the driving force for the change; examples: solidification, solid-state phase changes, precipitate coarsening, grain growth, recrystallisation; sizes of driving forces 6. Kinetics of structural change: I – diffusive transformations 57 why transformation rates peak – the opposing claims of driving force and thermal activation; why latent heat and diffusion slow transformations down 7. Kinetics of structural change: II – nucleation 68 how new phases nucleate in liquids and solids; why nucleation is helped by solid catalysts; examples: nucleation in plants, vapour trails, bubble chambers and caramel 8. Kinetics of structural change: III – displacive transformations 76 how we can avoid diffusive transformations by rapid cooling; the alternative – displacive (shear) transformations at the speed of sound 9. Case studies in phase transformations 89 artificial rain-making; fine-grained castings; single crystals for semiconductors; amorphous metals 10. The light alloys 100 where they score over steels; how they can be made stronger: solution, age and work hardening; thermal stability 11. Steels: I – carbon steels 113 structures produced by diffusive changes; structures produced by displacive changes (martensite); why quenching and tempering can transform the strength of steels; the TTT diagram 12. Steels: II – alloy steels 125 adding other elements gives hardenability (ease of martensite formation), solution strengthening, precipitation strengthening, corrosion resistance, and austenitic (f.c.c.) steels 13. Case studies in steels 133 metallurgical detective work after a boiler explosion; welding steels together safely; the case of the broken hammer 14. Production, forming and joining of metals 143 processing routes for metals; casting; plastic working; control of grain size; machining; joining; surface engineering B. Ceramics and glasses 15. Ceramics and glasses 161 the generic ceramics and glasses: glasses, vitreous ceramics, high- technology ceramics, cements and concretes, natural ceramics (rocks and ice), ceramic composites; design data 16. Structure of ceramics 167 crystalline ceramics; glassy ceramics; ceramic alloys; ceramic micro- structures: pure, vitreous and composite 17. The mechanical properties of ceramics 177 high stiffness and hardness; poor toughness and thermal shock resistance; the excellent creep resistance of refractory ceramics vi Contents 18. The statistics of brittle fracture and case study 185 how the distribution of flaw sizes gives a dispersion of strength: the Weibull distribution; why the strength falls with time (static fatigue); case study: the design of pressure windows 19. Production, forming and joining of ceramics 194 processing routes for ceramics; making and pressing powders to shape; working glasses; making high-technology ceramics; joining ceramics; applications of high-performance ceramics 20. Special topic: cements and concretes 207 historical background; cement chemistry; setting and hardening of cement; strength of cement and concrete; high-strength cements C. Polymers and composites 21. Polymers 219 the generic polymers: thermoplastics, thermosets, elastomers, natural polymers; design data 22. The structure of polymers 228 giant molecules and their architecture; molecular packing: amorphous or crystalline? 23. Mechanical behaviour of polymers 238 how the modulus and strength depend on temperature and time 24. Production, forming and joining of polymers 254 making giant molecules by polymerisation; polymer “alloys”; forming and joining polymers 25. Composites: fibrous, particulate and foamed 263 how adding fibres or particles to polymers can improve their stiffness, strength and toughness; why foams are good for absorbing energy 26. Special topic: wood 277 one of nature’s most successful composite materials D. Designing with metals, ceramics, polymers and composites 27. Design with materials 289 the design-limiting properties of metals, ceramics, polymers and composites; design methodology Contents vii 28. Case studies in design 296 1. Designing with metals: conveyor drums for an iron ore terminal 296 2. Designing with ceramics: ice forces on offshore structures 303 3. Designing with polymers: a plastic wheel 308 4. Designing with composites: materials for violin bodies 312 Appendix 1 Teaching yourself phase diagrams 320 Appendix 2 Symbols and formulae 370 Index 377 viii Contents General introduction Materials are evolving today faster than at any time in history. Industrial nations regard the development of new and improved materials as an “underpinning tech- nology” – one which can stimulate innovation in all branches of engineering, making possible new designs for structures, appliances, engines, electrical and electronic de- vices, processing and energy conservation equipment, and much more. Many of these nations have promoted government-backed initiatives to promote the development and exploitation of new materials: their lists generally include “high-performance” composites, new engineering ceramics, high-strength polymers, glassy metals, and new high-temperature alloys for gas turbines. These initiatives are now being felt throughout engineering, and have already stimulated design of a new and innovative range of consumer products. So the engineer must be more aware of materials and their potential than ever before. Innovation, often, takes the form of replacing a component made of one mater- ial (a metal, say) with one made of another (a polymer, perhaps), and then redesigning the product to exploit, to the maximum, the potential offered by the change. The engineer must compare and weigh the properties of competing materials with pre- cision: the balance, often, is a delicate one. It involves an understanding of the basic properties of materials; of how these are controlled by processing; of how materials are formed, joined and finished; and of the chain of reasoning that leads to a successful choice. This book aims to provide this understanding. It complements our other book on the properties and applications of engineering materials,* but it is not necessary to have read that to understand this. In it, we group materials into four classes: Metals, Ceramics, Polymers and Composites, and we examine each in turn. In any one class there are common underlying structural features (the long-chain molecules in poly- mers, the intrinsic brittleness of ceramics, or the mixed materials of composites) which, ultimately, determine the strengths and weaknesses (the “design-limiting” properties) of each in the engineering context. And so, as you can see from the Contents list, the chapters are arranged in groups, with a group of chapters to describe each of the four classes of materials. In each group we first introduce the major families of materials that go to make up each materials class. We then outline the main microstructural features of the class, and show how to process or treat them to get the structures (really, in the end, the properties) that we want. Each group of chapters is illustrated by Case Studies designed to help you * M. F. Ashby and D. R. H. Jones, Engineering Materials 1: An Introduction to their Properties and Applications, 2nd edition, Butterworth-Heinemann, 1996. understand the basic material. And finally we look at the role of materials in the design of engineering devices, mechanisms or structures, and develop a methodology for materials selection. One subject – Phase Diagrams – can be heavy going. We have tried to overcome this by giving a short programmed-learning course on phase dia- grams. If you work through this when you come to the chapter on phase diagrams you will know all you need to about the subject. It will take you about 4 hours. At the end of each chapter you will find a set of problems: try to do them while the topic is still fresh in your mind – in this way you will be able to consolidate, and develop, your ideas as you go along. To the lecturer This book has been written as a second-level course for engineering students. It pro- vides a concise introduction to the microstructures and processing of materials (metals, ceramics, polymers and composites) and shows how these are related to the properties required in engineering design. It is designed to follow on from our first-level text on the properties and applications of engineering materials,* but it is completely self- contained and can be used by itself. Each chapter is designed to provide the content of a 50-minute lecture. Each block of four or so chapters is backed up by a set of Case Studies, which illustrate and con- solidate the material they contain. There are special sections on design, and on such materials as wood, cement and concrete. And there are problems for the student at the end of each chapter for which worked solutions can be obtained separately, from the publisher. In order to ease the teaching of phase diagrams (often a difficult topic for engineering students) we have included a programmed-learning text which has proved helpful for our own students. We have tried to present the material in an uncomplicated way, and to make the examples entertaining, while establishing basic physical concepts and their application to materials processing. We found that the best way to do this was to identify a small set of “generic” materials of each class (of metals, of ceramics, etc.) which broadly typified the class, and to base the development on these; they provide the pegs on which the discussion and examples are hung. But the lecturer who wishes to draw other materials into the discussion should not find this difficult. Acknowledgements We wish to thank Prof. G. A. Chadwick for permission to reprint Fig. A1.34 (p. 340) and K. J. Pascoe and Van Nostrand Reinhold Co. for permission to reprint Fig. A1.41 (p. 344). x General introduction * M. F. Ashby and D. R. H. Jones, Engineering Materials 1: An Introduction to their Properties and Applications, 2nd edition, Butterworth-Heinemann, 1996. [...]...  12 Engineering Materials 2 Table 1.6 Properties of the generic metals Metal Density (Mg m −3) Young’s modulus (GPa) Yield strength (MPa) 7.9 7.9 7.8 7.8 7.8 7.4 21 1 21 0 21 0 20 3 21 5 1 52 50 22 0 350–1600 29 0–1600 170–1600 50–400 1 020 (1330) 750–1060 (980–1380) 1500 (20 00) 8.9 8.4 8.4 130 105 120 75 20 0 20 0 22 0 350 350 Nickel Monels Superalloys 320 0 ( 420 0) 3000 (3900) 5000 (6500) 8.9 8.9 7.9 21 4 185 21 4... 1 120 385 397 121 85 17 20 19 >100 >100 >100 1 728 1600 1550 450 420 450 89 22 11 13 14 12 0.1–0.5 0.1–0.45 0.1–0 .25 0.1–0.35 0.1–0.17 0.01–0.15 45 45 10–50 30–40 20 –70 5–30 933 915 860 890 890 860 917 24 0 180 130 150 140 24 24 24 22 24 20 0 .25 0.1–0 .2 50–80 1940 1 920 530 610 22 6 9 8 693 456 650 390 120 31 420 110 27 0.4 0.5 0 .2 0.4 0.07–0.15 wear resistance, thermal conductivity, electrical conductivity... 0.405 0 .22 9 0 .29 8 0 .28 9 0 .25 1 0.3 62 0.408 0. 320 0.384 0 .28 7 0.376 0.495 0. 321 0.891 0.315 0.3 52 0.330 0.389 0.3 92 0.380 0.409 0.331 0.346 0 .29 5 0.317 0.303 0.365 0 .26 7 0. 323 c 0.358 0.5 62 0.409 0.506 0.606 0. 521 0.553 0.468 0.573 0.495 0.515 Fig 2. 1 Some metals have more than one crystal structure The most important examples of this polymorphism are in iron and titanium 15 16 Engineering Materials 2 back... Series 20 00 Series 5000 Series 7000 Series Casting alloys 910 910 1100 1000 1100 1100 (1180) (1180) (1430) (1300) (1430) (1430) 2. 7 2. 7 2. 8 2. 7 2. 8 2. 7 71 71 71 71 71 71 25 – 125 28 –165 20 0–500 40–300 350–600 65–350 70–135 70–180 300–600 120 –430 500–670 130–400 Titanium Ti–6 A14 V 4630 (6 020 ) 5780 (7510) 4.5 4.4 120 115 170 800–900 24 0 900–1000 Zinc Lead–tin solder Diecasting alloy 330 (430) 20 00 (26 00)... m1 /2) 13 Melting temperature (K) Specific heat (J kg −1 K −1) Thermal conductivity (W m −1 K −1) Thermal expansion coefficient (MK −1) 0.3 0 .21 0.1–0 .2 0.1–0 .2 0.1–0.5 0–0.18 80 140 20 –50 50–170 50–170 6 20 1809 1765 1570 1750 1680 1403 456 4 82 460 460 500 78 60 40 40 12 30 12 12 12 12 10–18 0.5–0.9 0.5 0.5 >100 30–100 30–100 1356 1190 1 120 385 397 121 85 17 20 19 >100 >100 >100 1 728 1600 1550 450 420 ... steels High-alloy steels Cast irons Cost (UK£ (US$) tonne −1) 100 20 0 23 0 150 180 25 0 1100–1400 120 Copper Brasses Bronzes (140) (26 0–300) (20 0) (23 0–330) (1400–1800) (160) Tensile strength (MPa) 20 0 430 650 20 00 420 20 00 460–1700 10–800 120 28 0–330 Further reading Smithells’ Metals Reference Book, 7th edition, Butterworth-Heinemann, 19 92 (for data) ASM Metals Handbook, 10th edition, ASM International,... very big increases in strength Other important compounds are Ni3Al, Ni3Ti, Mo2C and TaC (in super-alloys) and Fe3C (in carbon steels) Figure 2. 3 shows the crystal structure of CuAl2 As with most compounds, it is quite complicated 18 Engineering Materials 2 Fig 2. 3 The crystal structure of the “intermetallic” compound CuAl2 The structures of compounds are usually more complicated than those of pure... tetrakaidecahedra when the grain-boundary energy is the dominating influence 22 Engineering Materials 2 Fig 2. 7 Many metals are made up of two phases This figure shows some of the shapes that they can have when boundary energies dominate To keep things simple we have sectioned the tetrakaidecahedral grains in the way that we did in Fig 2. 6(b) Note that Greek letters are often used to indicate phases We have... extent, be predicted Background reading M F Ashby and D R H Jones, Engineering Materials I, 2nd edition, Butterworth-Heinemann, 1996 Further reading D A Porter and K E Easterling, Phase Transformations in Metals and Alloys, 2nd edition, Chapman and Hall, 19 92 G A Chadwick, Metallography of Phase Transformations, Butterworth, 19 72 Problems 2. 1 Describe, in a few words, with an example or sketch where appropriate,... around 22 0 MPa, is more than strong enough It is also easy to cut, bend or machine to shape And last, but not least, it is cheap 4 Engineering Materials 2 Fig 1.1 A fully working model, one-sixth full size, of a steam traction engine of the type used on many farms a hundred years ago The model can pull an automobile on a few litres of water and a handful of coal But it is also a nice example of materials . R. H. Jones, Engineering Materials 1: An Introduction to their Properties and Applications, 2nd edition, Butterworth-Heinemann, 1996. Metals 1 A. Metals 2 Engineering Materials 2 Metals 3 Chapter. cements C. Polymers and composites 21 . Polymers 21 9 the generic polymers: thermoplastics, thermosets, elastomers, natural polymers; design data 22 . The structure of polymers 22 8 giant molecules and their. Engineering Materials 2 An Introduction to Microstructures, Processing and Design Engineering Materials 2 An Introduction to Microstructures, Processing