[...]... potential of adsorbed species j kJ/mol standard chemical potential of specie j in the gas phase electrochemical potential of electrons electrochemical potential of electrons in the reference electrode electrochemical potential of electrons in the working catalyst-electrode electrochemical potential of oxygen ions in YSZ electrochemical potential of oxygen ions on the gas exposed metal electrode surface Fermi... Modeling of Electrochemical Promotion 11.3.1.3 Mathematical Modeling of Metal-Support Interactions 487 490 500 501 501 503 507 CONTENTS xxxi 11.3.2 Numerical Examples 11.3.2.1 Electrochemically Promoted Films 11.3.2.2 Dispersed Supported Catalysts 11.3.3 Summary of Modelling Results 11.4 Interrelation of Promotion, Electrochemical Promotion and Metal-Support Interactions: The Double-Layer Model of Catalysis. .. Catalyst 12.2.2.2 Electrochemical Promotion of an Industrial Oxidation Catalyst Bipolar Electrochemical Promotion 12.3 12.3.1 Electrochemical Promotion of Oxidation on Pt Using a Bipolar Design Oxidation on Pt 12.3.2 Electrochemical Promotion of Using Multi-Stripe and Multi-Dot Bipolar Catalysts 12.3.3 Electrochemical Promotion Using a Bipolar Monolithic Reactor 12.3.4 Electrochemical Promotion of Particulate... The terms electrochemical promotion (EP), electrochemical promotion of catalysis (EPOC) and in situ controlled promotion (ICP) have been also proposed, as synonyms to the NEMCA effect, for the description of the electrochemical activation of heterogeneous catalysis Although the term “non-Faradaic” process has been used for many decades to describe transient electrochemical processes where part of the... the electrochemical community Earlier applications of solid electrolytes in catalysis, including solid electrolyte potentiometry and electrocatalysis have been reviewed previously The present book is the first on the electrochemical activation of catalytic reactions and is addressed both to the electrochemical and catalytic communities We stress both the electrochemical and catalytic aspects of electrochemical. .. constant mass of electron mass of proton Avogadro’s number permittivity of free space absolute zero of temperature Pi Value -2 73.15°C 3.14159265358979 NOMENCLATURE xxi CONTENTS Chapter 1 Introduction, Brief History and Basic Concepts 1.1 1.2 1.3 The Phenomenon of Electrochemical Promotion Basic Concepts and Terminology Structure of This Book 1 8 10 Chapter 2 Promotion in Heterogeneous Catalysis 2.1... Solutions Production of Ammonium Polysulfide Oxidation in Melts 475 476 481 482 482 Chapter 11 Electrochemical Promotion and Metal-Support Interactions 11.1 Metal-Support Interactions 11.2 Experimental Confirmation of the Mechanistic Equivalence of NEMCA and Metal-Support Interactions 11.3 Mathematical Modeling: Dimensionless Numbers Governing Electrochemical Promotion and Metal-Support Interactions... diameter energy activation energy catalytic activation energy chemisorption bond strength binding energy binding energy of core level electrons binding energy of core level electrons of species in the electrolyte denotes energy at bottom of the conduction band activation energy of desorption electrostatic energy defined in Eq (7.21) Fermi level kinetic energy denotes energy at top of valence band electric... readers, including those not frequently using electrochemical, catalytic and surface science methodology and terminology 1.2 BASIC CONCEPTS AND TERMINOLOGY The reader must have already identified some of the basic concepts which play a key role in understanding the electrochemical activation of heterogeneous catalysis: catalysis, electrocatalysis, promotion, electrochemical promotion, spillover, backspillover... Presence of Oxygen 8.1.4.4 Electrochemical Promotion of a Classically Promoted Rh Catalyst for NO Reduction by CO in Presence of The Use of Conductors 8.2.1 CO Oxidation on The Use of Mixed Conductors Oxidation on 8.3.1 Oxidation on 8.3.2 390 393 393 398 402 403 403 406 408 409 410 411 411 411 412 414 417 420 420 420 420 428 Chapter 9 Electrochemical Promotion with Cationic Conductors 9.1 The Use of Alkali . alt="" Electrochemical Activation of Catalysis Promotion, Electrochemical Promotion, and Metal-Support Interactions Costas G. Vayenas Symeon Bebelis University of Patras University of Patras Patras,. 0-3 0 6-4 755 1-0 Print ISBN: 0-3 0 6-4 671 9-4 2002 Kluwer Academic Publishers New York, Boston, Dordrecht, London, Moscow Print ©2001 Kluwer Academic/Plenum Publishers All rights reserved No part of. gas phase electrochemical potential of electrons electrochemical potential of electrons in the reference electrode electrochemical potential of electrons in the working catalyst-electrode electrochemical