[...]... 410 411 412 418 Chapter 9: The Plug Flow Reactor 9.1 9.2 9.3 The Continuity, Energy, and Momentum Equations Kinetic Studies Using a Tubular Reactor with Plug Flow 9.2.1 Kinetic Analysis of Isothermal Data 9.2.2 Kinetic Analysis of Nonisothermal Data Design and Simulation of Tubular Reactors with Plug Flow 9.3.1 Adiabatic Reactor with Plug Flow 9.3.2 Design and Simulation of Non-Isothermal Cracking... Application of RTD to Reactors 694 Example 12.6.4.A First Order Reaction(s) in 696 Isothermal Completely Mixed Reactors, Plug Flow Reactors, and Series of Completely Stirred Tanks Example 12.6.4.B Second Order Bimolecular 698 Reaction in Isothermal Completely Mixed Reactors and in a Succession of Isothermal Plug Flow and Completely Mixed Reactors: Completely Macro-Mixed versus Completely Macro- and MicroMixed... Cracker and Regenerator 753 753 756 758 762 763 765 Chapter 14: Multiphase Flow Reactors 14.1 14.2 14.3 Types of Multiphase Flow Reactors 780 14.1.1 Packed Columns 780 14.1.2 Plate Columns 782 14.1.3 Empty Columns 782 14.1.4 Stirred Vessel Reactors 783 14.1.5 Miscellaneous Reactors 783 Design Models for Multiphase Flow Reactors 784 14.2.1 Gas and Liquid Phases Completely Mixed 784 14.2.2 Gas and Liquid... Catalytic Reactors with 813 Cocurrent Upflow Upflow Packed Bubble Reactors 14.3.4 Plate Columns 815 Example 14.3.4.A The Simulation or Design of a 818 Plate Column for Absorption and Reaction Example 14.3.4.B The Absorption of CO2 in an 822 Aqueous Solution of Mono- and Diethanolamine (MEA and DEA) 14.3.5 Spray Towers 827 14.3.6 Bubble Reactors 827 Example 14.3.6.A Simulation of a Bubble Column 830 Reactor. .. Pressure Drop in Packed Beds 11.5.2 Design of a Fixed Bed Reactor According to the OneDimensional Pseudohomogeneous Model 11.5.3 Runaway Criteria Example 11.5.3.A Application of the First Runaway Criterion of Van Welsenaere and Froment 11.5.4 The Multibed Adiabatic Reactor 11.5.5 Fixed Bed Reactors with Heat Exchange Between the Feed and Effluent or Between the Feed and Reacting Gas “Autothermal Operation”...Contents — Chemical Reactor Analysis and Design, Third edition G.F Froment, K.B Bischoff, J De Wilde Chapter 1: Elements of Reaction Kinetics 1.1 1.2 1.3 1.4 1.5 1.6 1.7 Definitions of Chemical Rates 1.1.1 Rates of Disappearance of Reactants and of Formation of Products 1.1.2 The Rate of a Reaction Rate Equations 1.2.1 General... Models for Reactors with Complex Flow 699 Patterns 12.7.1 Multi-Zone Models 699 12.7.2 Axial Dispersion and Tanks-in-Series Models 703 Chapter 13: Fluidized Bed and Transport Reactors 13.1 13.2 13.3 13.4 13.5 13.6 13.7 13.8 Introduction Technological Aspects of Fluidized Bed and Riser Reactors 13.2.1 Fluidized Bed Catalytic Cracking 13.2.2 Riser Catalytic Cracking Some Features of the Fluidization and Transport... 439 441 Chapter 10: The Perfectly Mixed Flow Reactor 10.1 10.2 10.3 10.4 Introduction 453 Mass and Energy Balances 454 10.2.1 Basic Equations 454 10.2.2 Steady-State Reactor Design 455 Design for Optimum Selectivity in Simultaneous Reactions 461 10.3.1 General Considerations 461 10.3.2 Polymerization in Perfectly Mixed Flow Reactors 468 Stability of Operation and Transient Behavior 471 10.4.1 Stability... Oscillations in a Mixed 481 Reactor for the Vapor-Phase Chlorination of Methyl Chloride Chapter 11: Fixed Bed Catalytic Reactors PART ONE INTRODUCTION 11.1 The Importance and Scale of Fixed Bed Catalytic Processes 11.2 Factors of Progress: Technological Innovations and Increased Fundamental Insight 11.3 Factors Involved in the Preliminary Design of Fixed Bed Reactors 11.4 Modeling of Fixed Bed Reactors 503 PART... mixture Weber number,  L L ² d p / Ω²  L Wj amount of catalyst in bed j of a multibed Wo , W p , adiabatic reactor cost of reactor idle time, reactor charging time WQ , WR reactor discharging time and of reaction time wij weighting factor in objective function (Chapters 1 and 2) wj x price per kmole of chemical species Aj fractional conversion $ kg $/s $/kmol xii x A , xB , x j fractional conversion of . Froment, Gilbert F. Chemical reactor analysis and design. 3rd ed. / Gilbert Froment, Juray DeWilde, and Kenneth Bischoff. p. cm. Includes bibliographical references and index. ISBN 978-0-470-56541-4. (with D.M. Himmelblau) (1968); and Chemical Reactor Analysis and Design , (with G.F. Froment) (1979). He was elected to the National Academy of Engineering in 1988, and he received the 1972 Ebert. Catholique de Louvain. This is the Third Edition of Chemical Reactor Analysis and Design. The first was published by Wiley in 1979 and the second, after a substantial revision, in 1990.