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HIGH PERFORMANCE
POLYMERS –
POLYIMIDES BASED –
FROM CHEMISTRY TO
APPLICATIONS
Edited by Marc Jean Médard Abadie
High Performance Polymers – Polyimides Based – From Chemistry to Applications
http://dx.doi.org/10.5772/2834
Edited by Marc Jean Médard Abadie
Contributors
C. Aguilar-Lugo, A.L. Perez-Martinez, D. Guzman-Lucero, D. Likhatchev, L. Alexandrova, S.
Diaham, M L. Locatelli, R. Khazaka, Evgenia Minko, Petr Sysel, Martin Spergl, Petra Slapakova,
Anton Georgiev, Dean Dimov, Erinche Spassova, Jacob Assa, Peter Dineff, Gencho Danev,
Shie-Chang Jeng, Shug-June Hwang, Takayuki Ishizaka, Hitoshi Kasai, Guangming Gong,
Juntao Wu, Lutang Wang, Nian Fang, Zhaoming Huang, Andreea Irina Barzic, Iuliana Stoica,
Camelia Hulubei, Aziz Paşahan, A.A. Périchaud, R.M. Iskakov, Andrey Kurbatov,
T. Z. Akhmetov, O.Y. Prokohdko, Irina V. Razumovskaya, Sergey L. Bazhenov, P.Y. Apel,
V. Yu. Voytekunas, M.J.M. Abadie
Published by InTech
Janeza Trdine 9, 51000 Rijeka, Croatia
Copyright © 2012 InTech
All chapters are Open Access distributed under the Creative Commons Attribution 3.0 license,
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Notice
Statements and opinions expressed in the chapters are these of the individual contributors and
not necessarily those of the editors or publisher. No responsibility is accepted for the accuracy
of information contained in the published chapters. The publisher assumes no responsibility for
any damage or injury to persons or property arising out of the use of any materials,
instructions, methods or ideas contained in the book.
Publishing Process Manager Marina Jozipovic
Typesetting InTech Prepress, Novi Sad
Cover InTech Design Team
First published December, 2012
Printed in Croatia
A free online edition of this book is available at www.intechopen.com
Additional hard copies can be obtained from orders@intechopen.com
High Performance Polymers – Polyimides Based – From Chemistry to Applications,
Edited by Marc Jean Médard Abadie
p. cm.
ISBN 978-953-51-0899-3
Contents
Preface IX
Section 1 Chemistry 1
Chapter 1 Polyimides Based on
4-4’-Diaminotriphenylmethane (DA-TPM) 3
C. Aguilar-Lugo, A.L. Perez-Martinez, D. Guzman-Lucero,
D. Likhatchev and L. Alexandrova
Chapter 2 BPDA-PDA Polyimide: Synthesis, Characterizations,
Aging and Semiconductor Device Passivation 15
S. Diaham, M L. Locatelli and R. Khazaka
Chapter 3 Hyperbranched Polyimides Prepared from
4,4´,4´´-Triaminotriphenylmethane and Mixed
Matrix Materials Based on Them 37
Evgenia Minko, Petr Sysel, Martin Spergl, Petra Slapakova
Section 2 Chemical and Physical Properties 63
Chapter 4 Chemical and Physical Properties of Polyimides:
Biomedical and Engineering Applications 65
Anton Georgiev, Dean Dimov, Erinche Spassova,
Jacob Assa, Peter Dineff and Gencho Danev
Section 3 Applications 85
Chapter 5 Controlling the Alignment of Polyimide
for Liquid Crystal Devices 87
Shie-Chang Jeng and Shug-June Hwang
Chapter 6 Fabrication of Polyimide Porous
Nanostructures for Low-k Materials 105
Takayuki Ishizaka and Hitoshi Kasai
Chapter 7 Novel Polyimide Materials Produced by Electrospinning 127
Guangming Gong and Juntao Wu
VI Contents
Chapter 8 Polyimide-Coated Fiber Bragg Grating Sensors
for Humidity Measurements 145
Lutang Wang, Nian Fang and Zhaoming Huang
Chapter 9 Semi-Alicyclic Polyimides:
Insights into Optical Properties and Morphology
Patterning Approaches for Advanced Technologies 167
Andreea Irina Barzic, Iuliana Stoica and Camelia Hulubei
Chapter 10 Sensor Applications of Polyimides 199
Aziz Paşahan
Chapter 11 Auto-Reparation of Polyimide Film Coatings for
Aerospace Applications Challenges & Perspectives 215
A.A. Périchaud, R.M. Iskakov, Andrey Kurbatov, T. Z. Akhmetov,
O.Y. Prokohdko, Irina V. Razumovskaya, Sergey L. Bazhenov,
P.Y. Apel, V. Yu. Voytekunas and M.J.M. Abadie
Preface
The term “High Performance Polymers” covers a large number of organic materials.
Some consider the thermal stability as a criterion of high performance and consider
that polymers are able to sustain long-term service at 180°C and are termed as “High
Temperature Polymers”. Others referred to as “Heat Resistant Polymers” whose
macromolecular backbone is constituted by alternate moieties of aromatic rings and
heterocyclic units which is represented by Polyimides and derivatives.
Dr. Cyrus E. Sroog, at E.I. DuPont de Nemours and Company, Wilmington DE, was the
precursor of high performance organic materials by developing a polymer based on the
polycondensation of pyromelitic acid dianhydride and oxydianiline, universally known
as the “PMDA-ODA” polyimide. This new concept of “polyheterocyclisation” was at the
origin of an impressive series of new high performance polymers.
For the last three decades, increasing need in the high technology industries (space,
micro and nano electronics, civil transportation, planes, automotive, membranes, fuel
cells, etc.) has been the driving force for the development of new polymeric systems
and materials combining both thermal mechanical and temperature resistance and also
properties others such as lightweight, high corrosion resistance, good wear properties,
dimensional stability, low flammability, separation properties, moisture resistance,
insulating properties and ability to be transformed with conventional equipment.
In fact all these properties were unavailable in conventional materials but may be
covered by aromatic and heterocyclic linear and thermosetting resins such as: acetylene
terminated resins, bismaleimides, polyetherimides, polyamide-imides,
polybenzimidazoles, polyimides, polyetherketones, polyphenylquinoxalines,
polyphenylensulfides, polysulfones & derivatives, polystyrylpyridines, fluoropolymers,
silicones, etc.
The feature of polyimides and other heterocyclic polymers are now well-established
and used for long term temperature durability in the range of 250 – 350°C.
New structures coming from the chemical modifications of the heterocyclic backbones
or from the creation of new architectures are under development for advanced
technologies for the future. Some new chemical structures based on Polyimides and
different applications are presented.
X Preface
This book will review synthesis, mechanisms, ultimate properties, physico-chemical
properties, processing and applications of such high performance materials needed in
advanced technologies. It presents interdisciplinary papers on the state of knowledge
of each topic under consideration through a combination of overviews and original
unpublished research.
The volume contains eleven chapters by 41 authors from 11 countries. The book is
divided into three sections as follow:
- Chemistry highlighting new chemical architectures – Chapters I to III
- Chemical and Physical Properties (Review) – Chapter IV
- Applications to :
o Liquid Crystal Devices – Chapter V
o Low-k – Chapter VI
o Polyimides Fibers and Nano-fibers – Chapters VII and VIII
o Optical Properties – Chapter IX
o Sensors – Chapter X
o Self-healing of Films – Chapter XI.
I would like to dedicate this book on “High Performance Polymers - Polyimides Based
- From Chemistry to Applications” to Professor Alexander L’vovich Russanov known
as Shura, and his team from Institute A. N. Nesmeyanov INEOS, Russian Academy of
Science, Moscow. His contribution to polyheterocyclic polymers is immense by the
originality of the chemistry developed and also by the novelty brought to the
Polyimide family and derivatives. Shura has been for nearly thirty years my cheerful
companion and during this period I was impressed not only by his creative chemistry
but also by his sense of humor and his optimism. For sure, the scientific community
will miss him, his competence and joviality.
Prof. Marc Jean Médard Abadie
POLYTECH’ Montpellier - Université Montpellier; ICGM – AIME,
France
Nanyang Technological University, School of Materials Science,
Singapore
. HIGH PERFORMANCE
POLYMERS –
POLYIMIDES BASED –
FROM CHEMISTRY TO
APPLICATIONS
Edited by Marc Jean Médard Abadie
High Performance. hard copies can be obtained from orders@intechopen.com
High Performance Polymers – Polyimides Based – From Chemistry to Applications,
Edited by Marc
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