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Lecture Notes in Physics
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R. Beig, Wien, Austria
J. Ehlers, Potsdam, Germany
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urich, Switzerland
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urich, Switzerland
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Klaus R. Mecke Dietrich Stoyan (Eds.)
Statistical Physics
and Spatial Statistics
The Art of Analyzing and Modeling
Spatial Structures and Pattern Formation
13
Editors
KlausR.Mecke
Fachbereich Physik
Bergische Universit
¨
at Wuppertal
42097 Wuppertal, Germany
Dietrich Stoyan
Institut f
¨
ur Stochastik
TU Bergakademie Freiberg
09596 Freiberg, Germany
Library of Congress Cataloging-in-Publication Data applied for.
Die Deutsche Bibliothek - CIP-Einheitsaufnahme
Statistical physics and spatial statistics : the art of analyzing and
modeling spatial structures and pattern formation / Klaus R. Mecke ;
Dietrich Stoyan (ed.). - Berlin ; Heidelberg ; New York ; Barcelona ;
HongKong;London;Milan;Paris;Singapore;Tokyo:Springer,
2000
(Lecture notes in physics ; Vol. 554)
(Physics and astronomy online library)
ISBN 3-540-67750-X
ISSN 0075-8450
ISBN 3-540-67750-X Springer-Verlag Berlin Heidelberg New York
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Preface
Modern physics is confronted with a large variety of complex spatial structures;
almost every research group in physics is working with spatial data. Pattern for-
mation in chemical reactions, mesoscopic phases of complex fluids such as liquid
crystals or microemulsions, fluid structures on planar substrates (well-known
as water droplets on a window glass), or the large-scale distribution of galax-
ies in the universe are only a few prominent examples where spatial structures
are relevant for the understanding of physical phenomena. Numerous research
areas in physics are concerned with spatial data. For example, in high energy
physics tracks in cloud chambers are analyzed, while in gamma ray astronomy
observational information is extracted from point patterns of Cherenkov photons
hitting a large scale detector field. A development of importance to physics in
general is the use of imaging techniques in real space. Methods such as scanning
microscopy and computer tomography produce images which enable detailed
studies of spatial structures.
Many research groups study non-linear dynamics in order to understand
the time evolution of complex patterns. Moreover, computer simulations yield
detailed spatial information, for instance, in condensed matter physics on config-
urations of millions of particles. Spatial structures also derive from fracture and
crack distributions in solids studied in solid state physics. Furthermore, many
physicists and engineers study transport properties of disordered materials such
as porous media.
Because of the enormous amount of information in patterns, it is difficult
to describe spatial structures through a finite number of parameters. However,
statistical physicists need the compact description of spatial structures to find
dynamical equations, to compare experiments with theory, or to classify patterns,
for instance. Thus they should be interested in spatial statistics, which provides
the tools to develop and estimate statistically such characteristics. Nevertheless,
until now, the use of the powerful methods provided by spatial statistics such
as mathematical morphology and stereology have been restricted to medicine
and biology. But since the volume of spatial information is growing fast also in
physics and material science, physicists can only gain by using the techniques
developed in spatial statistics.
The traditional approach to obtain structure information in physics is Fourier
transformation and calculation of wave-vector dependent structure functions.
Surely, as long as scattering techniques were the major experimental set-up in
VI Preface
order to study spatial structures on a microscopic level, the two-point correlation
function was exactly what one needed in order to compare experiment and the-
ory. Nowadays, since spatial information is ever more accessible through digitized
images, the need for similarly powerful techniques in real space is obvious.
In the recent decades spatial statistics has developed practically indepen-
dently of physics as a new branch in statistics. It is based on stochastic geometry
and the traditional field of statistics for stochastic processes. Statistical physics
and spatial statistics have many methods and models in common which should
facilitate an exchange of ideas and results. One may expect a close cooperation
between the two branches of science as each could learn from the other. For in-
stance, correlation functions are used frequently in physics with vague knowledge
only of how to estimate them statistically and how to carry out edge corrections.
On the other hand, spatial statistics uses Monte Carlo simulations and random
fields as models in geology and biology, but without referring to the helpful and
deep results already obtained during the long history of these models in statis-
tical physics. Since their research problems are close and often even overlap, a
fruitful collaboration between physicists and statisticians should not only be pos-
sible but also very valuable. Physicists typically define models, calculate their
physical properties and characterize the corresponding spatial structures. But
they also have to face the ‘inverse problem’ of finding an appropriate model for
a given spatial structure measured by an experiment. For example, if in a given
situation an Ising model is appropriate, then the interaction parameters need to
be determined (or, in terms of statistics, ‘estimated’) from a given spatial con-
figuration. Furthermore, the goodness-of-fit of the Ising model for the given data
should be tested. Fortunately, these are standard problems of spatial statistics,
for which adequate methods are available.
The gain from an exchange between physics and spatial statistics is two-sided;
spatial statistics is not only useful to physicists, it can also learn from physics.
The Gibbs models used so extensively today in spatial statistics have their origin
in physics; thus a thorough study of the physical literature could lead to a deeper
understanding of these models and their further development. Similarly, Monte
Carlo simulation methods invented by physicists are now used to a large extent
in statistics. There is a lot of experience held by physicists which statisticians
should be aware of and exploit; otherwise they will find themselves step by step
rediscovering the ideas of physicists.
Unfortunately, contact between physicists and statisticians is not free of con-
flicts. Language and notation in both fields are rather different. For many statis-
ticians it is frustrating to read a book on physics, and the same is true for
statistical books read by physicists. Both sides speak about a strange language
and notation in the other discipline. Even more problems arise from different
traditions and different ways of thinking in these two scientific areas. A typical
example, which is discussed in this volume, is the use of the term ‘stationary’
and the meaning of ‘stationary’ models in spatial statistics. This can lead to seri-
ous misunderstandings. Furthermore, for statisticians it is often shocking to see
how carelessly statistical concepts are used, and physicists cannot understand
Preface VII
the ignorance of statisticians on physical facts and well-known results of physical
research.
The workshop ‘Statistical Physics and Spatial Statistics’ took place at the
University of Wuppertal between 22 and 24 February 1999 as a purely German
event. The aim was simply to take a first step to overcome the above mentioned
difficulties. Moreover, it tried to provide a forum for the exchange of fundamen-
tal ideas between physicists and spatial statisticians, both working in a wide
spectrum of science related to stochastic geometry. This volume comprises the
majority of the papers presented orally at the workshop as plenary lectures, plus
two further invited papers. Although the contributions presented in this volume
are very diverse and methodically different they have one feature in common: all
of them present and use geometric concepts in order to study spatial configura-
tions which are random.
To achieve the aim of the workshop, the invited talks not only present recent
research results, but also tried to emphasize fundamental aspects which may
be interesting for the researcher from the other side. Thus many talks focused
on methodological approaches and fundamental results by means of a tutorial
review. Basic definitions and notions were explained and discussed to clarify dif-
ferent notations and terms and thus overcome language barriers and understand
different ways of thinking.
Part 1 focuses on the statistical characterization of random spatial config-
urations. Here mostly point patterns serve as examples for spatial structures.
General principles of spatial statistics are explained in the first paper of this vol-
ume. Also the second paper ‘Stationary Models in Stochastic Geometry - Palm
Distributions as Distributions of Typical Elements. An Approach Without Lim-
its’ by Werner Nagel discusses key notions in the field of stochastic geometry
and spatial statistics: stationarity (homogeneity) and Palm distributions. While
a given spatial structure cannot be stationary, a stationary model is often ade-
quate for the description of real geometric structures. Stationary models are very
useful, not least because they allow the application of Campbell’s theorem (used
as Monte Carlo integration in many physical applications) and other valuable
tools. The Palm distribution is introduced in order to remove the ambiguous
notion of a ‘randomly chosen’ or ‘typical’ object from an infinite system.
In the two following contributions by Martin Kerscher and Karin Jacobs et
al. spatial statistics is used to analyze data occurring in two prominent phys-
ical systems: the distribution of galaxies in the universe and the distribution
of holes in thin liquid films. In both cases a thorough statistical analysis not
only reveals quantitative features of the spatial structure enabling comparisons
of experiments with theory, but also enables conclusions to be drawn about the
physical mechanisms and dynamical laws governing the spatial structure.
In Part 2 geometric measures are introduced and applied to various exam-
ples. These measures describe the morphology of random spatial configurations
and thus are important for the physical properties of materials like complex
fluids and porous media. Ideas from integral geometry such as mixed measures
or Minkowski functionals are related to curvature integrals, which characterize
VIII Preface
connectivity as well as content and shape of spatial patterns. Since many phys-
ical phenomena depend crucially on the geometry of spatial structures, integral
geometry may provide useful tools to study such systems, in particular, in com-
bination with the Boolean model. This model, which is well-known in stochastic
geometry and spatial statistics, generates random structures through overlapping
random ‘grains’ (spheres, sticks) each with an arbitrary random location and ori-
entation. Wolfgang Weil focuses in his contribution on recent developments for
inhomogeneous distributions of grains. Physical applications of Minkowski func-
tionals are discussed in the paper by Klaus Mecke. They range from curvature
energies of biological membranes to the phase behavior of fluids in porous media
and the spectral density of the Laplace operator. An important application is
the morphological characterization of spatial structures: Minkowski functionals
lead to order parameters, to dynamical variables or to statistical methods which
are valuable alternatives to second-order characteristics such as correlation func-
tions.
A main goal of stereology, a well-known method in statistical image anal-
ysis and spatial statistics, is the estimation of size distributions of particles in
patterns where only lower-dimensional intersections can be measured. Joachim
Ohser and Konrad Sandau discuss in their contribution to this volume the es-
timation of the diameter distribution of spherical objects which are observed
in a planar or thin section. R¨udiger Hilfer describes ideas of modeling porous
media and their statistical analysis. In addition to traditional characteristics of
spatial statistics, he also discusses characteristics related to percolation. The
models include random packings of spheres and structures obtained by simu-
lated annealing. The contribution of Helmut Hermann describes various models
for structures resulting from crystal growth; his main tool is the Boolean model.
Part 3 considers one of the most prominent physical phenomena of random
spatial configurations, namely phase transitions. Geometric spatial properties of
a system, for instance, the existence of infinite connected clusters, are intimately
related to physical phenomena and phase transitions as shown by Hans-Otto
Georgii in his contribution ‘Phase Transition and Percolation in Gibbsian Parti-
cle Models’. Gibbsian distributions of hard particles such as spheres or discs are
often used to model configurations in spatial statistics and statistical physics.
Suspensions of sterically-stabilized colloids represent excellent physical realiza-
tions of the hard sphere model exhibiting freezing as an entropically driven phase
transition. Hartmut L¨owen gives in his contribution ‘Fun with Hard Spheres’ an
overview on these problems, focusing on thermostatistical properties.
In many physical applications one is not interested in equilibrium configu-
rations of Gibbsian hard particles but in an ordered packing of finite size. The
question of whether the densest packing of identical coins on a table (or of balls in
space) is either a spherical cluster or a sausage-like string may have far-reaching
physical consequences. The general mathematical theory of finite packings pre-
sented by J¨org M. Wills in his contribution ‘Finite Packings and Parametric
Density’ to this volume may lead to answers by means of a ‘parametric density’
Preface IX
which allows, for instance, a description of crystal growth and possible crystal
shapes.
The last three contributions focus on recent developments of simulation tech-
niques at the interface of spatial statistics and statistical physics. The main rea-
son for performing simulations of spatial systems is to obtain insight into the
physical behaviour of systems which cannot be treated analytically. For exam-
ple, phase transitions in hard sphere systems were first discovered by Monte
Carlo simulations before a considerable amount of rigorous analytical work was
performed (see the papers by H. L¨owen and H O. Georgii). But also statisti-
cians extensively use simulation methods, in particular MCMC (Markov Chain
Monte Carlo), which has been one of the most lively fields of statistics in the
last decade of 20th century. The standard simulation algorithms in statistical
physics are molecular dynamics and Monte Carlo simulations, in particular the
Metropolis algorithm, where a Markov chain starts in some initial state and then
‘converges’ towards an equilibrium state which has to be investigated statisti-
cally. Unfortunately, whether or not such an equilibrium configuration is reached
after some simulation time cannot be decided rigorously in most of the simu-
lations. But Elke Th¨onnes presents in her contribution ‘A Primer on Perfect
Simulation’ a technique which ensures sampling from the equilibrium configu-
ration, for instance, of the Ising model or the continuum Widomn-Rowlinson
model.
Monte Carlo simulation with a fixed number of objects is an important tool
in the study of hard-sphere systems. However, in many cases grand canonical
simulations with fluctuating particle numbers are needed, but are generally con-
sidered impossible for hard-particle systems at high densities. A novel method
called ‘simulated tempering’ is presented by Gunter D¨oge as an efficient alter-
native to Metropolis algorithms for hard core systems. Its efficiency makes even
grand canonical simulations feasible. Further applications of the simulated tem-
pering technique may help to overcome the difficulties of simulating the phase
transition in hard-disk systems discussed in the contribution by H. L¨owen.
The Metropolis algorithm and molecular dynamics consider each element
(particle or grain) separately. If the number of elements is large, handling of
them and detecting neighbourhood relations becomes a problem which is ap-
proached by Jean-Albert Ferrez, Thomas M. Liebling, and Didier M¨uller. These
authors describe a dynamic Delaunay triangulation of the spatial configurations
based on the Laguerre complex (which is a generalization of the well-known
Voronoi tessellation). Their method reduces the computational cost associated
with the implementation of the physical laws governing the interactions between
the particles. An important application of this geometric technique is the simu-
lation of granular media such as the flow of grains in an hourglass or the impact
of a rock on an embankment. Such geometry-based methods offer the potential
of performing larger and longer simulations. However, due to the increased com-
plexity of the applied concepts and resulting algorithms, they require a tight
collaboration between statistical physicists and mathematicians.
X Preface
It is a pleasure to thank all participants of the workshop for their valuable
contributions, their openness to share their experience and knowledge, and for
the numerous discussions which made the workshop so lively and fruitful. The
editors are also grateful to all authors of this volume for their additional work;
the authors from the physical world were so kind to give their references in the
extended system used in the mathematical literature. The organizers also thank
the ‘Ministerium f¨ur Schule und Weiterbildung, Wissenschaft und Forschung des
Landes Nordrhein-Westfalen’ for the financial support which made it possible to
invite undergraduate and PhD students to participate.
Wuppertal Klaus Mecke
Freiberg Dietrich Stoyan
June 2000
[...]... Shape (Springer-Verlag, New York, Berlin, Heidelberg) 35 Soille, P (1999): Morphological Image Analysis Principles and Applications (Springer-Verlag, Berlin, Heidelberg, New York) 36 Stoyan, D (1998): ‘Random sets: models and statistics Int Stat Rev 6 6, pp 1–27 37 Stoyan, D ., W.S Kendall, J Mecke (1995): Stochastic Geometry and its Applications (J Wiley & Sons, Chichester) 38 Stoyan, D ., M Schlather... ‘On the random sequential adsorption model with disks of different sizes , submitted 39 Stoyan, D ., H Stoyan (1986): ‘Simple stochastic models for the analysis of dislocation distributions’ Physica Stat Sol (a) 9 7, pp 163–172 40 Stoyan, D ., H Stoyan (1994): Fractals, Random Shapes and Point Fields (J Wiley & Sons, Chichester) 41 Stoyan, D ., H Stoyan (1998): ‘Non-homogeneous Gibbs process models for... censoring’ In: [2 ], pp 37–78 2 Barndorff-Nielsen, O.E ., W.S Kendall, M.N.M van Lieshout (1999): Stochastic Geometry Likelihood and Computation (Chapman & Hall / CRC, Boca Raton, London, New York, Washington) 3 Chil`s, J.-P ., P Delfiner (1999): Geostatistics Modeling Spatial Uncertainity (J e Wiley & Sons, New York) 4 Cressie, N (1993): Statistics of Spatial Data (J Wiley & Sons, New York) 5 Davies, S ., P Hall... least time-consuming Acknowledgment The author thanks H.-O Georgii and K Mecke for helpful discussions on Sect 5 He is also grateful to D J Daley for a discussion of the distribution of the one-dimensional hard core Gibbs process and to H L¨wen, K Mecke and M o Schmidt for comments on an earlier version of this paper 20 Dietrich Stoyan References 1 Baddeley, A (1999): Spatial sampling and censoring’... using spatial data , J Roy Statist Soc B 6 1, pp 3–37 6 Diggle, P.J ., T Fiksel, P Grabarnik, Y Ogata, D Stoyan, D ., M Tanemura (1994): ‘On parameter estimation for pairwise interaction point processes’ Int Statist Rev 6 2, pp 9 9-1 17 7 Dryden, I.L ., K. V Mardia (1998): Statistical Shape Analysis (J Wiley & Sons, Chichester) 8 Evans, J.W (1993): ‘Random and cooperative adsorption’ Rev Modern Phys 6 5, pp... Stereology (World Scientific, Singapore) 20 Kendall, W.S ., M.N.M van Lieshout, A.J Baddeley (1999): ‘Quermass-interaction processes: Conditions for stability’ Adv Appl Prob 3 1, pp 315–342 21 Matheron, G (1975): Random Sets and Integral Geometry (J Wiley & Sons, New York) 22 Matheron, G (1989): Estimating and Choosing (Springer-Verlag, Berlin, Heidelberg, New York) 23 McGibbon, A.J ., S.J Pennycook, D. E Jesson... papers by G D ge, J.-A Ferrez, Th M Liebling and D M¨ller, H.-O Georgii and E o u Th¨nnes in this volume describe some of these ideas o Mathematically, two general ideas play a key role in spatial statistics: random sets and random measures With the exception of random fields all the geometrical structures of spatial statistics can be interpreted as random sets Fundamental problems can be solved by means... Press, Baltimore and London) 13 Hahn, U ., A Micheletti, R Pohlink, D Stoyan, H Wendrock (1999): ‘Stereological analysis and modelling of gradient structures‘’ J Microsc 19 5, pp 11 3-1 24 14 Hahn, U ., D Stoyan (1999): ‘Unbiased stereological estimation of the surface area of gradient surface processes’ Adv Appl Prob 30 pp 904–920 15 Hansen, J.-P ., I.R McDonald (1986): Theory of Simple Liquids (Academic... distribution of the Boolean model Ξ is, as for any random set, determined by its capacity functional, P (Ξ ∩ K = ∅ ), the probability that the test set K does not intersect Ξ It is given by the simple formula ˇ P (Ξ ∩ K = ∅) = 1 − exp(−λ ν (K0 ⊕ K) ) for K ∈ K ˇ Here ⊕ denotes Minkowski addition, A ⊕ B = {a + b : a ∈ A, b ∈ B }, K is the set { k : k ∈ K} , and is the mean value operator The derivation of this formula... stochastic models, both in statistical physics and spatial statistics In the world of mathematics such models are developed and investigated in stochastic geometry As expressed already in the foreword, both sides, physicists and statisticians could learn a lot from the other side, since the methods and results are rather different Two statistical problems arise in the context of models: estimation of model parameters . in Physics
Editorial Board
R. Beig, Wien, Austria
J. Ehlers, Potsdam, Germany
U. Frisch, Nice, France
K. Hepp, Z
¨
urich, Switzerland
W. Hillebrandt, Garching,. 1 7,
D- 69121 Heidelberg, Germany
Series homepage – http://www.springer.de/phys/books/lnpp
Klaus R. Mecke Dietrich Stoyan (Eds.)
Statistical Physics
and Spatial
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