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Designing and synthesis of shape memory polymers for biomedical application

Designing and synthesis of shape memory polymers for biomedical application

Designing and synthesis of shape memory polymers for biomedical application

... DESIGNING AND SYNTHESIS OF SHAPE- MEMORY POLYMERS FOR BIOMEDICAL APPLICATION XUE LIANG (Msc in Chemistry, Zhejiang University, China ) A THESIS SUBMITTED FOR THE DEGREE OF DOCTOR OF PHYLOSOPHY ... mechanical and shape- memory properties of SMPs is examined The characterization of polymers structure, thermal, and mechanical properties, and the investigation of shapememory behavior of star polymers ... tensile strength (σm) of 14-20 MPa and Young’s modulus (E) of 70-91 MPa) and exhibited excellent shape- memory property at 40 oC, with Rf of over 95%, Rr of over 97%, and shape recovery within...
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Preparation and characterization of bimodal magnetofluorescent nanoprobes for biomedical application

Preparation and characterization of bimodal magnetofluorescent nanoprobes for biomedical application

... 3.6 g of iron-oleate, 1.91 mL of oleylamine and 0.64 mL of oleic acid were mixed together and were heated at 120∘C for one hour After that, the dark solution was quickly heated up to 200∘C and ... CTAB;[16] and 0.5 mL of the resulting Fe3 O4 /CTAB aqueous solution were diluted with 10 mL of water Then 0.3 mL of NH4 OH aqueous solution, 0.03 mL of tetraethylorthosilicate (TEOS), and 0.5 mL of ... stirring for 30 s, and then aged for three hours The Fe3 O4 /SiO2 nanoparticles were collected by centrifugation and washed with water and ethanol several times, and then redispersed in 10 mL of ethanol...
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identification, design and synthesis of oxygenated hydrocarbon-based carbon dioxide-soluble polymers for chemical and petroleum engineering applications

identification, design and synthesis of oxygenated hydrocarbon-based carbon dioxide-soluble polymers for chemical and petroleum engineering applications

... ABSTRACT IDENTIFICATION, DESIGN AND SYNTHESIS OF OXYGENATED HYDROCARBON-BASED CO2-SOLUBLE POLYMERS FOR CHEMICAL AND PETROLEUM ENGINEERING APPLICATIONS Lei Hong, Ph.D University of Pittsburgh, 2006 ... defended on March 29, 2006 and approved by Dr Eric J Beckman, Professor, Chemical and Petroleum Engineering Department Dr J Karl Johnson, Professor, Chemical and Petroleum Engineering Department ... Professor, Department of Chemistry Dissertation Director: Dr Robert M Enick, Chairman and Professor, Chemical and Petroleum Engineering Department ii Copyright © by Lei Hong 2006 iii ABSTRACT IDENTIFICATION,...
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Báo cáo hóa học:

Báo cáo hóa học: " Synthesis and characterization of integrated layered nanocomposites for lithium ion batteries" ppt

... doi:10.1186/1556-276X-7-60 Cite this article as: Gim et al.: Synthesis and characterization of integrated layered nanocomposites for lithium ion batteries Nanoscale Research Letters 2012 7:60 ... range of stoichiometric compositions Therefore, the present work reports on the synthesis and systematic investigations on the structure, morphology, and electrochemical performances of an integrated ... results and wrote the paper JS, HP, JWK, and KK participated in the characterization of samples and carried out experiments VM contributed to the technical discussions All the authors have read and...
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Báo cáo hóa học:

Báo cáo hóa học: " Synthesis of Bio-Compatible SPION–based Aqueous Ferrofluids and Evaluation of RadioFrequency Power Loss for Magnetic Hyperthermia" docx

... photon energy of diode laser (670 nm) The simulation of the power loss spectrum of the sample was performed for applied field strength of 500Oe in the range 100–900 kHz Results and Discussion ... introduced for hyperthermia application So, the power loss and hence the heat generated becomes a function of domain magnetization, anisotropy and volume of the particle for an AC field of fixed strength ... that the power dissipation at an applied frequency of 800 kHz is 80 W/g and for 200 kHz, 10 W/g for an applied field strength of 200 Oe In this study, the corresponding values of power loss are...
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báo cáo hóa học:

báo cáo hóa học:" Synthesis and characterization of integrated layered nanocomposites for lithium ion batteries" pdf

... doi:10.1186/1556-276X-7-60 Cite this article as: Gim et al.: Synthesis and characterization of integrated layered nanocomposites for lithium ion batteries Nanoscale Research Letters 2012 7:60 ... range of stoichiometric compositions Therefore, the present work reports on the synthesis and systematic investigations on the structure, morphology, and electrochemical performances of an integrated ... results and wrote the paper JS, HP, JWK, and KK participated in the characterization of samples and carried out experiments VM contributed to the technical discussions All the authors have read and...
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Design and synthesis of donor acceptor hybridized small molecules and graphene derivatives for photovoltaic and optical studies

Design and synthesis of donor acceptor hybridized small molecules and graphene derivatives for photovoltaic and optical studies

... DESIGN AND SYNTHESIS OF DONOR ACCEPTOR HYBRIDIZED SMALL MOLECULES AND GRAPHENE DERIVATIVES FOR PHOTOVOLTAIC AND OPTICAL STUDIES ANUPAM MIDYA M.Sc (Chemistry), ... the interface of the donor and acceptor material and split into hole and electron For efficient charge separation, the HOMO and LUMO energy levels of p-type (Donor) and n-type (Acceptor) materials ... and formation of bonds (a) for two sp2 -hybridized carbon atoms Figure 1.2 A schematic diagram of energy levels, hybridization of atomic orbitals creates two continuous band states of filled and...
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Synthesis and characterization of collagen terpolymer fibers for applications in tissue engineering

Synthesis and characterization of collagen terpolymer fibers for applications in tissue engineering

... desired site and to direct new tissue formation into the scaffolds [14] Some of the successes of Tissue Engineering include: engineering of artificial skin [15] to help burn victims and diabetic ... expression of extracellular matrix proteins and new tissue formation Therefore, the properties of such biomaterials are crucial in determining the success of many tissue engineering applications Tissue ... expression of extracellular matrix proteins and new tissue formation Hence, the properties of the scaffolding materials are crucial in determining the success of many tissue engineering applications...
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Synthesis and functionalization of micro nano particles for malicious cells detection and elimination

Synthesis and functionalization of micro nano particles for malicious cells detection and elimination

... SYNTHESIS AND FUNCTIONALIZATION OF MICRO/ NANO- PARTICLES FOR MALIGNANT CELLS DETECTION AND ELIMINATION HU FEIXIONG (B E., M S., Tianjin University) A THESIS SUBMITTED FOR THE DEGREE OF DOCTOR ... technique for preparing antibacterial microparticles has the advantages of ease of mass production and scale up, and the microparticles possess stability for repeated usage In the second part of the ... magnetic nanoparticles (0.2 mg/ml) for day and (c) for days, (d) cells after culturing in medium containing PPEGMA-immobilized nanoparticles (0.2 mg/ml) for day The PPEGMA-immobilized nanoparticles...
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Synthesis and characterization of  non shrinking  nanocomposites for dental applications 2

Synthesis and characterization of non shrinking nanocomposites for dental applications 2

... residual chloroform-d (CDCl3) as an internal standard for 1H and 13C and TMS (Tetramethylsilane) as external standard for 29 Si NMR 4 .2. 3 .2 Fourier Transform Infrared Spectroscopy Fourier Transform Infrared ... NMe4OH / MeOH / H2O RT, >48h "Octaanion" Figure 4.4 Synthesis of “Octaanion” 4 .2. 2 Step 2: Synthesis of Octa(hydridodimethylsiloxy)silsesquioxane, (HMe2SiOSiO1.5)8 Reaction of (HSiMe2OSiO1.5)8 was ... (HMe2SiOSiO1.5)8 NMR of Octa(hydridodimethylsiloxy)silsesquioxane, 49 100 90 80 70 %T 60 50 40 30 Si-H 21 42 Si(CH3 )2 125 7 20 10 400 Si-O-Si, 1089 800 120 0 1600 20 00 24 00 28 00 320 0 3600 4000 Wavenumbers...
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Synthesis and characterization of  non shrinking  nanocomposites for dental applications 1

Synthesis and characterization of non shrinking nanocomposites for dental applications 1

... compound F 11 6 13 C NMR of compound F 11 7 29 Si NMR of compound F 11 8 H NMR of compound G 11 9 13 C NMR of compound G 12 0 29 Si NMR of compound G 12 1 H NMR of compound H 12 2 13 C NMR of compound H 12 3 ... Figure 6 .10 Figure 6 .11 Figure 6 .12 Figure 6 .13 Figure 6 .14 Figure 6 .15 Figure 6 .16 Figure 6 .17 Figure 6 .18 H NMR of compound E 13 C NMR of compound E 11 4 29 Si NMR of compound E 11 5 H NMR of compound ... 6 .1 Introduction 6.2 Materials and Methods 10 2 6.3 Results and Discussions 11 0 6.4 Conclusions Chapter 10 1 14 2 SSQ-BASED MONOMERS AS COPOLYMERS 7 .1 Introduction 14 3 7.2 Materials and Methods 14 4...
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Synthesis and characterization of novel jacketed polymers and investigation of their self assembly and application 6

Synthesis and characterization of novel jacketed polymers and investigation of their self assembly and application 6

... rigid core exert hindrance to self- assembly whereas the pyrimidine groups stabilized the self- assembly of jacketed polymers A series of novel jacketed liquid crystalline polymers, in which the terphenyl ... expected to help the self- assembly of the polymers The length of the alkyl chain and position of the alkyl chain on the mesogenic units appears to have significant effect on the self- assembly Besides ... between rigid segments and flexible segments, polar or nonpolar effect is investigated through the incorporation of the polar functional groups A series of novel jacketed polymers were synthesized...
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Synthesis and characterization of novel jacketed polymers and investigation of their self assembly and application 5

Synthesis and characterization of novel jacketed polymers and investigation of their self assembly and application 5

... of polymers 3a, 3b and 3c were measured in chloroform solution The absorption and emission spectra of the polymers are shown in Fig .5. 3 and the values as given in Table 5. 2 The UV spectrum of ... = 5. 2Hz, CCH(O)-, H), 4 .5 (d, J = 5. 5 Hz, O-CH2-, H), 2.7 (s, -OH, H) 13 CNMR ( 75. 4 MHz, CDCl3, δ ppm) 154 .2, 137.2, 134.7, 127.7, 126.7, 126.0, 1 25. 7, 1 25. 5, 121.0, 1 05. 3 (ArC), 69.4 (O-CH-), ... 300 400 50 0 wavelength (nm) Figure 5. 3 UV-vis absorption and Fluorescence spectra of polymers measured in chloroform at room temperature Table 5. 2 The detailed data of UV-vis absorption and Fluorescence...
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Synthesis and characterization of novel jacketed polymers and investigation of their self assembly and application 4

Synthesis and characterization of novel jacketed polymers and investigation of their self assembly and application 4

... CDCl3, δ ppm): 171, 149 .80, 149 .45 , 141 .17, 137.08, 136.62, 135.76, 1 34. 62, 1 34. 49, 133.79, 130.59, 129.33, 128.88, 126.63, 1 24. 90, 1 24. 07, 123 .45 , 113.72, 77.33, 76.91, 76 .48 , 69.11, 31.79, 30.79, ... 2θ1/° 2θ2/° 2θ3/° 2 4/ ° 2θ5/° d1(Å) d2(Å) d3(Å) d4(Å) d5(Å) 2 .46 2.86 P1(DBSA)0.5 3.02 20.1 P1 4. 91 7 .42 19.8 35.9 30.6 29 .4 17.9 11.9 4. 5 4. 4 The XRD diffraction pattern of P1 shows sharp reflection ... formed via host polymers with pyrimidine groups and alkyl sulfonic acid and investigate their self- assembling properties in the solid state 1 14 4.2 Experimental section 4. 2.1 Materials and reagents...
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Synthesis and characterization of novel jacketed polymers and investigation of their self assembly and application 3

Synthesis and characterization of novel jacketed polymers and investigation of their self assembly and application 3

... 4H), 3. 86 (s, Ar-O-CH3, 3H), 3. 78 (s, Ar-O-CH3, 3H), 3. 77 (s, Ar-O-CH3, 3H), 2.20 (b, -C-OH, 1H) 13 C NMR (75.4 MHz, CDCl3, δ ppm) 158.7, 151.2, 149.4, 131 .4, 130 .4, 129.7, 129 .3, 114.6, 1 13. 5, ... 150.4, 130 .4, 129.7, 129 .3, 128.9, 127.8, 118.0, 115 .3, 114 .3 (ArC), 69.6 (O-CH2-), 56 .3 (O-CH3), 31 .8, 29.5 (-CH2-), 13. 4 (-CH3) MS (EI): m/z: 474.4, 420 .3, 36 4 .3, 30 7.2, 247.1, 199 Mp: 1 23 °C ... Hz, -CH3, H) 13C NMR (75.4 MHz, CDCl3, δ ppm) 158 .3, 151.1, 149.68, 137 .4, 130 .6, 130 .5, 129.6, 129.5, 129.4, 129 .3, 128 .3, 127.5, 127.1, 118.5, 117.4, 115 .3, 115.1, 114 .3, 114.0, 1 13. 3, 1 13. 0 (ArC),...
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