TOXICOLOGICAL CHEMISTRY AND BIOCHEMISTRY - CHAPTER 16 pdf
TOXICOLOGICAL CHEMISTRY AND BIOCHEMISTRY - CHAPTER 16 pdf
... quantities as substi-tutes for ozone-depleting chlorofluorocarbons (CFCs). The two most common HCFCs are 1, 1- dichloro-2,2,2-trifluoroethane (HCFC-123) and 1,1-dichloro- 1- uoroethane (HCFC-141b):+O2OOCCH..CCHLipidradical, ... trifluoroacetylchloride: (16. 2.6)1,1-Dichloro-2,2, 2- trifluoroethane (HCFC-123)HCClClCFFFFCClClCHHH1,1-Dichloro- 1- fluoroethane (HCFC-141b)OCOOHOHHOOHOCCFHClHClHO C C FHClHCl2,2-Dichloro-2-fluoroethylglucuronide2,2-Dichloro-2-fluoroethanolFCFFCClClBrFCFFCClClBr ... CCH3HCOOOClClClCl2,4-Dichlorophenoxy-acetic acid (and esters)2,4,5-Trichlorophenoxy-acetic acid (and esters)Silvex2,3,7,8-Tetrachloro-p-dioxinCl2ClClClClClCl8-Octachlorobornane L1618Ch16Frame Page 341...
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TOXICOLOGICAL CHEMISTRY AND BIOCHEMISTRY - CHAPTER 4 pdf
... COO - CHHCOO - CHHCO - OCCOO - CHHCOO - CHCO - OHHOCCCO - OHHOO - OCHHCCitrate Isocitrate α-KetoglutarateCCSHHOO - OCHHCCoACHHO - OCHHCCOO - CO - OCCCOO - HHCO - OCCCOO - HHHOHCO - OCCCOO - OHHOxaloacetate Malate Fumarate ... with acetyl-CoA from glycolysis to start the cycleover again.Acetyl = CoAHCHHCOCoA HO C COO - CHHCOO - CHHCO - OCCOO - CHHCOO - CHCO - OHHOCCCO - OHHOO - OCHHCCitrate ... (ADP):ATPNNCNNNH2HCCCCHOOHHCHHHOHOPOPOP - OO - O - O - OOOHCCCCHOOHHCHHHOHOPOP - OO - O - OONNCNNNH2HHADP L1618Ch04Frame Page 87 Tuesday, August 13, 2002 5:53...
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TOXICOLOGICAL CHEMISTRY AND BIOCHEMISTRY - CHAPTER 1 pot
... ofenvironmental chemistry. Chapter 3, Biochemistry, ” gives the fundamentals of the chemistry oflife processes essential to understanding toxicological chemistry and biochemistry. Chapter 4,“Metabolic ... 100 known elements which may be found in any Figure 1.2 Atoms of carbon and nitrogen. - - - - - - - - - - An atom of carbon, symbol C.Each C atom has 6 protons (+)in its nucleus, so ... Cataloging-in-Publication Data Manahan, Stanley E. Toxicological chemistry and biochemistry / by Stanley E. Manahan 3rd ed.p. cm.Includes bibliographical references and index.ISBN 1-5 667 0-6 1 8-1 1....
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TOXICOLOGICAL CHEMISTRY AND BIOCHEMISTRY - CHAPTER 3 pps
... |||||).CNCCCNOOHHHHCH3CNCCCNOOHHHNCCCNCNCNHHHNH2NCCCNCNCNHHOH2NHCCCCCH2HOHHHOHOHOHHOCCCCCH2HOHHHOHHOHHOPO - O - - OOOccur in both DNA and RNAUracil (U)Thymine (T)Adenine (A)Guanine(G)Phosphate2-Deoxy-β-D-ribofuranoseCNCCCNNH2OHHHHCytosine (C)β-D-RibofuranoseOccur ... Medical Biochemistry, Mosby, St. Louis, 1998.Switzer, R.L. and Garrity, L.F., Experimental Biochemistry, W.H. Freeman and Co., New York, 1999.Voet, D., Voet, J.G., and Pratt, C., Fundamentals of Biochemistry, ... in Biochemistry, McGraw-Hill, Health Professions Division, New York,2000.Kuchel, P.W., Ed., Schaum’s Outline of Theory and Problems of Biochemistry, McGraw-Hill, New York, 1998.Lea, P.J. and...
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TOXICOLOGICAL CHEMISTRY AND BIOCHEMISTRY - CHAPTER 6 pps
... substances and theirmetabolites react biochemically in an organism to exert a toxic effect. Chapter 7 is devoted todefining and explaining toxicological chemistry, and Chapters 10–19 cover the toxicological ... . 6.1.5 Toxicological Chemistry Toxicological chemistry relates chemistry to toxicology. It deals with the chemical nature oftoxic substances, how they are changed biochemically, and how xenobiotic ... xenobiotics, such as organophosphate com-pounds (see Chapter 18) and carbamates (see Chapter 15) inhibit acetylcholinesterase, with theresult that acetylcholine accumulates and nerves are overstimulated....
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TOXICOLOGICAL CHEMISTRY AND BIOCHEMISTRY - CHAPTER 7 pptx
... benzo(a)pyrene 7, 8- diol-9,10-epoxide.Benzo(a)pyrene{O}, epoxidationOBenzo(a)pyrene7,8-epoxide+ H2O, epoxidehydrolaseHOHOBenzo(a)pyrene7,8-diolbenzo(a)pyrene7,8-diol-9,10-epoxideHOHOO{O}, ... DNANCNCCCNNCHHOH2NNCNCCCNNCHHOH2NCH3CH3Dimethylnitros- 3,3-Dimethyl- 1- 1,2-Dimethylhydra- Methylmethane-ONNCH3CH3NNHHH3CCH3CH3SOOH3CONNNCH3CH3amine phenyltriazine ... sulfonateCHHOHNCH3NOONNCHHCH3OHCHHOONNHCH3HO -+ NNHCH3Other products +CH3L1618Ch07Frame Page 160 Tuesday, August 13, 2002 5:50 PMCopyright © 2003 by CRC Press LLC and benzo(a)pyrene 7,8-diol-9,10-epoxide is the ultimate...
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TOXICOLOGICAL CHEMISTRY AND BIOCHEMISTRY - CHAPTER 8 doc
... facile detection of β-galactosidase activity. Thisis accomplished with the chromogenic substrate 5-bromo-4-chloro-3-indoyl-β-D-galactopyrano-side, which is metabolized by β-galactosidase to ... Zetterqulist, H., and Olerup, O., HLA-DR, -DQ, and -DP alleles in nickel, chromium and/ or cobalt-sensitive individuals: genomic analysis based on restriction fragment length polymor-phisms, J. Invest. ... (C), and adenine (A) is opposite thymine (T) in the opposing strand. Thestructures of these nitrogenous bases are such that hydrogen bonds form between them on the twostrands, bonding the strands...
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TOXICOLOGICAL CHEMISTRY AND BIOCHEMISTRY - CHAPTER 10 ppsx
... phosphorylation.CCPO3COHHHOHHOCCPO3COPO3HHOHHOOCCPO3COAsO3HHOHHOO 2- 2- 2- 2- 3- PhosphateGlyceraldehyde3-phosphateAdditional processesleading to ATPformation 3- Arsenite (AsO3 )1-arseno- 3- phosophoglycerateSpontaneous ... element?SSCdH+SH+SHCd2++CCPO3COHHHOHHOCCPO3COPO3HHOHHOOCCPO3COAsO3HHOHHOO2 - 2 - 2 - 2 - 3 - PhosphateGlyceraldehyde3-phosphate3 - Arsenite (AsO3)Spontaneous hydrolysis+CCOHHNH3CHHOOCCHHALA ... Explain what is shown by the illustration below:CCO - *OHH*NHHCC* - OOHHN*HH+ Cu2+CC* - OOHHN*HHCuHH*NHHOO - *CCL1618Ch10Frame Page 232 Tuesday, August 13, 2002...
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TOXICOLOGICAL CHEMISTRY AND BIOCHEMISTRY - CHAPTER 11 pot
... human blood and on rodents suggest that ClO2 and its metabolic productClO2–cause formation of methemoglobin, decrease the activities of glucose-6-phosphate dehydro-genase and glutathione ... gases, 3.5 g/l forHBr and 5.7 g/l for HI at 0°C and atmospheric pressure. These compounds are used much lessthan HCl. Both are irritants to the skin and eyes and to the oral and respiratory mucous ... Newhook, R., Meek, M.E., and Walker, M., Carbon disulfide: hazard characterization and exposure-response analysis, Environ. Carcinog. Ecotoxicol. Rev., C19, 125 160 , 2001.QUESTIONS AND PROBLEMS1. What...
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TOXICOLOGICAL CHEMISTRY AND BIOCHEMISTRY - CHAPTER 12 pps
... AsOHOOHNO23-Nitro-4-hydroxyphenyl-arsinic acid (Roxarsone)HO AsOHOHHCNH2ON-carbamoylarsinic acid(Carbarsone)NNNSCHHHAs OHHOOH2-Methylthio- 4-( 2'-phenylarsenic acid )- aminopyrimidineL1618Ch12Frame ... compounds found in seaweed and in sheep feeding on the seaweed.β-D-Ribofuranoside,2,3-dihydroxypropyl5-deoxy- 5-( dimethylarsinyl)(an arsenosugar)Arsenobetaine Arsenocholine 2-( Dimethylarsinyl)ethanolAsH3CCH3OHHCOHO ... cancer and leukemic cells, is 2- methylthio- 4-( 2'-phenylarsenic acid)-aminopyrimidine:Organoarsenic compounds are used as animal feed additives. The major organoarsenic feedadditives and...
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