INTERFACIAL APPLICATIONS IN ENVIRONMENTAL ENGINEERING - CHAPTER 6 docx
INTERFACIAL APPLICATIONS IN ENVIRONMENTAL ENGINEERING - CHAPTER 6 docx
... 24 16 11 26 28 388.0 14 11 9 16 16 24sequence of increasing exchange efficiency can be considered to reflect an in- creasing effectiveness in neutralizing the negative charge on the aluminosilicateframework. ... exchangewith cations in external solution. An increase in exchange temperature enhancedHM removal by reducing the solvation coating and kinetic diameter of the in- going HM cation, facilitating exchange ... solution using Na-Y was investi-gated using a fixed-zeolite-bed configuration. The breakthrough curves for fourselected HM are shown in Figure 5 under identical operating conditions. Break-through...
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INTERFACIAL APPLICATIONS IN ENVIRONMENTAL ENGINEERING - CHAPTER 17 (END) docx
... and brominated flame-retardant-containing high-impact polystyrene(HIPS) mixed plastics over iron-base catalysts.A. Catalytic Dechlorination of Chloro-OrganicCompounds from PVC-Containing Mixed ... since the amount of chlorine-containing compounds in the original mixed plastics–derived oil was not high enough to produce anysignificant change in the C-NP gram.Figure 8 shows the time-on-stream ... chloro-organic compounds (Cl-NP gram) areshown in Figure 1a and 1b, respectively. The C-NP gram was obtained by plottingthe weight percent of carbon-containing compounds in the MX/PVC oil againstthe...
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INTERFACIAL APPLICATIONS IN ENVIRONMENTAL ENGINEERING - CHAPTER 1 pot
... Guidelines for Drinking-Water Quality: Health Criteria & Other Supporting Infor-mation. World Health Organization, 19 96. 31. CJM Kramer, JC Duinker, eds. Complexation of Trace Metals in Natural ... (4) wasteminimization/recycle. Each contribution has either a theoretical significance orpractical utility or both. Interfacial Applications in Environmental Engineer-ing is an invaluable resource ... proton is more acidic in H3Cu-FAU than in Na2HCu-FAU. Indeed, their calculated proton affinities are smallerby about 10 kcal moleϪ1 in the fully protonated model [66 ]. Combining calculatedand...
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INTERFACIAL APPLICATIONS IN ENVIRONMENTAL ENGINEERING - CHAPTER 2 potx
... mixed in the vicinity of the catalyst sample in theinfrared reactor cell, as shown in the inset of Figure 1. One-hundred-mg catalystswere pressed into three to four thin disks, each weighing ... Cu-ZSM-5 produced bridged Cu2ϩ(NO3Ϫ). This species has also been observed during theNO decomposition reaction over Cu-ZSM-5 [ 26 28]. Pulsing C3H 6 into the NO/O2/He flow resulted in ... species during the step-and-pulse switch of the NO, O2,C3H 6 reactant flows during the SCR reaction over Cu-ZSM-5.II. EXPERIMENTALA. Catalyst PreparationThe overexchanged Cu-ZSM- 5-5 23 was...
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INTERFACIAL APPLICATIONS IN ENVIRONMENTAL ENGINEERING - CHAPTER 3 doc
... 0. 260 (65 3 K) 0.437CuZ-4.4 0.251 (450 K) 0.134 ( 461 K) 0.2 16 (66 3 K) 0 .60 1Ti-PILC — — — —CuTi-4 .6 0.405 (473 K) 0.172 (543 K) 0.0 46 (66 3 K) 0 .62 3CuTi-7.4 0.321 (431 K) 0.170 (507 K) 0.051 (68 5 ... Zeolite- andPILC-Based Catalysts Ion Exchanged by CuTemperature forMaximum maximum NOxCatalyst NOx conversion conversion (K)CuZ-2.4 56. 9 62 3CuZ-2 .6 62.4 62 3CuZ-2.9 65 .7 62 3CuZ-3.7 65 .6 623CuZ-4.4 ... role in electron transfer from theelectron-accepting to the electron-donating sites at the catalytic surface. Ac-cording to Bahranowski et al. [48], single doping of Al-PILC with copper intro-duced...
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INTERFACIAL APPLICATIONS IN ENVIRONMENTAL ENGINEERING - CHAPTER 4 pdf
... showsthe majority/minority spin configurations. The HOMO is the Π bonding in the majorityspin and the LUMO is the Π antibonding in the minority spin. (b) SO2(singlet, C2v). (c)SO3(singlet, C3v).TMCopyright ... most stableconfigurations involved dicoordination binding through both η2-S,O and η2-O,Ostructures on the Pt(111) surface but no flat-lying configurations.Our first-principles DFT calculations ... showed an increasing bonding energy in the orderof η1-S Ͻ η2-S,O Ͻ η2-O,O Ͻ η3-S,O,O. To make comparison with experiments,Rodriguez et al. further proposed η2-O,O or η2-S,O to be...
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INTERFACIAL APPLICATIONS IN ENVIRONMENTAL ENGINEERING - CHAPTER 5 pdf
... (%) Gasoline C1ϩ C2C3ϩ C4Coke (%)0 64 .10 40.31 2.02 13.72 8.05 63 .1010 63 .83 40.72 1.78 12.88 8.45 63 .2220 64 .31 40.91 2.09 13.31 8.00 63 .61 30 63 .99 40 .67 1. 86 13. 26 8.20 63 .55Temperature: ... increaseswith the boiling point of distillate and concentrates in the high-boiling-point dis-tillates.Because the distillate of IBP -6 0 °C is too ‘‘light’’ and that of 160 -EP is too‘‘heavy,’’ ... the results obtained from on-line pulse-reactionchromatography. Ten grams of thiophene/n-heptane or the gasoline distillate waspumped into the reactor within 1 min. Sulfides in the liquid product...
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INTERFACIAL APPLICATIONS IN ENVIRONMENTAL ENGINEERING - CHAPTER 8 doc
... Stoichiometric 6 6.0 50.00 8.07 0.2Hg Stoichiometric 20 6. 0 50.00 6. 85 0.2Hg 10% dose increase 1 6. 0 50.00 6. 72 0.2Hg 10% dose increase 6 6.0 50.00 5.20 0.2Hg 10% dose increase 20 6. 0 50.00 3.97 ... [3]Thio-RedPb Stoichiometric 1 6. 0 50.00 38.24 5.0Pb Stoichiometric 6 6.0 50.00 44.83 5.0Pb Stoichiometric 20 6. 0 50.00 48.17 5.0Pb 10% dose increase 1 5.5 50.00 33 .67 5.0Pb 10% dose increase ... Stoichiometric 20 6. 0 50.00 32.98 2.0Fe(II) 10% dose increase 1 5.0 50.00 34.79 2.0Fe(II) 10% dose increase 6 5.0 50.00 34. 56 2.0Fe(II) 10% dose increase 20 5.0 50.00 33. 56 2.0Hg Stoichiometric 1 6. 0 50.00...
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INTERFACIAL APPLICATIONS IN ENVIRONMENTAL ENGINEERING - CHAPTER 9 ppsx
... Ͼ10 9 364 7 .6 25.8 332 Coastal area Barren soil 10 163 3 7.4 16. 6 223 Depression Barren soil 6 6 46 8.0 8.7 94 Creek Open shrub 3 61 8 7.4 8 .6 85 Arid plateau Shrub steppe 3 387 7 .6 9.3 12 6 Meadow ... strong inhibitory effect of water content can be interpreted as water-aidedinterruption of inter- and intramolecular contacts in the soil upon oil sorption.An increase in Kdwhen increasing the ... Logarithmic 1337 1017 0.9 96 2.32 1.22 3.813 Linear 1387 8 96 0.978 2.27 0.37 1.034 Linear 1348 13 46 0.942 2.14 0. 46 2.955 Linear 878 1035 0. 961 1.95 0.52 1.95 6 Linear 901 971 0. 960 1.73 0.57 1.28TMCopyright...
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INTERFACIAL APPLICATIONS IN ENVIRONMENTAL ENGINEERING - CHAPTER 10 pptx
... Carbon 37:1 265 –1274, 1999. 66 . AO Eremina, VV Golovina, ML Shchipko, EV Burmakina. Russ J Appl Chem 73: 266 – 268 , 2000. 67 . C Lepont, AD Gunatillaka, CF Poole. Analyst 1 26: 1318–1325, 2001. 68 . NK Shoniya, ... Fritz, W Merk, E Schluender. Chem Eng Sci 36: 731–741, 1981.12. F Caturla, JM Martin-Martinez, M Molina-Sobio, F Rodriguez-Reinoso, R Torre-grosa. J Colloid Interface Sci 124:528–534, 1988.13. W ... Svec. J Am Wat Wks 69 :66 9 67 4, 1977.42. JA Mendendez, J Phillips, B Xia, LR Radovic. Langmuir 12: 4404–4410, 19 96. 43. MV Lopez-Ramon, F Stoeckli, C Moreno-Castilla, F Carrasco-Marin. Carbon 37:1215–1221,...
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