BIOLOGICALLY ACTIVE NATURAL PRODUCTS: AGROCHEMICALS - CHAPTER 3 ppsx

... 98 86 3. 1 27 1.9 1 23 83 8SolanaceaeLycopersicon esculentum (R) 98 1 23 3 .3 38 1.4 131 45 10Lycopersicon esculentum (S) 96 136 5.9 23 1.9 135 37 10Solanum carolinense (S) 96 120 0.8 1 53 0.9 ... lanatus (L) 95 102 3. 7 26 1 .3 133 69 6Citrullus lanatus (R) 94 1 03 4.2 23 2.2 1 13 74 12.5Citrullus lanatus (stem) 96 116 3. 0 36 1.7 129 59 6Cucumis sativus (R) 98 224 4 .3 52 1 .3 159 71 10Cucumis ... 3- yr. crop 16.82 (40.1) 1, 2, 3, 5, 6, 7, 8, 9, 10, 11, 12, 13, 14Tomato 3- yr. crop 4.92 (64.9) 1, 5, 6, 9, 12, 13, 17Velvetbean 2-yr. crop 0.00 (0.0) No emergenceVelvetbean 1-yr. crop, 1-yr....

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BIOLOGICALLY ACTIVE NATURAL PRODUCTS: AGROCHEMICALS - CHAPTER 4 ppsx

... 4 - -xyloside, 3- methylquercetin 3 - -xyloside19Dienoic, trienoic, and tetraenoic acids20α-aminoadipic acid21β-sitosterol, gallic acid, 1-hexacosanol22Nupharin, nymphaeine, nymphalin 23 Tocopherylesters24N. ... skeleton incorporated into 3- furyl-substituted piperidines or quin-olizidines, as well as C30 alkaloids that contain a sulfur atom along with two 3- furyl sub-stituents.1 1-1 3 As none of these alkaloids ... Gulacar, F.O., Phytochemistry, 36 , 81 3- 8 14, 1994.25. Saeed, A., Omer, E., and Hashem, A., Bull. Fac. Pharm. (Cairo Univ.), 31 , 34 7 -3 51, 19 93, Chem.Abstr., 122, 1 831 83s, 1995.26. Haeed, A.A. and...

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BIOLOGICALLY ACTIVE NATURAL PRODUCTS: AGROCHEMICALS - CHAPTER 6 ppsx

... natural compounds:(24R )-1 4α-methyl-5α-ergostan -3 - one; 14α-methyl-5α-cholestan -3 - one; cycloart-5-ene- 3 ,25-diol; cycloart -3 ,25-diol; 4α-methylergostan-5-ene -3 -ol; stigmast-4,22-dien-6β-ol- 3- one ... stigmast-4,22-dien-6β-ol- 3- one and 24-phenylethyl-cholest -3 , 6-dione were identified; together with several knowncompounds: (24R)-stigmast-4-ene -3 - one; ergost-4-ene -3 - one; (24R)-stigmast-4-ene -3 , 6- dione; stigmast-4,22-diene -3 , 6-dione; ... stigmast-4,22-diene -3 , 6-dione; ergost-4-ene -3 , 6-dione; (24R )-5 α-stigmast -3 , 6-dione;stigmast-22-ene -3 , 6-dione; ergost -3 , 6-dione; cholesterol; ergosterol; campesterol; stigmas-terol; β-sitosterol;...

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BIOLOGICALLY ACTIVE NATURAL PRODUCTS: AGROCHEMICALS - CHAPTER 9 ppsx

... herbicides (pendimetha-lin [N-(1-ethylpropyl ) -3 ,4-dimethyl-2,6-dinitrobenzenamine]; thiobencarb [S-[(4-chlorophe-nyl)methyl]-diethylcarbamothioate]; quinclorac (3, 7-dichloro-8-quinolinecarboxylic ... acid);bensulfuron [methyl 2-[ [[[[(4,6-dimethoxy-2-pyrimidinyl)amino]carbonyl]amino]sulfo-nyl]methyl]benzoate]; or bentazon [ 3- ( 1-methylethyl )-( 1H )-2 ,1 , 3- benzothiadiazin-4(3H)-one© 1999 by CRC Press ... of L-(N5-phosphono)methionine-S-sulfoximinyl-L-ala-L-ala (PMSO-Ala-Ala)76 isolated from a Streptomyces species.77 PMSO and MSO can result from the actionof peptidase on PMSO-Ala-Ala or...

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BIOLOGICALLY ACTIVE NATURAL PRODUCTS: AGROCHEMICALS - CHAPTER 1 ppt

... 2-( 4-dichlorophenoxy) phe-noxy-methyl propanoate, Hoelon®, 1974; Butyl 2-[ 4-( 5-trifluoro-2-pyridyloxy)phenoxy]propionate, Fusilade®, 1980; Methyl 2-( 4-( ( 3- chloro-5-trifluoromethyl )-2 -pyridinyloxy )- phenoxy) ... aphrodisiac), ajmaline, serpentine, and serpertinine. 3- 5 Of these, reserpine,11,17α-dimethyoxy-18 -[ (3, 4,5-trimethoxybenzoyl) oxy ] -3 β, 20α-yohimban-1 6- -carboxy-lic acid methyl ester, was the constituent ... G., 1 93 2- Biologically active natural products: agrochemicals / Horace G. Cutler, Stephen J. Cutler.p. cm.Includes bibliographical references and index.ISBN 0-8 49 3- 1 88 5-8 (alk. paper)1. Natural...

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BIOLOGICALLY ACTIVE NATURAL PRODUCTS: AGROCHEMICALS - CHAPTER 2 docx

... kaurenoid carboxylic acids:(–)-kaur-16-en-19-oic acid (28), (–)-grandifloric acid, (–)-angeloylgrandifloric acid (29), andthe (– )-1 7-hydroxy-16β-kauran-19-oic acid (30 ) (Figure 2.7).In general, ... length except for 32 and 33 with H. vulgare. Compound 32 had an inhibitory effect on the shoot length (10–6M,–42%; 10–7M, –44%) and 32 (10–9M, +30 %), and 33 (10–7M, +36 %) stimulated germination.Most ... of concentra-tion such as compounds 32 , 33 , 35 , 44, and 45 and those with no significant activity likecompound 34 . The only difference in the stereochemistry of compounds 34 and 35 is thedouble...

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BIOLOGICALLY ACTIVE NATURAL PRODUCTS: AGROCHEMICALS - CHAPTER 5 ppt

... derivatized to yield the herbicides dicamba (3, 6-dichloro-2-methoxybenzoic acid) and chloramben ( 3- amino-2,5-dichlorobenzoic acid). The allelo-pathic terpenoid 1,8-cineole has served as a model for the ... M., Am. J. Bot., 83, 196, 1996. With permission.)© 1999 by CRC Press LLC 1960s, 3 0 -3 2 but it was not recognized to be the major phytotoxic component until the1990s. 3 3- 3 5 Ailanthone belongs ... retroflexus) <0 .3 <0 .3 Oats (Avena sativa cv. Ogle) <0 .3 0.6Common lambsquarters (Chenopodium album) <0 .3 <0 .3 Field bindweed (Convolvulus arvensis) <0 .3 <0 .3 Yellow nutsedge...

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BIOLOGICALLY ACTIVE NATURAL PRODUCTS: AGROCHEMICALS - CHAPTER 8 potx

... (Koto fresh K-20) 1/1000c15(±)-CA 10 6(+ )-( 1S,2S)-CA 5 6–7(– )-( 1R,2R)-CA 5 6(±)-AlloCA 10 8–10(±)-AlloCAb10 10–11(+ )-( 1R,2S)-AlloCA 10 12– 13 5 10–111.67 9(– )-( 1S,2R)-AlloCA 10 8–95 ... aromatic amino acids), not naturally occurring JA-Gly, JA-β-Ala, JA-ACC,JA-(+)-coronamic acid were also synthesized. Among them, JA-Leu, JA-Ile, JA-Val,JA-ACC, and JA-(+)-coronamic acid are structurally ... component. Feeding experiments ofthe [3, 4- 13 C2]-DL-glutamate into this bacterium gave a labeled cyclopentenone 8 whichexhibits 13 C- 13 C coupling between C-2 and C -3 with an enrichment at each carbon...

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BIOLOGICALLY ACTIVE NATURAL PRODUCTS: AGROCHEMICALS - CHAPTER 10 potx

... 1994. 30 . White, N.J., Trans. Royal Soc. Trop. Med. Hyg., 88, Suppl. 1, 3, 1994. 31 . Delabays, N., Benakis, A., and Collet, G., Acta Hortic., 33 0, 2 03, 19 93. 32 . Laughlin, J.C. Acta Hortic., 33 1, ... 19 93. 32 . Laughlin, J.C. Acta Hortic., 33 1, 53. 19 93) 33 . ElSohly, H.N., Croom Jr., E.M., El-Feraly, F.S., and El-Sherei, M.M., J. Nat. Prod., 53, 1560, 1990. 34 . Vonwiller, S.C., Haynes, R.K., King, ... Wang, H J., Planta Med., 59, 562, 19 93. 35 . Zhao, S.S. and Yeng, M.Y., Planta Med., 51, 233 , 1985. 36 . Mathis, C. and Ourisson, G., Phytochemistry, 2, 157, 19 63. 37 . Müller, W.E., Rolli, M., Schäfer,...

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BIOLOGICALLY ACTIVE NATURAL PRODUCTS: AGROCHEMICALS - CHAPTER 11 pps

... 6.4Hz, H-7), 1.22(6H,s,H-9 and H-10), 3. 72(1H,dt,J = 10.4,4.3Hz,H -3 ) . 13 CNMR(50MHz,CDCl 3 , TMS): δ22.0(q,C-9), 23. 8(q,C-10), 27.1(t,C-5), 30 .1(q,C-7), 31 .4(d,C-1), 34 .6(t,C-6), 44.7(t,C-2), 53. 5(C-4), ... 35 .0(t,C-6), 42.6(t,C-2), 48.4(d,C-4), 68.1(d,C -3 ) , 73. 3(s,C-8).p-Menthane -3 , 8-trans-diol(2). Mp 77. 3- 7 8 .3 (from Et2O-hexane), [α] 23 D± 0° (CHCl 3 ; c =0.1). IRνKBrmaxcm–1: 32 50, 2960, 2920, ... 0.87(3H,d,J = 6.4Hz, H-7), 1.22(3H,s,H-9), 1 .36 (3H,s,H-10), 4.41(1H,q,J = 2.4Hz,H -3 ) . 13 CNMR(50MHz, CDCl 3 , TMS): δ20.4 (t,C-5), 22 .3 (q,C-7), 25.7 (d,C-1), 28.8(q,C-9),29.0(q,C-10), 35 .0(t,C-6),...

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