... leaky tunnel were present, we would e xpect thebulkier nascent NH2OH to either leak out to bulk solvent,like the nascent NH3(route 4 in Scheme 1), and thereforeexhibit the same degree ... (Oakville, ON, Canada), except where mentionedotherwise. For HPLC experiments, a Waters 510 pump and680 controller were used for solvent delivery. Injections weremade using a Rheodyne 7725i sample ... acceptors are similar, and hencethey are expected to behave similarly within the proteins,provided no adverse steric interactions are encountered.Nascent NH3and its analoguesThe abilities...