... pseudosubstrates and as reversible and irreversible inhibitors of EIIGlc and EIIMan. Two assayswere employed: (a) nonvectorial phosphorylation of Glc(analogues) by solubilized and purified EII and byEII-containing ... 279([M + Na]+, 100%).RESULTS Synthesis of inhibitorsThe synthesis and characterization of compounds 1b, 1d, 1f,1g and 3b (Scheme 1) is reported for the first time, and theepoxypropyl derivative ... J. (1982) Synthesis of destomic and epidestomic acid, and their C-6 epimers.Carbohydr. Res. 104, 87–104.30. Johns, B.A., Pan, Y.T., Elbein, A.D. & Johnson, C.R. (1997) Synthesis and biological...