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ziegler natta catalysts and polymer stereochemistry

bài tập lớn xúc tác ziegler natta

bài tập lớn xúc tác ziegler natta

Hóa học - Dầu khí

... cấu tạo Xúc tác Ziegler- Natta hệ 2, sau: Hình :Công thức cấu tạo Xúc tác Ziegler- Natta hệ 2, 3và 12 Tiến hóa chất xúc tác Ziegler- Natta Nói chung, hệ thống chất xúc tác Ziegler- Natta định nghĩa ... động học trình xúc tác dùng hệ xúc tác ZieglerNatta Yêu cầu công nghệ sử dụng hệ xúc tác Ziegler- Natta Ý nghĩa vai trò xúc tác nói chung hệ xúc tác Ziegler- Natta nói riêng Phần I: Nguồn gốc lịch ... 2.5 2.6 Sự đời phát triển xúc tác ZieglerNatta 3.1 Sự đời xúc tác ZieglerNatta Các công trình nghiên cứu trình trùng hợp olefin Karl Ziegler Đức Giulio Natta Ý có tác động lớn ngành hóa...
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nmr spectra of polymers and polymer additives

nmr spectra of polymers and polymer additives

Đại cương

... polyethylene and ethylene copolymers and derivatives; (B) polypropylene and propylene copolymers and derivatives; and (C) polymers and copolymers based on other 1-olefins Many of these polymers, ... II.B.3— Polymers and Copolymers of Other 1-Olefins There are also commercially available homopolymers and copolymers made from higher 1-alkenes, such as 1butene, 3-methyl-1-propene (isobutylene), and ... Industrial Polymers Munich: Hanser Publishers, 1993 J Brandrup and E H Immergut Polymer Handbook New York: Wiley, 1975 J C Randall J Macromol Sci Rev Macromol Chem Phys C29:201, 1989 E Breitmaier and...
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Numerical studies on collective motion and polymer statistics

Numerical studies on collective motion and polymer statistics

Cao đẳng - Đại học

... fluids and try to understand the flow field generated by micro swimmers The second part of the thesis deals with polymer statistics Polymers are chains made up with repeating units For example, polymers ... hydrodynamic forces and try to understand the fluid particle interactions Chapter then studies a single polymer statistics We will review some famous existing polymer models and then focus on the ... obviously linear and we can see that ψ1 and ψ2 can be solved separately, with the right hand side of (2.2.64) being − sin φ sin θMΩ and cos φ sin θMΩ respectively With the right hand side fixed,...
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Binary metal oxide and polymer based liquid repellent self cleaning surfaces

Binary metal oxide and polymer based liquid repellent self cleaning surfaces

Kỹ thuật - Công nghệ

... Murugan, Dr Venugopal and Dr Molamma for teaching me new scientific concepts and polymer chemistry The knowledge that I imparted from them helped me to formulate new ideas and assisted me to advance ... excellent guidance and valuable advice in scientific discussions and furthermore, spending his time in showing and explaining the entire process involved in the fabrication and installations of ... beloved parents and my lovely brother Without my parents’ blessings and moral support, I don’t think I could have completed my PhD Studies Thank you mom and dad!!! I love you and am forever indebted...
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Well defined silica polymer core shell hybrids and polymer hollow structures synthesis, characterization and application

Well defined silica polymer core shell hybrids and polymer hollow structures synthesis, characterization and application

Cao đẳng - Đại học

... SILICA -POLYMER CORE-SHELL HYBRIDS AND POLYMER HOLLOW STRUCTURES: SYNTHESIS, CHRACTERIZATION AND APPLICATIONS LI GUOLIANG M Sci., Polymer Chemistry and Physics Nankai University 2007 B Eng., Polymer ... synthesize hollow polymer micro- and nanospheres with novel morphology and functions via a combination of inorganic and polymer synthesis and optimize the applications of these hollow polymer structures ... microspheres, and (e) and (f) Ag@air@P(MAA-co-DVB)-click-PNIPAM hybrid microrattles Figure 5.22 XPS wide-scan and C 1s core-level spectra of the (a and b) Au@SiO2@P(MAA-co-DVB), and (c and d) Au@SiO2@P(MAA-co-DVB)-click-PEG...
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Synthesis and fabrication of nanostructional functional polymeric materials via plasma processes and polymer modification

Synthesis and fabrication of nanostructional functional polymeric materials via plasma processes and polymer modification

Cao đẳng - Đại học

... Research Objectives and Scope … …………… … Chapter Literature Survey ………… ………………….….….……… …… 2.1 2.2 Fluoropolymers and Plasma Polymerization …………………… 10 Polymer Modification and Fine Polymer Nanostructures ... LITERATURE SURVEY Chapter 2.1 Fluoropolymers and Plasma Polymerization 2.1.1 Applications of Plasma Polymerized Fluoropolymers Fluoropolymer nanostructures and nanopatterns have broad applications ... contributes to both the polymer- forming and polymer- degrading processes Plasma polymerization is therefore a balance between the polymer- forming and the ablation process, and the balance can shift...
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Materials for solid base catalysts and oxygen storage

Materials for solid base catalysts and oxygen storage

Cao đẳng - Đại học

... solid catalysts have many advantages over liquid catalysts, such as reduced corrosion and environmental problems Solid acid and base catalysts have been used in many industrial processes and their ... Zhong Liang, Jeck Fei for their help and encouragement I would also like to thank my parents, brother and my husband for their constant support, understanding and encouragement Lastly, I am indebted ... the demand in the petroleum and petrochemical industries In contrast, fewer efforts have been made to study solid base catalysts Comparing the industrial applications of solid acid and base catalysts, ...
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Clays and oxide minerals as catalysts and nanocatalysts in Fentonlike reactions

Clays and oxide minerals as catalysts and nanocatalysts in Fentonlike reactions

Hóa học - Dầu khí

... pumice particles (Kitis and Kaplan, 2007), and ironimmobilized aluminates (Muthuvel and Swaminathan, 2008) Clays and oxide minerals, either as such or as supports of iron and other metal species, ... et al., 2008) and iron-oxide minerals (Lin and Gurol, 1998; Kwan and Voelker, 2002, 2003; Wu et al., 2006; Matta et al., 2007; Hanna et al., 2008; Liou and Lu, 2008) However, these catalysts, especially ... 2008) and iron-oxide minerals (Lin and Gurol, 1998; Kwan and Voelker, 2002, 2003; Wu et al., 2006; Matta et al., 2007; Hanna et al., 2008; Liou and Lu, 2008) have been proposed as heterogeneous catalysts...
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In vitro and in vivo evaluation of transferrin conjugated lipid shell and polymer core nanoparticles for targeted delivery of docetaxel

In vitro and in vivo evaluation of transferrin conjugated lipid shell and polymer core nanoparticles for targeted delivery of docetaxel

Tổng hợp

... synthesis and characterization of lipid shell and polymer core nanoparticles (LPNPs) are discussed in Chapter while the synthesis and characterization of transferrin conjugated lipid shell and polymer ... potential and drug encapsulation 49 efficiency of docetaxel-loaded lipid shell and polymer core nanoparticles Table 2: Size, polydispersity and zeta potential of docetaxel-loaded 60 PLGA/50-50 NPs and ... CHAPTER 3: SYNTHESIS AND CHARACTERIZATION OF LIPID SHELL 44 AND POLYMER CORE NANOPARTICLES 3.1 Introduction 44 3.2 Materials 45 3.3 Methods 45 3.3.1 Preparation of Lipid Shell and Polymer Core Nanoparticles...
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Physical effects of nano particles and polymer on vesicles

Physical effects of nano particles and polymer on vesicles

Kỹ thuật - Công nghệ

... such as plasma membranes and various organelle membranes, which mainly consist of complex polymers and lipids 19 2.4 Rheology Rheology is an important area of colloid and polymer science Materials ... thickness and the number of lamellae; molecular weight; degree of polydispersity; vesicle-vesicle, vesicle-solvent and vesicle-other species (i.e., proteins, polymers, colloidal particles and others) ... effectiveness of drugs and minimize their toxicity by encapsulating the drugs in vesicles and delivering them efficiently and specifically to the affected areas (Hiemenz and Rajagopalan, 1997)...
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Immobilizing catalysts in continuous flow micro reactors polymer encapsulated metals and engineered biofilms

Immobilizing catalysts in continuous flow micro reactors polymer encapsulated metals and engineered biofilms

Cao đẳng - Đại học

... ligand (yellow sticks) and αvβ3 integrin αv and β3 residues are labeled blue and red, respectively Oxygen and nitrogen atoms are visualized as red and blue balls, respectively Hydrogen bond and ... parents, brothers and sister for their love, understanding and everlasting support Last but not least, I would like to thank my fiancé, Low Chin Yen and his family for their love and care ii Table ... mm, length 115.0 mm) A polystyrene backbone polymer with crosslinkable functional groups was synthesized and characterized by GPC and NMR The subsequent polymerencapsulated palladium which formed...
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Isolation and characterization of an extracellular polymer closely related to flocculation of activated sludge

Isolation and characterization of an extracellular polymer closely related to flocculation of activated sludge

Môi trường

... pronase-digested polymer, the heat-treated polymer and the intact polymer for kaolin clay (each polymer concentration was ppm) The flocculating activity of the pronase-digested polymer significantly ... extracellular polymer Flocculating activities of the extracellular polymer are summarized in Table The polymer showed flocculating activity for kaolin clay and activated charcoal suspension, and stimulated ... the polymer Extent of flocculation (%) 100 50 0 Time (min) Fig Effect of pronase-digestion and heat treatment of extracellular polymer on flocculating activity Intact polymer Pronase-digested polymer...
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Barriers and Catalysts to Sound Financial Management Systems in Small Sized Enterprises

Barriers and Catalysts to Sound Financial Management Systems in Small Sized Enterprises

Tài chính doanh nghiệp

... emphasis on financial reporting and year end accounts and little assistance on management accounting information, systems and business strategy development Barriers and Catalysts to Sound Financial ... the characteristics of the owner/director and business development training and support The study was based on small businesses in central and north Scotland The parameters selected for categorising ... angel demanded appropriate accounting systems and required the firm to change, and recommended who should replace, its external accountant The new accountant ‘has good business sense and takes...
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Tài liệu POLYMER AGING, STABILIZERS AND AMPHIPHILIC BLOCK COPOLYMERS ppt

Tài liệu POLYMER AGING, STABILIZERS AND AMPHIPHILIC BLOCK COPOLYMERS ppt

Sức khỏe giới tính

... Stabilizers and Amphiphilic Block Copolymers Liudvikas Segewicz and Marijus Petrowsky (Editors) 2010 ISBN: 978-1-60692-928-5 POLYMER SCIENCE AND TECHNOLOGY SERIES POLYMER AGING, STABILIZERS AND AMPHIPHILIC ... the polymer by the way of immobilization of the chiral ligand Different types of ligand immobilization are presented: pendant ligands anchored on a polymer prepared by a polymer reaction, ligands ... solution temperature, and/ or pH, as well as due to complexation This book also reviews the contribution of soluble polymer- supported ligands and isoluble polymersupported ligands to asymmetric catalysis...
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Tài liệu DRUG STEREOCHEMISTRY Analytical Methods and F''''hannacology Second Edition_2 ppt

Tài liệu DRUG STEREOCHEMISTRY Analytical Methods and F''''hannacology Second Edition_2 ppt

Sức khỏe giới tính

... severaland step series of reactions involvingring opening and amide formation with pyrrolidine,oxidationtothealdehyde,epimerization,reduction ,and ether formation ledto amide [34] Ozonolysis and ... theunexpectedloss of tosylate and aziridine formation Olefin formation from [56] via the N-oxide and chain extensiongaveacid [57J Iodolactonization and tri-n-butyltin hydride reduction in thestandard fashion ... protectionof the primaryand secondary hydroxyl groups as a tosylate and ethoxyethyl ether, respectively and reaction with lithium dibutylcuprate.Treatment of [l061 with acid ledtodeprotectionand lactonization...
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Tài liệu Báo cáo khoa học: The stereochemistry of benzo[a]pyrene-2¢-deoxyguanosine adducts affects DNA methylation by SssI and HhaI DNA methyltransferases pptx

Tài liệu Báo cáo khoa học: The stereochemistry of benzo[a]pyrene-2¢-deoxyguanosine adducts affects DNA methylation by SssI and HhaI DNA methyltransferases pptx

Báo cáo khoa học

... Kd (K rel ) and kcat (k rel ) values for binding and d cat methylation of DNA containing (+)-cis-B[a]PN2-dG and (+)-trans-B[a]P-N2-dG adducts by M.SssI (A) and M.HhaI (B) The K rel and k rel d ... and Moscow State University), NIH Grant CA 099194 (New York University), and RFBR Grants 04-04-49488 and 05-0449690 (Moscow State University) We thank Dr B Jack and Dr G Wilson from New England ... M.SssI and M.HhaI The rates of methylation of the X+CG ⁄ CGC, GCX+ ⁄ CGC, X+CG ⁄ CGM and GCX+ ⁄ CGM duplexes by SssI and HhaI MTases were determined under steadystate conditions (Fig 4), and the...
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Oriented silicon nanowires on silicon substrates from oxide assisted growth and gold catalysts

Oriented silicon nanowires on silicon substrates from oxide assisted growth and gold catalysts

Vật lý

... °C and (b) 700 °C The scale bar is lm (c) TEM image of a SiNW with an Au particle tip and (d) corresponding silicon elemental mapping The scale bar is 50 nm (e) EDX spectrum of the nanowire and ... grew along the Æ1 2æ and Æ1 0æ directions, similar to SiNWs grown by the OAG method without any catalysts As shown in Fig 4a, the side surfaces of the SiNW are made of the {1 1} and {1 0} facets ... the SiNWs and limited the wire diameter The present SiO–Au approach offers certain advantages over the common metal-catalytic VLS method and the OAG method, such as the absence of toxic and flammable...
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