Thermal analysis fundamentals and applications to polymer science hatakeyama, t quinn, f x

Thermal Analysis - Fundamentals and Applications to Polymer Science Part 8 pot

... Calorimetry and Thermal Analysis from Y Yamamoto, M Nakazato and Y Saito, Netsu Sokutei, 16, 58, (1 989 )) film was then annealed by sandwiching it between metal plates, one of which was maintained at 4 38 ... 430 K and at 439 K are attributed to melting of α-type crystals and melting of recrystallized α-type crystals, respectively At high heating rates only the melting peaks of ß-type and α-type crystals ... determined using X-ray diffractometry, IR spectroscopy and DSC where Tm is the melting temperature of the polymer- diluent system, Vu and V1 are the molar volumes of the repeating unit and the diluent,...

Thermal Analysis - Fundamentals and Applications to Polymer Science Part 9 ppsx

... Crystallization of Polymers, McGraw-Hill, New York ( 196 4) [23] Yamamoto, Y , Nakazato, M and Saito, Y Netsu Sokutei 16, 58 ( 198 9) file:///Q|/t_/t_118.htm2/13/2006 12:58: 29 PM Document Page 1 19 6— Other Thermal ... Paulik, J and Paulik, F Journal of Thermal Analysis 17, 507 ( 197 9); and Analytica Chimica Acta 124, 341 ( 198 1) [18] Khanna, Y.P , Kuhn, W.P and Sichina, W.J Macromelecules 28, 2644 ( 199 5) [ 19] Reading, ... Hatakeyama, T and Kanetsuna, H Thermochimica Acta 138, 327 ( 198 9) [2] Takahashi, Y Thermochimica Acta 88, 199 ( 198 5) [3] Ozawa, T and Kanari, K Thermochimica acta 253, 183 ( 199 5) [4] Freeman, E.S and Carroll,...

Thermal Analysis - Fundamentals and Applications to Polymer Science Part 10 pot

... than in the case of DSC-RLI 6.5 Simultaneous DSC-X-Ray Analysis Simultaneous DSC-X-ray analysis is a very powerful and versatile method for following changes in the morphology and structure of a ... for DSC-TLI (Section 6.4.2), are available for simultaneous DSC-small-angle X-ray scattering, wide-angle X-ray diffraction and synchrotron orbital radiation analysis (SAXS, 0.25 < 2θ ≤ 10 ; WAXD, ... DMA is a sensitive method to measure Tg of polymers Side-chain or main-chain motion in specific regions of the polymer and local mode relaxations which cannot be monitored by DSC can be observed...

Thermal Analysis - Fundamentals and Applications to Polymer Science Part 11 pdf

... Figure 6.27 Thermal diffusivity of n-alkane as a function of temperature and the corresponding DSC curve The lowtemperature feature is due to a crystal -to- crystal transition and the high-temperature ... form of short-duration pulses and the thermal emission transient observed by means of a wide-band infrared detector (Figure 6.32) An optothermal decay curve plots the intensity of the thermal emission ... material, D is 0.14 W/Km 6 .11 Micro -thermal Analysis (µTA) Micro -thermal analysis (µTATM) [10] is a recently developed technique in which the cantilever tip of an atomic force microscope (AFM)...

Thermal Analysis - Fundamentals and Applications to Polymer Science Part 12 doc

... x1 0-2 m3/mol Boltzmann's constant k = R/L 1.380 658 (12) x1 0-2 3 J/K Acceleration due to gravity g 9.806 65 m/s2 file:///Q|/t_/t_167.htm2/13/2006 12: 59:58 PM 0(µ0 c2 )-1 8.854 187 816 x1 0-1 2 F/m Document ... 0.239 006 0.947 831 xl 0-3 2.777 778 x1 0-7 9.868 96 x1 0-3 0.101 972 4.184 3.965 73 x1 0-3 1.162 222 x1 0-6 4 .129 29 x1 0-2 0.426649 1.055 040 x103 2.521 61 x102 2.930 667 x1 0-4 10. 412 44 1.075 84 x102 ... C(0) + C(l)x + + C(10)x10, 100 ≤ T/K ≤ 120 0 and x = (T/ K - 650)/550 C(0) = 1 .127 05 C(4) = -0 .23778 C(8) = -0 .47824 C(1) = 0.23260 C(5) = -0 .10023 C(9) = -0 .37623 C(2) = 0.21704 C(6) = 0.15393...

Thermal Analysis - Fundamentals and Applications to Polymer Science Part 13 ppsx

... 110, 111, 115, 139 , 159 DSC melting curve, PE 32, 33 DSC, automated 21 heat-flux type 8, 9, 10, 160 power compensation 11, 12, 160 DSC-RLI 137 DSC-TLI 137 DSC-X-ray analysis 137 , 139 DSC high sensitivity ... Viscoelasticity 130 , 131 , 132 Viscosity 126, 132 Volume expansion coefficient 133 , 136 W Water 31, 96, 109, 111, 113, 115 WAXD, see Thermally stimulated current Wide-angle X-ray scattering 140 William-Landel-Ferry ... Dynamic loss modulus 130 , 131 Dynamic mechanical analysis 1, 4, 91, 125, 159 Dynamic method, see Non-isothermal method Dynamic modulus 130 , 131 , 132 Dynamic storage modulus 130 , 131 E Earthquake...