Zeolite-like metal–organic frameworks (ZMOFs):design, synthesis, and properties
Zeolite-like metal–organic frameworks (ZMOFs):design, synthesis, and properties
... number of zeolite-like networks from hypothetical databases.89 The edge-expansion approach to zeolite-like metal–organic frameworks (ZMOFs) 3.1 ZMOFs from angular ditopic N-donor ligands: pyrimidine-, ... imidazolate ligands.100 Accordingly, half of the negatively charged imidazolate ligands were replaced by neutral ligands, giving rise to new materials, named MVLIF-1 and MVLIF-2 (MVLIF stands for mixed ... on identifying possible strategies and relevant examples of MOFs that possess periodic intra-framework organic functionality and zeolite-like topologies and properties The portrayed examples demonstrate...
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DESIGN, SYNTHESIS AND PROPERTIES OF METAL COMPLEXES AND COORDINATION POLYMERS FOR 2+2 PHOTO CYCLOADDITION REACTIONS
... representation of transformation of 1D CP 1-22 into 3D MOF through photo cycloaddition reaction Figure 1- 11 PSM of 3D MOF through solid state [2+2] photo 1-23 cycloaddition reaction Figure 1- 12 Photo cycloaddition ... PSM of 3D MOF through solid state [2+2] photoreaction 1.6.3 Photoreactivity in metal complexes using monodentate ligand Compared to the bidentate ligands, photoreactivity of monodentate ligands ... 1.6.1 Photoreactivity of metal complexes using bidentate 1-15 ligand 1.6.2 Photoreactivity in CPs using bidentate ligand 1-19 1.6.3 Photoreactivity in metal complexes using monodentate 1-23 ligand...
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Zeolite like metal–organic frameworks (ZMOFs) (1)
... with uniwork inside various zeolites, for instance, zeolites Y, b, and L, form pore sizes USY zeolite was adopted as the template to and then carbonized the polymer /zeolite composites to obtain ... walls of zeolites have a uniThe Mallouk group synthesized phenol–formaldehyde (PF) form thickness of < nm, zeolites have been used as inorganic polymers by making use of the acidity of the zeolite ... with the results obtained by Kyotani and zeolite Carbonization followed by the removal of the zeolite co-workers Moreover, the ordered structure of the zeolite template produced microporous carbon...
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Zeolite like metal–organic frameworks (ZMOFs)
... as reflected in the high number of zeolite- like networks from hypothetical databases.89 The edge-expansion approach to zeolite- like metal–organic frameworks (ZMOFs) 3.1 ZMOFs from angular ditopic ... organic functionality and zeolite- like topologies and properties The portrayed examples demonstrate that complex structures, based on non-default nets, such as zeolite- like MOFs (ZMOFs), not only can ... of MOFs related to zeolite nets The focus will be placed on the breadth and efficacy of design routes (Fig 1), delineating avenues toward the construction of zeolite- like MOFs (ZMOFs): (i) based...
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Design, synthesis and applications of Metal Organic Frameworks
... Assembly of metal organic frameworks (MOFs) by the copolymerization of metal ions with organic linkers to give (a) flexible metal bipyridine structures with expanded diamond topology and (b) rigid metal carboxylate ... MOFs—namely synthesis of new ligands to expand the library of molecular building blocks for constructing MOFs as well as synthesis of MOFs from those ligands, investigation of several MOF systems ... Assembly of metal organic frameworks (MOFs) by the copolymerization of metal ions with organic linkers to give (a) flexible metal bipyridine structures with expanded diamond topology and (b) rigid metal carboxylate...
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Nanoscale metal-organic frameworks synthesis and application of bimodal micromeso-structure and nanocrystals with controlled size and shape
... preparing bimodal micro- and meso-porous MOF nanocrystals, uniform nanosized MOFs with controlled- shape and size and subsequently, the extensive application of the prepared nanosized MOFs The first objective ... preparation of mesoporous MOF nanocrystals and uniform nanoscale MOFs with desired shape and size 1.2 Objectives of the thesis The aim of this thesis is to develop synthetic methods for preparing bimodal ... developed to achieve bimodal micro/mesoporous MOF nanocrystals as well as nanosized MOFs with controlled size and shape In addition, using the synthesized MOF nanocrystals as templates, a new hollow...
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Molecular simulations of biofuel and water purification in metal organic frameworks
... increases with decreasing cavity size and also with increasing the number of carbon atoms in organic linker.140 Jiang and Sandler studied the separation of linear and branched alkanes in IRMOF-1 ... hydrolysis reaction and water stability in MOFs Among MOF-5, IRMOF-10 and MOF-74, they found MOF-74 has a superior resistance to water than other MOFs.149 The presence of water in MOFs influences not ... heats of water adsorption in Li-, Na- and Csexchanged rho-ZMOF as a function of loading 47 Figure 2.8 Locations of water in the single 8-membered ring in Li-, Na- and Cs-exchanged rho-ZMOF at...
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Computational study of adsorption and diffusion in metal organic frameworks
... linkers in various MOFs (IRMOF-1, IRMOF-3, IRMOF-1-4NH2, IRMOF-6, IRMOF-8, IRMOF-12, IRMOF-14, IRMOF-18 and IRMOF-993) and found that the larger linkers bind more H2 molecules and addition of ... predicted in catenated and non-catenated MOFs To study the adsorption and diffusion of a model drug (ibuprofen) in mesoporous MIL-101 and UMCM-1 The energetics and dynamics of ibuprofen in the MOFs ... (left) and volumetric (right) isotherms of CO2 116 adsorption in IRMOF1, Mg-IRMOF1, Be-IRMOF1, IRMOF1 (NH2)4, IRMOF10, IRMOF13, IRMOF14, UMCM-1, F-MOF1 and COF102 Figure 5.9 Gravimetric (left) and...
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Metal organic frameworks IRMOF 8, ZIP 9, MOF 199 and IRMOF 3 as catalysts for the friedel crafts acylation, knoevenagel, aza michael and paal knorr reactions
... NGUYEN THI LE LIEN METAL- ORGANIC FRAMEWORKS IRMOF- 8, ZIF -9, MOF1 99 AND IRMOF- 3 AS CATALYSTS FOR THE FRIEDEL CRAFTS ACYLATION, KNOEVENAGEL, AZA- MICHAEL AND PAAL- KNORR REACTIONS Major: Organic chemical ... measurements, given the high surface area materials of the four MOFs synthesized in this study The four MOFs: IRMOF- 8, ZIF -9, MOF- 1 99, IRMOF- 3 were applied as catalysts in the four organic reactions: ... 31 2.2 MOF synthesis 32 2.2.1 IRMOF- 8 32 2.2.2 ZIF-9 32 2.2 .3 MOF- 199 33 2.2.4 IRMOF- 3 33 2 .3 Catalytic studies 33 vi 2 .3. 1...
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Tài liệu Metal Organic Chemical Vapor Deposition: Technology and Equipment docx
... MOCVD Technology and Equipment 201 24 CVD Metalorganics for Vapor Phase Epitaxy Product Guide and Literature Review, Rohm and Haas, 60 Willow Street, North Andover, MA 01845 25 Haigh, J., and O’Brien, ... organometallic chemical vapor deposition (OMCVD), metal- organic vapor phase epitaxy (MOVPE—the name used by one of the most important conferences), organometallic pyrolysis, or metal- alkyl vapor ... (From Killeen and Breiland.)[72] Chapter 4: MOCVD Technology and Equipment 6.3 199 New Materials Although MOCVD has been used to deposit a large number of III-V and II-VI materials and structures,...
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Ứng dụng của Metal-Organic Frameworks ppt
... nghiên cứu tiến hành phòng thí nghiệm chứng tỏ khả tách lưu trữ khí MOF (N2, Ar, CO2, CH4, and H2) [1–9] Cấu trúc MOF-5 ...
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Aircraft Design: Synthesis and Analysis - part 1 doc
... the DC- 9 -1 0, a 77,000 lb, 80 passenger airplane grew into a DC- 9-2 0, then the -3 0, -4 0, -5 0, -8 0 then on to the MD-80 and MD-90 series The MD-90 weighs as much as 17 2,000 lbs and can carry 15 0 ... development of the DC-9 and DC -1 0 , and taught at Stanford University after that for 20 years To a large extent, this is his course Instructions This version of Aircraft Design: Synthesis and Analysis is ... In 19 5 8-5 9, Boeing and Douglas introduced the jet transport By 19 61 again, the airlines were in financial trouble and 707 and DC-8 production was down to a trickle The increase from 13 0 or 14 0...
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Aircraft Design: Synthesis and Analysis - part 2 pptx
... 765 20 0 1,1 42 248 1983 173 23 1 511 315 798 20 8 1,190 25 9 1984 184 24 5 555 343 847 22 1 1 ,27 7 27 8 1985 194 25 9 590 364 899 23 5 1,367 29 7 1986 198 26 4 603 3 72 960 25 1 1,4 52 316 1987 22 2 29 6 688 425 ... 23 6.9 1990 55 25 0.0 22 1 368.3 485 20 1 .2 783 24 9.4 1991 51 23 1.8 21 2 353.3 469 194.6 760 24 2.0 19 92 55 25 0.0 23 9 398.3 484 20 0.8 806 25 6.7 1993 57 25 9.1 24 5 408.3 487 20 2.1 814 25 9 .2 * By region ... 3 82 158.5 561 178.7 1986 36 163.6 125 20 8.3 431 178.8 622 198.1 1987 42 190.9 151 25 1.7 459 190.5 681 21 6.9 1988 48 21 8 .2 180 300.0 475 197.1 726 23 1 .2 1989 50 22 7.3 197 328 .3 4 72 195.9 744 23 6.9...
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Aircraft Design: Synthesis and Analysis - part 3 ppt
... 222 A300/A310/A 330 /A340 9 252 237 237 MD11 9 252 235 235 L1011 9 252 244 244 777 16 33 3/ 232 266 33 6 A3xx Study (1994) 16 10 34 3 /33 256 30 8 747 18 10 34 3/242 266 33 6 A380 Coach 19 11 35 3/242 MD-12 ... 104 Dash 8 -3 00 4 22 1 13 1 13 Concorde 5 23 134 134 BAC111 5 23 130 130 F100 5 23 131 .5 1 43 MD80/717 6 33 148 737 /757 6 33 147 DC8 6 33 140 140 BAE146 6 33 155.5 A320 7 232 198 217 767 7 232 186 7J7 ... 19 11 234 2/242 30 7 37 3 Boeing NLA (study) 26 10 34 3 /34 3 /33 261 4 03 A 3- deck guess 29 12 34 3 /36 3/ 232 33 5 4 03 Based on Douglas Study Exercise 2: Fuselage Cross-Section Enter fuselage cross-section...
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