Heterogeneous catalysis in protodecarboxylation and c c bond formation 2
Heterogeneous catalysis in protodecarboxylation and c c bond formation 1
... Experimental 17 9 6.2 .1 Preparation of supported Cu catalyst 17 9 6.2.2 Catalytic studies 18 1 Results and discussion 18 1 6.3 .1 Characterisation of catalysts 18 1 6.3.2 Catalytic testing 19 1 6.3 6.3.2 .1 194 ... Deposition-precipitation 15 1. 1.3.4 1. 2 Impregnation Ion exchange 17 Ag, Cu and Pd nanocatalysts in cross coupling reactions 1. 2 .1 18 21 Suzuki coupling V 1. 2.2 Ullmann reaction 23 1. 3 Decarboxylative ... reaction 17 0 5.4 Conclusion 17 1 5.5 References 17 2 Chapter 6: Heterogeneous catalysts for the decarboxylative cross-coupling of aryl carboxylic acids and aryl halides 17 4 6 .1 Introduction 17 4 6.2...
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Heterogeneous catalysis in protodecarboxylation and c c bond formation 2
... group O O CO OC OC CO C OC CO M M OC CH3 OC CH3 C + CO OC CO M CH3 OC CO CO CO (c) Migratory insertion of hydride/ beta-hydride elimination (reverse) H M CH2 CH2 M H CH2 M C H2 CH2 CH3 (d) Oxidative ... 1.37 1.44 1 .28 Density/ g/cm3 12. 38 10.5 8.96 Melting point/ C 1555 9 62 1085 Electronegativity (Pauling scale) 2. 20 1.93 1.9 Atomic weight f .c. c.: face-centred cubic Pd, Ag, and Cu nanocatalysts ... Pd /C in the presence of zinc as reducing reagent (Scheme 1.4) [69] R1 Cl R1 + Zn + OH- R2 mol % Pd /C mol % PEG-400 60- 120 oC, 1 -2 h, H2O R2 + R2 R1 R2 + ZnO + H2O + Cl- R1 where R1= H, CH3 and R2=...
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Báo cáo khoa học: Protein folding and disulfide bond formation in the eukaryotic cell pptx
... emerge in the coming years Protein targeting and disulfide bond formation in mitochondria Not only must proteins fold in the ER, but they must also be targeted to the right intracellular or extracellular ... Protein folding and disulfide formation A M Benham Elsinore focused mainly on protein folding in the eukaryotic endoplasmic reticulum (ER) and mitochondria An important consideration in these ... elucidating the folding pathways of disulfide bond- containing proteins [8] The Ventura group and others have made considerable progress in studying three model proteins from human pests, namely the...
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Tài liệu Báo cáo khoa học: Insights into and speculations about snake venom metalloproteinase (SVMP) synthesis, folding and disulfide bond formation and their contribution to venom complexity pdf
... [9] Superficially, one could simply Snake venom metalloproteinases and venom complexity attribute venom complexity to genomic ⁄ transcriptomic complexity, and to a certain degree this is the case ... 2008 FEBS 3017 Snake venom metalloproteinases and venom complexity J W Fox and S M T Serrano proteins are synthesized in the cytoplasm of secretory cells in the gland and transferred to the rough ... variety of proteomic and transcriptomic investigations of snake venom and venom glands respectively, numerous databases have been generated that illuminate the complexity of snake venoms, particularly...
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Báo cáo khoa học: Cytoglobin conformations and disulfide bond formation pdf
... the role of the disulfide bond in protein function and its involvement in the tertiary and quaternary structures Cytoglobin conformations and disulfide bond formation A Results and Discussion Quaternary ... government works 2701 Cytoglobin conformations and disulfide bond formation heterogeneity of kinetics After breaking the S–S bond, the histidine relaxes towards a stable conformation, and kinetic curves ... 8539–8547 Cytoglobin conformations and disulfide bond formation 10 Hankeln T, Ebner B, Fuchs C, Gerlach F, Haberkamp M, Laufs TL, Roesner A, Schmidt M, Weich B, Wystub S et al (2005) Neuroglobin and cytoglobin...
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Báo cáo khoa học: Aegyptin displays high-affinity for the von Willebrand factor binding site (RGQOGVMGF) in collagen and inhibits carotid thrombus formation in vivo ppt
... the sequence involved in collagen interaction with vWF, and also interacts with GPVI and integrin a2b1 binding sites Aegyptin effectively inhibits carotid thrombus formation in vivo Results Aegyptin ... detectable for collagen (lower right panel) Aegyptin binds with high affinity to the vWF binding site in collagen, independently of hydroxyproline In an attempt to identify the binding sites involved in ... Mosquito collagen -binding protein A C Fig Aegyptin displays high affinity for the vWF binding site of collagen Sensorgrams show aegyptin binding to immobilized cross-linked RGQOGVMGF (A), linear...
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Advances in Optical and Photonic Devices 2011 Part 2 pptx
... Vol 21 , No 1, (January 20 09) 30- 32 20 Advances in Optical and Photonic Devices Van der Poel, M.; Mork, J.; Somers, A.; Forchel, A.; Reithmaier, J P & Eisenstein, G (20 06) Ultrafast gain and index ... island plane at a given bias 24 Advances in Optical and Photonic Devices The photonic (de Broglie) quantum corral effect imposes a λ /2 period transient ordering upon the imminently recombinant ... threshold is poor suffering from the soft lasing turn-on behavior here 26 Advances in Optical and Photonic Devices Spectral Intensity (a.u) θ = 10o m5 θ = 15o φ = 20 μm I =2. 5 mA T = 18oC 845 m11...
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Physical Processes in Earth and Environmental Sciences Phần 2 ppt
... Q1= Q2 = a1u1 = a2u2 u1 > u a = area a2 > a1 Q2 a2 r1 u2 Fig 2. 21 Continuity of volume: constant density case in 1D u1 r = variable m1= m2 = a1r1u1 = a2r2u2 a1 r2 m1 a2 u2 Fig 2. 22 Continuity ... Chapter Salinity g kg–1 1040 1030 AVERAGE SEAWATER 1 020 30 10 20 30 Salinity (g kg–1) 40 16 50 Fig 2. 10 Variation of seawater density with salinity 20 22 24 20 30 26 10 freezing point 30 Salinity ... defined in Section 2. 4 and are best LEED-Ch- 02. qxd 11 /26 /05 12: 45 Page 32 32 Chapter (a) (b) Cylinder axis normal to page Fig 2. 19 Flow visualization photos (a) Dye introduced continuously into...
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báo cáo khoa học: "Systematic evaluation of implementation fidelity of complex interventions in health and social care Henna Hasson1,2,3" pdf
... systematically implementation fidelity and possible factors influencing fidelity of complex interventions in health and social care The purpose is to test the conceptual framework for implementation fidelity ... Discussion The aim of this project is to systematically evaluate implementation fidelity and possible factors influencing fidelity of complex interventions in health and social care The intention is ... three interventions are complex in nature, including several active ingredients In addition, the interventions are conducted in complex health or social care environments where several professional...
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Flocculation In Natural And Engineered Environmental Systems - Chapter 2 pdf
... Copyright 20 05 by CRC Press “L1615_S001” — 20 04/11/18 — 22 :34 — page 24 — #2 Overview of Flocculation Processes in Freshwater Ecosystems Gary G Leppard and Ian G Droppo CONTENTS 2. 1 2. 2 2. 3 2. 4 2. 5 2. 6 ... sources and with a variety of compositions 1-5 667 0-6 1 5-7 /05/$0.00+$1.50 © 20 05 by CRC Press Copyright 20 05 by CRC Press “L1615_C0 02 — 20 04/11/19 — 02: 47 — page 25 — #1 25 Flocculation in Natural and ... Copyright 20 05 by CRC Press “L1615_C0 02 — 20 04/11/19 — 02: 47 — page 27 — #3 Flocculation in Natural and Engineered Environmental Systems 28 (a) (b) (c) (d) (f) (g) (e) m (h) (i) (j) (k) (l) (m) 20 0...
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Tài liệu Debugging C and C++ code in a Unix environment ppt
... if you are interested in it Chapter Aspects of debugging C and C+ + code Debugging C and C+ + code entails noticing, localising, understanding and repairing bugs Noticing and localising a bug You ... 21 Chapter Aspects of debugging C and C+ + code System call tracers A system call tracer is a program that allows you to see what system calls (including parameters and return values) a process ... the causes of problems with C and C+ + code, is the policy of requiring explicit allocation and deallocation of dynamic storage (malloc(2) and free(2) (C) or new and delete (C+ +)) As C and C+ +...
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Tài liệu Báo cáo khoa học: Verprolin function in endocytosis and actin organization Roles of the Las17p (yeast WASP)-binding domain and a novel C-terminal actin-binding domain doc
... both a novel C-terminal actin- binding submodule (CABS) containing a novel actin monomer binding verprolin homology C-terminal (VH2-C) domain and a second submodule comprising the previously characterized ... actinbinding domain (this actin- binding domain has not yet been mapped) [23] We name the actin- binding domain that we have identified VH2-C and VH2-N because it is not yet clear how closely these domains ... Type I myosins can interact via an acidic tail (A) domain with the Arp2 ⁄ complex like Las17p, but they lack an actin- monomer-binding WH2 domain, which in WASP-family proteins (including Las17p) ...
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RAN D OM WALK IN RANDOM AND NO N- RAND OM ENVIRONMENTS h E C D N D E D I T I O N pdf
... N O N- RAND O M ENVIRONMENTS h E C D N D E D I T I O N This page intentionally left blank L RANDEOM WALK IN RANDOM AND N NON RANDOM N M ENVIRONMENTS ENVIRO E C O N EDITION D Pal Revesz Technische ... presented In some cases more proofs are given, in some cases none The proofs are omitted when they can be obtained by routine methods and when they are too long and too technical In both cases ... interesting ones and to fit them in this Second Edition Many of my friends helped me to find the most important new results and to discover some of the mistakes in the First Edition My special thanks...
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Báo cáo khoa học: Respective roles of the catalytic domains and C-terminal tail peptides in the oligomerization and secretory trafficking of human acetylcholinesterase and butyrylcholinesterase potx
... both the catalytic domain and the C-terminal t peptides contribute to the control of oligomerization and secretion, in a complex interplay Origin and significance of the difference between the t peptides ... C-terminal t peptides not in uence the catalytic activity of AChE and BChE We examined the possible in uence of the C-terminal peptides on the AChE and BChE activities by comparing the catalytic ... followed by small C-terminal t peptides of 40 and 41 residues, respectively In the present study, the catalytic domains are indicated by capital letters (A and B) and the C-terminal peptides by lower...
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Từ khóa: Nghiên cứu sự biến đổi một số cytokin ở bệnh nhân xơ cứng bì hệ thốngBáo cáo quy trình mua hàng CT CP Công Nghệ NPVMột số giải pháp nâng cao chất lượng streaming thích ứng video trên nền giao thức HTTPGiáo án Sinh học 11 bài 13: Thực hành phát hiện diệp lục và carôtenôitGiáo án Sinh học 11 bài 13: Thực hành phát hiện diệp lục và carôtenôitĐỒ ÁN NGHIÊN CỨU CÔNG NGHỆ KẾT NỐI VÔ TUYẾN CỰ LY XA, CÔNG SUẤT THẤP LPWANPhát triển du lịch bền vững trên cơ sở bảo vệ môi trường tự nhiên vịnh hạ longNghiên cứu về mô hình thống kê học sâu và ứng dụng trong nhận dạng chữ viết tay hạn chếĐịnh tội danh từ thực tiễn huyện Cần Giuộc, tỉnh Long An (Luận văn thạc sĩ)Thơ nôm tứ tuyệt trào phúng hồ xuân hươngTổ chức và hoạt động của Phòng Tư pháp từ thực tiễn tỉnh Phú Thọ (Luận văn thạc sĩ)Quản lý nợ xấu tại Agribank chi nhánh huyện Phù Yên, tỉnh Sơn La (Luận văn thạc sĩ)BT Tieng anh 6 UNIT 2Tranh tụng tại phiên tòa hình sự sơ thẩm theo pháp luật tố tụng hình sự Việt Nam từ thực tiễn xét xử của các Tòa án quân sự Quân khu (Luận văn thạc sĩ)Giáo án Sinh học 11 bài 15: Tiêu hóa ở động vậtGiáo án Sinh học 11 bài 15: Tiêu hóa ở động vậtchuong 1 tong quan quan tri rui roGiáo án Sinh học 11 bài 14: Thực hành phát hiện hô hấp ở thực vậtGiáo án Sinh học 11 bài 14: Thực hành phát hiện hô hấp ở thực vậtĐổi mới quản lý tài chính trong hoạt động khoa học xã hội trường hợp viện hàn lâm khoa học xã hội việt nam