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Heterogeneous catalysis in protodecarboxylation and c c bond formation 1

Heterogeneous catalysis in protodecarboxylation and c c bond formation 1

Heterogeneous catalysis in protodecarboxylation and c c bond formation 1

... Experimental 17 9 6.2 .1 Preparation of supported Cu catalyst 17 9 6.2.2 Catalytic studies 18 1 Results and discussion 18 1 6.3 .1 Characterisation of catalysts 18 1 6.3.2 Catalytic testing 19 1 6.3 6.3.2 .1 194 ... Deposition-precipitation 15 1. 1.3.4 1. 2 Impregnation Ion exchange 17 Ag, Cu and Pd nanocatalysts in cross coupling reactions 1. 2 .1   18 21 Suzuki coupling V         1. 2.2 Ullmann reaction 23 1. 3 Decarboxylative ... reaction 17 0 5.4 Conclusion 17 1 5.5 References 17 2 Chapter 6: Heterogeneous catalysts for the decarboxylative cross-coupling of aryl carboxylic acids and aryl halides 17 4 6 .1 Introduction 17 4 6.2...
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Heterogeneous catalysis in protodecarboxylation and c c bond formation 2

Heterogeneous catalysis in protodecarboxylation and c c bond formation 2

... group O O CO OC OC CO C OC CO M M OC CH3 OC CH3 C + CO OC CO M CH3 OC CO CO CO (c) Migratory insertion of hydride/ beta-hydride elimination (reverse) H M CH2 CH2 M H CH2 M C H2 CH2 CH3 (d) Oxidative ... 1.37 1.44 1 .28 Density/ g/cm3 12. 38 10.5 8.96 Melting point/ C 1555 9 62 1085 Electronegativity (Pauling scale) 2. 20 1.93 1.9 Atomic weight f .c. c.: face-centred cubic Pd, Ag, and Cu nanocatalysts ... Pd /C in the presence of zinc as reducing reagent (Scheme 1.4) [69] R1 Cl R1 + Zn + OH- R2 mol % Pd /C mol % PEG-400 60- 120 oC, 1 -2 h, H2O R2 + R2 R1 R2 + ZnO + H2O + Cl- R1 where R1= H, CH3 and R2=...
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Báo cáo khoa học: Protein folding and disulfide bond formation in the eukaryotic cell pptx

Báo cáo khoa học: Protein folding and disulfide bond formation in the eukaryotic cell pptx

... emerge in the coming years Protein targeting and disulfide bond formation in mitochondria Not only must proteins fold in the ER, but they must also be targeted to the right intracellular or extracellular ... Protein folding and disulfide formation A M Benham Elsinore focused mainly on protein folding in the eukaryotic endoplasmic reticulum (ER) and mitochondria An important consideration in these ... elucidating the folding pathways of disulfide bond- containing proteins [8] The Ventura group and others have made considerable progress in studying three model proteins from human pests, namely the...
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Tài liệu Báo cáo khoa học: Insights into and speculations about snake venom metalloproteinase (SVMP) synthesis, folding and disulfide bond formation and their contribution to venom complexity pdf

Tài liệu Báo cáo khoa học: Insights into and speculations about snake venom metalloproteinase (SVMP) synthesis, folding and disulfide bond formation and their contribution to venom complexity pdf

... [9] Superficially, one could simply Snake venom metalloproteinases and venom complexity attribute venom complexity to genomic ⁄ transcriptomic complexity, and to a certain degree this is the case ... 2008 FEBS 3017 Snake venom metalloproteinases and venom complexity J W Fox and S M T Serrano proteins are synthesized in the cytoplasm of secretory cells in the gland and transferred to the rough ... variety of proteomic and transcriptomic investigations of snake venom and venom glands respectively, numerous databases have been generated that illuminate the complexity of snake venoms, particularly...
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Báo cáo khoa học: Cytoglobin conformations and disulfide bond formation pdf

Báo cáo khoa học: Cytoglobin conformations and disulfide bond formation pdf

... the role of the disulfide bond in protein function and its involvement in the tertiary and quaternary structures Cytoglobin conformations and disulfide bond formation A Results and Discussion Quaternary ... government works 2701 Cytoglobin conformations and disulfide bond formation heterogeneity of kinetics After breaking the S–S bond, the histidine relaxes towards a stable conformation, and kinetic curves ... 8539–8547 Cytoglobin conformations and disulfide bond formation 10 Hankeln T, Ebner B, Fuchs C, Gerlach F, Haberkamp M, Laufs TL, Roesner A, Schmidt M, Weich B, Wystub S et al (2005) Neuroglobin and cytoglobin...
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Báo cáo khoa học: Aegyptin displays high-affinity for the von Willebrand factor binding site (RGQOGVMGF) in collagen and inhibits carotid thrombus formation in vivo ppt

Báo cáo khoa học: Aegyptin displays high-affinity for the von Willebrand factor binding site (RGQOGVMGF) in collagen and inhibits carotid thrombus formation in vivo ppt

... the sequence involved in collagen interaction with vWF, and also interacts with GPVI and integrin a2b1 binding sites Aegyptin effectively inhibits carotid thrombus formation in vivo Results Aegyptin ... detectable for collagen (lower right panel) Aegyptin binds with high affinity to the vWF binding site in collagen, independently of hydroxyproline In an attempt to identify the binding sites involved in ... Mosquito collagen -binding protein A C Fig Aegyptin displays high affinity for the vWF binding site of collagen Sensorgrams show aegyptin binding to immobilized cross-linked RGQOGVMGF (A), linear...
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Advances in Optical and Photonic Devices 2011 Part 1 potx

Advances in Optical and Photonic Devices 2011 Part 1 potx

... nonlinear spectroscopy, microscopy, and laser biomedicine 2 Advances in Optical and Photonic Devices The first mid-infrared broadband semiconductor laser was demonstrated in an intersubband ... distinct laser emissions (1. 65, 1. 62, and 1. 59 µm) from E0, E1 and E2 energy transitions were obtained at J = 1. 1×Jth from lasers with cavities L of 10 00, 300, and 15 0 µm, respectively The distinct ... increase in annealing temperature initiates more intermixing, and therefore improves the uniformity in shape, size and composition of Qdash leading to reduction in PL linewidth The result points...
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Physical Processes in Earth and Environmental Sciences Phần 1 pdf

Physical Processes in Earth and Environmental Sciences Phần 1 pdf

... Page xii LEED-Ch- 01. qxd 11 /26/05 12 :16 Page 1 Planet Earth and Earth systems 1. 1 Comparative planetology 1. 1 .1 Lateral thinking from general principles Physical processes on Earth and other planets ... Planet Earth and Earth systems, 1. 1 Comparative planetology, 1. 2 Unique Earth, 1. 3 Earth systems snapshots, 1. 4 Measuring Earth, 1. 5 Whole Earth, 10 1. 6 Subtle, interactive Earth, 14 Further reading, ... Allen and Unwin, 19 61) ; 5 .10 D Latin in Tectonic Evoution of the North Sea Rifts (Oxford, 19 90); 5 .12 , 5 .13 , 5 .14 I Kushiro, in Physics of Magmatic Processes, (Princeton, 19 80); 5 .15 USGS; 5 .16 ,...
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Báo cáo y học:

Báo cáo y học: " Detection of HIV-1 RNA/DNA and CD4 mRNA in feces and urine from chronic HIV-1 infected subjects with and without anti-retroviral therapy" pptx

... diagnosis of infection with human immunodeficiency virus type (HIV-1) by detection of antibody IgGs to pol and gag proteins of HIV-1 and p24 antigen of HIV-1 in urine, saliva, and/ or serum with highly ... DNA/ RNA and CD4 mRNA detection in feces and urine samples from HIV-1 infected individuals In addition, HIV-1 compartmentalization was revealed in gut, renal system and blood in one infected ... during HIV-1 infection, HIV-1 free virus and infected/ uninfected CD4+ T cells constantly shed from GALT into the intestinal lumen and are discharged with feces Therefore, the amount of HIV-1 and...
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Flocculation In Natural And Engineered Environmental Systems - Chapter 1 pot

Flocculation In Natural And Engineered Environmental Systems - Chapter 1 pot

... Cataloging -in- Publication Data Flocculation in natural and engineered environmental systems/ edited by Ian G Droppo [et al.] p cm Includes bibliographical references and index ISBN 1- 5 667 0-6 1 5-7 ... by CRC Press “L1 615 _C0 01 — 2004 /11 /19 — 02:46 — page 13#13 Flocculation in Natural and Engineered Environmental Systems 14 incorporated This combination permits simultaneous in situ detection ... Press “L1 615 _C0 01 — 2004 /11 /19 — 02:46 — page — #3 Flocculation in Natural and Engineered Environmental Systems Laser based sizing instruments are now being widely used to determine floc size in situ. 41, 42...
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Báo cáo sinh học:

Báo cáo sinh học: " Identification of a major gene in F and F data when alleles 1 2 assumed fixed in the parental lines" pps

... considering a the type I error rate as irrelevant When the variance in F increased when in fact no major gene was present, a major gene was found in 10 0% of the cases For smaller increases of the variance ... given major gene variance of 50 When using only F data, the test had a power of only 12 % for detection of an additive effect oft = 20 (table IV) When including i F data, however, the power was 10 0% ... increase in variance in F caused by , the major gene, was taken as an important indication for the presence of a major gene The power to detect a major gene in F data may also increase if alleles...
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The gulf of mexico oil spill   a corpus based study of metaphors in british and american media discourse 3 1

The gulf of mexico oil spill a corpus based study of metaphors in british and american media discourse 3 1

... refines the metaphorical analysis as it allows the analyst to understand the link between the grammatical context of the collocations and the range of metaphors generated A preliminary analysis ... diagrammatic representations of metaphors will enable the analyst to have a pictorial grasp of the overarching entailments and the range of conceptual metaphors employed in the analysis of the ... far/armchair engineers brainstormed for ways to stop the torrent of oil spilling into the Gulf of Mexico/ thousands of barrels of oil spilling into the gulf each day (6) Spilled oil behaves in many ways,...
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The gulf of mexico oil spill   a corpus based study of metaphors in british and american media discourse 6 1

The gulf of mexico oil spill a corpus based study of metaphors in british and american media discourse 6 1

... the 9 /11 attacks (THE BP OIL SPILL IS AN ENVIRONMENTAL 9 /11 ) The constant contextual parallels with Hurricane Katrina with respect to the Obama administration’s handling of the BP oil spill and ... handling of the BP Oil Spill and the Bush Administration’s handling of “Hurricane Katrina” in 2005 This will serve as an additional analysis to triangulate the metaphorical findings generated by the ... to the oil spill In conclusion, the detailed analysis of the range of analogy -based metaphors across the target semantic domains indicates the presence of a clear unifying ideological thread across...
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Tài liệu Debugging C and C++ code in a Unix environment ppt

Tài liệu Debugging C and C++ code in a Unix environment ppt

... if you are interested in it Chapter Aspects of debugging C and C+ + code Debugging C and C+ + code entails noticing, localising, understanding and repairing bugs Noticing and localising a bug You ... 21 Chapter Aspects of debugging C and C+ + code System call tracers A system call tracer is a program that allows you to see what system calls (including parameters and return values) a process ... the causes of problems with C and C+ + code, is the policy of requiring explicit allocation and deallocation of dynamic storage (malloc(2) and free(2) (C) or new and delete (C+ +)) As C and C+ +...
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Tài liệu Báo cáo khoa học: Verprolin function in endocytosis and actin organization Roles of the Las17p (yeast WASP)-binding domain and a novel C-terminal actin-binding domain doc

Tài liệu Báo cáo khoa học: Verprolin function in endocytosis and actin organization Roles of the Las17p (yeast WASP)-binding domain and a novel C-terminal actin-binding domain doc

... both a novel C-terminal actin- binding submodule (CABS) containing a novel actin monomer binding verprolin homology C-terminal (VH2-C) domain and a second submodule comprising the previously characterized ... actinbinding domain (this actin- binding domain has not yet been mapped) [23] We name the actin- binding domain that we have identified VH2-C and VH2-N because it is not yet clear how closely these domains ... Type I myosins can interact via an acidic tail (A) domain with the Arp2 ⁄ complex like Las17p, but they lack an actin- monomer-binding WH2 domain, which in WASP-family proteins (including Las17p) ...
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