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Advanced organic chemistry

Hóa hữu cơ nâng cao Tổng hợp phân tử phức tạp ( Advanced Organic Chemistry Synthesis of Complex Molecules )

Hóa hữu cơ nâng cao Tổng hợp phân tử phức tạp ( Advanced Organic Chemistry Synthesis of Complex Molecules )

... during the reaction: O • OH – Ru(VII) + 2e → Ru(V) TBSO 78% H3C CH3 HCH3O OTBS H H O O O O H O TBSO 2Ru(V) → Ru(VI) + Ru(IV) Julia-Lythgoe Olefination Ru(VI) + 2e– → Ru(IV) Griffith, W P.; Ley, S V.; ... Aldehyde (Ketone) R-CHO (RCOR ') hemiketal (hemiacetal) Oppenauer Oxidation Chromium (VI) Oxidants Sodium Hypochlorite N-Bromosuccinimide (NBS) Bromine Cerium (IV) Oxidants R Pyridinium Dichromate (PDC) ... Selectivity: (a) oxidation typically occurs at the more highly substituted terminus of the alkene (b) the order of reactivity of C–H bonds is CH2 > CH3 > CH [rule (a) takes precedence over rule (b)] (c)...
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Advanced organic chemistry

Advanced organic chemistry

... Professor of Organic Chemistry Department of Chemistry University of Missouri Columbia, Missouri 65211 (for feedback: HarmataM@missouri.edu) Reinhard Bruckner Professor of Organic Chemistry Institut ... richly rewarding field of organic chemistry Paul A Wender Stanford University Preface to the English Edition Writing a textbook at any level is always a challenge In organic chemistry, exciting new ... of organic and physical chemistry will suffice as a foundation for using this textbook to advantage The approach taken in this book conveys the message that the underlying theory of organic chemistry...
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advanced laboratory manual of organic chemistry

advanced laboratory manual of organic chemistry

... Bighta Reserved Press of J, J Uttte & Ivos Company HOT York, U S L TO N T H PREFACE In the field of organic chemistry there are a number of elementary laboratory manuals, any one of which may be ... choice of a guide for an advanced course, however, there is a vast amount of material available from which a selection in the form of a laboratory manual has never been made Hence the student is often ... product of the reaction is ^-nitroso-o-cresol« OF ORGANIC CHEMISTRY 17 54 g of o-cresol are dissolved in liters of ice-water in a battery jar provided with an adequate mechanical stirrer, and 34 g of...
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Advanced practical organic chemistry

Advanced practical organic chemistry

... though they may often be taught in isolation 2 Advanced Practical Organic Chemistry Organic chemistry is all around us, life is based on organic chemistry, the clothes we wear, the drugs we take, ... of organic molecules Organic chemists determine the structures of organic molecules, study their various reactions, and develop procedures for the synthesis of organic substances Organic chemistry ... of organic chemistry Organic molecules contain both carbon and hydrogen Though many organic chemicals also contain other elements, it is the carbon-hydrogen bond that defines them as organic Organic...
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Bài soạn Chapter 20 Organic Chemistry

Bài soạn Chapter 20 Organic Chemistry

... and σ bonds Chemistry, Julia Burdge, 2nd e., McGraw Hill Why Carbon sp3, sp2, and sp hybridization Chemistry, Julia Burdge, 2nd e., McGraw Hill FUNCTIONAL GROUPS Alkane Organic chemistry is ... of studying Organic Alkyl halide chemistry is the making of Aromatic carbon-carbon bonds, C-X, C-O, C-N, and C-S bonds to make new molecules Alcohol Aldehyde Ketone Carboxylic Acid Inorganic molecules ... isomerism Tro, Chemistry: A Molecular Approach 27 Possible Structural Isomers Carbon Molecular Possible Content Formula Isomers C4H10 C5H12 C6H14 C7H16 C8H18 18 C9H20 35 10 C10H22 75 Tro, Chemistry: ...
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Tài liệu THE VOCABULARY AND CONCEPTS OF ORGANIC CHEMISTRY pptx

Tài liệu THE VOCABULARY AND CONCEPTS OF ORGANIC CHEMISTRY pptx

... governs the size of the orbital (wave function) and determines the energy of the orbital The value of n corresponds to the number of the shell in the Bohr atomic theory and the larger the n, the ... behavior of the atoms and so knowledge of the positions and energies of the electrons is of great importance The correlation of the properties of atoms with their atomic structure expressed in the ... the energy of the electrons, and their location in space with respect to the nuclei they hold together are fundamental to the understanding of all chemistry The nature of the bonding of atoms to...
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Fundamentals of organic chemistry

Fundamentals of organic chemistry

... bridge from general chemistry to your beginning study of organic chemistry Once you have a firm understanding of structure, the puzzle of organic chemistry can become one of very manageable size ... OMPOUNDS 1.1 AND C HEMICAL B ONDS INTRODUCTION Organic chemistry is the study of the compounds of carbon The compounds of carbon are the central substances of which all living things on this planet ... some of these sugars, together with inorganic phosphates, combined with purines and pyrimidines to become simple molecules of ribonucleic acids (RNAs) and DNA We live in an Age of Organic Chemistry: ...
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hóa hữu cơ ( organic chemistry )

hóa hữu cơ ( organic chemistry )

... Phan, Hoa T V Tran Organic chemistry , VNU-HCMC Publisher, 2010 [2] Nam T S Phan, ‘Study guide to organic chemistry , VNU-HCMC Publisher, 2009 [3] Paula Y Bruice, Organic chemistry , fifth edition, ... group in a periodic table -I CH CH CH COOH CH3CH2CH(Cl)COOH 1.5 139 Strong -I 8.9 weak -I CH CH(Cl)CH COOH CONJUGATION / MESOMERIC EFFECTS (C / M) Electron delocalization in a conjugated system: ... or achiral (meso compounds) 38 Separating enantiomers Racemic mixture: 1/1 mixture of enantiomers 39 CHIRALITY & BIOLOGICAL ACTIVITY 40 CHIRALITY & BIOLOGICAL ACTIVITY 41 ORGANIC CHEMISTRY Dr...
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ORGANIC CHEMISTRY (hóa học hữu cơ _FOURTH EDITION_Maitland Jones, Jr. Steven A. Fleming

ORGANIC CHEMISTRY (hóa học hữu cơ _FOURTH EDITION_Maitland Jones, Jr. Steven A. Fleming

... Data Jones, Maitland, 1937– Organic chemistry / Maitland Jones, Jr. 4th ed / Steven A Fleming p cm Includes bibliographical references and index ISBN 978-0-393-93149-5 (hardcover) Chemistry, Organic Textbooks ... Organic Chemistry Organic Chemistry FOURTH EDITION Maitland Jones, Jr NEW YORK UNIVERSITY Steven A Fleming TEMPLE UNIVERSITY W W Norton & Company ... up yet What Is Organic Chemistry? Organic chemistry is traditionally described as the chemistry of carbon-containing compounds Until the nineteenth century, it was thought that organic molecules...
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Tài liệu Small Scale Laboratory: Organic Chemistry at University Level doc

Tài liệu Small Scale Laboratory: Organic Chemistry at University Level doc

... COMPONENTS OF SMALL- LAB KIT • SMALL- SCALE APPARATUS AND TECHNIQUE CHAPTER I: TECHNIQUES IN THE ORGANIC CHEMISTRY LABORATORY • RECRYSTALLIZATION • DISTILLATION • SUBLIMATION • CHROMATOGRAPHY CHAPTER ... Science, Chulalongkorn University, Bangkok, Thailand 10330 Tel / Fax +66 2218 7641, e-mail: supawan.t@chula.ac.th Small Scale Laboratory: Organic Chemistry at University Level FOREWORD INTRODUCTION ... Science, Chulalongkorn University, Bangkok, Thailand 10330 Tel / Fax +66 2218 7641, e-mail: supawan.t@chula.ac.th Small Scale Laboratory: Organic Chemistry at University Level Compiled, Tested...
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EXPERIMENTAL ORGANIC CHEMISTRY pptx

EXPERIMENTAL ORGANIC CHEMISTRY pptx

... handling problems in organic chemistry A chapter of the book is devoted to detailed directions for carrying out the simpler operations used in laboratory work in organic chemistry In order that ... 202—Casein, 203—Textile fibers, 203 CHAPTER XXVII.—THE IDENTIFICATION OF ORGANIC COMPOUNDS 205 APPENDIX 211 INDEX 215 EXPERIMENTAL ORGANIC CHEMISTRY CHAPTER I LABORATORY METHODS General Directions to the ... result of the introduction of traces of organic matter, a tiny piece of a crystal of potassium nitrate will destroy the color 34 EXPERIMENTAL ORGANIC CHEMISTRY The substance, the melting-point...
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Introduction to Organic Chemistry doc

Introduction to Organic Chemistry doc

... 56 Aromatics 58 Chem Nat Substances p Introduction to Organic Chemistry An Introduction to Organic Chemistry Organic chemistry is the study of carbon containing compounds and ... Substances p4 Introduction to Organic Chemistry Class exercise: Given carbon atoms and as many hydrogen atoms as required construct possible organic molecules which contain (i) oxygen atom (ii) different ... it can form molecules that contain from one to an infinite number of C atoms Chem Nat Substances p3 Introduction to Organic Chemistry Additionally C atoms may:  be bonded by multiple bonds (i.e...
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PRACTICAL ORGANIC CHEMISTRY potx

PRACTICAL ORGANIC CHEMISTRY potx

... appreciated by most teachers of practical organic chemistry Teachers of chemistry (and of the sciences generally) will have found that many students appear to dissociate their practical work sharply in ... comparative practical value This combination of theory and practice will, it is hoped, both simplify and elucidate the practical study of organic chemistry, and enable the student to visualise his practical ... steady condensation of steam in C will produce too great a volume of liquid 34 PRACTICAL ORGANIC CHEMISTRY If the organic compound which is being steam-distilled is freely soluble in water, an...
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ORGANIC CHEMISTRY LABORATORY PROCEDURES pdf

ORGANIC CHEMISTRY LABORATORY PROCEDURES pdf

... This page left blank ORGANIC CHEMISTRY LABORATORY PROCEDURES Fourth Edition RICHARD L WHEET Department of Chemical Technology Texas ... writing from the author REFERENCES Morrison and Boyd, Organic Chemistry Hajian, Modern Chemical Technology This page left blank TABLE OF CONTENTS LABORATORY SAFETY SIMPLE DISTILLATION OF A SINGLE ... purity of an organic compound Extremely pure compounds have ranges of 0.1 to 0.3 C Commercially available compounds (technical grade) have ranges of 2-3 C The normal laboratory grade organic (ACS)...
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ORGANIC CHEMISTRY LABORATORY MANUAL pdf

ORGANIC CHEMISTRY LABORATORY MANUAL pdf

... 114 Organic Laboratory Equipment and Procedures Organic Chemistry I and II Lab Manual Organic Laboratory Equipment and Procedures Introduction: Organic chemistry lab is different from general chemistry ... State University Organic Chemistry I and II Lab Manual Page of 114 Safety Guidelines Organic Chemistry I and II Lab Manual Laboratory Safety Guidelines Dakota State University Chemistry Laboratories ... Introduction Organic Chemistry I and II Lab Manual Introduction Organic chemistry is a fascinating field Think about it, of roughly 110 elements on the periodic chart, organic chemistry is a...
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