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Structures and electronic properties of si nanowires grown along the [1 1 0] direction role of surface reconstruction

Structures and electronic properties of si nanowires grown along the [1 1 0] direction role of surface reconstruction

Structures and electronic properties of si nanowires grown along the [1 1 0] direction role of surface reconstruction

... primarily along the [11 0] direction while the NWs with large diameter are grown along the [11 1] direction. The HRTEM has also observed the hexagonal nanowire shapewhich consists of {0 01} and {11 1} ... and p-bonded chain structures on flat Si( 11 1) surface (0 .13 eV /1 Â 1 cell). The appearance of p-bonded chain implies that the stability of {11 1} facets is similarto that in clean Si( 11 1) surface. 3In ... Structures and electronic properties of Si nanowires grown along the [11 0] direction: Role of surface reconstruction Toru Akiyama*, Kohji Nakamura, Tomonori ItoDepartment of Physics Engineering,...
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Multilevel modeling of the influence of surface transport peculiarities on growth, shaping, and doping of si nanowires

Multilevel modeling of the influence of surface transport peculiarities on growth, shaping, and doping of si nanowires

... blocking of the surface transport in the presence of slowly diffu sing additives at the surface; (2) appearance of the surface flux anisotropy and transfer to the mode of sub-diffusion, when the coverage ... PRESSFig. 4. The MC simulations of the surface steady-state characteristicsunder the adsorption of silicon-containing molecules together with the surface transport of silicon adatoms towards the sidewalls. ... function. The second equation of the system describes the NWaxial growth due to bulk diffusion of silicon atoms from the surface to the catalyst/NW interface.Here, h is the height of the NW and O...
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Si nanowires grown from silicon oxide

Si nanowires grown from silicon oxide

... scale, the Ä4appearance of 11 1 surfaces of the Si crystals paral-lel to the axes of the nanowires reduces the systemenergy. Combined, these factors determine the ²:growth direction of Si nanowires ... below. Si O™ Si qSiO x )1 Ž.xxy1 and 2SiO™ SiqSiO .2These decompositions result in the precipitation of silicon nanoparticles, i.e. the nuclei of Si nanowires, clad by shells of silicon oxide as ... due to the small size effect of Si wxnanocrystals or defects 11 ,16 since there were manynanoparticles in the product, as well as Si nanowires wxcontaining a high-density of defects 10 ,11 . In...
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Characteristics of siox nanowires synthesized via the thermal heating of cu coated si substrates

Characteristics of siox nanowires synthesized via the thermal heating of cu coated si substrates

... beenfabricated previously using the VLS method [10 ,13 16 , 1921, 23,24]. The growth of the SiOx nanowires in the present studycan be divided into several steps. In the first step, when the Si wafer with Cu ... for the first time we report the production of SiOx nanowires by the simple heating of Cu-coated Si substrates. We have investigated the effect of Cu layerthickness on the growth of SiOx nanowires. ... novel properties, and potential applications [1 3], considerable efforts havebeen placed on the synthesis and characterization of thosematerials over the past several years.Silicon (Si) and silica...
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Amorphous silica nanowires grown by the vapor–solid mechanism

Amorphous silica nanowires grown by the vapor–solid mechanism

... Increasing the process time up to 12 0 mindoes not change the diameter and the length of the silica nanowires significantly, indicating the Fig. 3. EDS spectra according to the positions of the silica ... 2.7 eV band is ascribed to the neutral ox-ygen vacancy (BSi–SiB) [12 ], and the 3 .1 eV bandis due to a twofold coordinated silicon lone-paircenters (O Si O) [13 ]. These defects are clearlyinduced ... regions of the silica particle layers to form the nanowires. In an initial stage of the nanowire growth, ironvapor forms a Fe Si O phase, as shown in Fig. 3b,with silica at the surface of the silica...
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Electronic and Optoelectronic Properties of Semiconductor Structures

Electronic and Optoelectronic Properties of Semiconductor Structures

... Semiconductor Bandstructure 10 19 10 18 10 17 10 16 10 15 10 14 10 13 10 12 10 11 10 10 10 9 10 8 10 7 10 6 10 00 500 200 10 027 0−20T(C)0.5 1. 0 1. 5 2.0 2.5 3.0 3.5 4.0 10 00/T(K− 1 )Ge Si GaAsINTRINSICCARRIER ... arsenide [11 1] [10 0] Eg= 1. 43eVat 300 KFigure 2 .17 : Bandstructure of GaAs. The bandgap at 0 K is 1. 51 eV and at 300 K it is 1. 43 eV. The bottom of the conduction band is atk =(0, 0, 0), i.e., the ... 81 at 300 KSilicon65432 1 0− 1 −2−3−4 1. 1Eg3.4(a)ENERGY(eV)(b)kzkx (10 0)( 010 )(0 01) ( 010 ) (10 0)(0 01) kySix equivalentvalleys atconductionbandedgeΓ [11 0] [11 1] Eg=...
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Preparation and photoluminescence properties of amorphous silica nanowires

Preparation and photoluminescence properties of amorphous silica nanowires

... light emission at350 nm was observed in oxidized porous silicon and annealed SiO2 [15 ]. The PL spectrum is alsodierent from that of oxidized Si nanowires [16 ]. The growth process of the nanowires ... by the vapor±liquid±solid (VLS) mech-anism, since little droplets can be seen at the tops of the nanowires [17 ]. The growth of the nanowires Fig. 2. XPS of the sample. (a) survey spectrum of the ... found todeposit on the surface of the pellets and the ther-malcouple. TEM images of the products were takenwith a JEM-200CX transmission electron micro-scope. The composition of SiONWs was...
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Si nanowires synthesized by laser ablation of mixed sic and sio2 powders

Si nanowires synthesized by laser ablation of mixed sic and sio2 powders

... consists of the 11 1 ,Ž. Ž.220 and 311 rings of silicon. The other corre-Ž.Ž. Ž.sponds to the 11 1 , 220 and 311 rings of b-SiC.This confirms that the sample is a mixture of SiNWs and b-SiC. ... a Siemens D500 system. The spec-trum shows two sets of peaks. One set consists of the Ž.Ž. Ž. 11 1 , 220 and 311 peaks of Si which are fromŽ.Ž. the SiNWs. The other set consists of the 11 1 , ... consists of the 11 1 , 220Ž. and 311 peaks of b-SiC which are from the b-SiCnanoparticles. The positions of the peaks fit the wxvalues in the standard XRD handbook 17 . The Raman scattering measurement...
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Spontaneous growth and luminescence of si siox core shell nanowires

Spontaneous growth and luminescence of si siox core shell nanowires

... axes of the nanowires can minimize the system energy, since the {1 1 1} surface has the lowest surface energy among the Si surfaces, whichbecomes increasingly important when the crystalsize ... istaken from the single core at the tip area. It couldbe indexed for the [2 1 1] zone axis of single crys-talline Si, and indicates that the nanowire growthoccurs along [1 1 1] direction. A ... nanometer scale. Theseimportant factors may determine the growth direction of Si nanowires to be h 112 i. The oxide-assisted mechanism can predict some of the mor-phology of nanowires [11 ], which were...
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Synthesis of large scale sic–sio2 nanowires decorated with amorphous carbon nanoparticles and raman and PL properties

Synthesis of large scale sic–sio2 nanowires decorated with amorphous carbon nanoparticles and raman and PL properties

... madeassigning to the outstanding ultraviolet-blue emission property of SiC–SiO2 nanowires. In previous works, the PL property of SiC–SiO2 nanowires has been studied as -grown [15 19 ] and no efforthas ... of hemispheric depositions werefound on the surface of the nanowires synthesized under the con-dition -1. The mean diameter of hemispheric depositions was eval-uated to be about 20 nm and their ... mode [ 21 23]. The SiC LO mode, which is expected at972 cm 1 , is not very clear in two spectra. The degradation of the corresponding SiC LO mode is indicative of growth along the [1 1 1] direction...
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