... composition, we completed additional MS andNMR-based analysis of the cRBC glycan pool. Inaddition to identification and quantification of othermonosaccharides, we aimed to characterize the overallsialic ... pool, we detect the presence of several important signatures, including the H-1 anomeric protons, the H-2 protons of man-nose (Man) (d 4.05–4.25 p.p.m.), and the methyl pro-tons of the N-acetyl ... from the proton spectrum of cRBC glycans, the presence of a prevalent proton sig-nal from the anomeric position of Manb1 fi 4 necessi-tated running an HSQC experiment to resolve thisregion of the...